AC-assisted microbially induced carbonate precipitation for sand reinforcement: An experimental study

Abstract

Microbially induced carbonate precipitation (MICP) is a promising method for transforming natural soils into a rock-like material, enhancing soil strength and creating an environmentally friendly engineered geomaterial for load-bearing purposes. Applying alternating current (AC) for enhancing precipitation including changing the crystalline form of the calcium carbonate precipitates appeals as a possible solution to break the upper limit of the unconfined compressive strength (UCS) of bio-treated specimens. To assess the viability of AC-assisted MICP, a series of experiments were designed and conducted under various combination of conditions. The UCS, calcium carbonate content and permeability of the bio-fabricated specimens were obtained to evaluate the treatment effectiveness of AC-assisted MICP. The results demonstrate that the UCS of the sand column exhibits a linear increase with the applied voltage from 10 V to 30 V (i.e., electric field strength from 0.91 V/cm to 2.73 V/cm). The UCS value of the bio-specimen reaches 9.4 MPa after 3 treatments at a concentration of 1.00 mol/L, a voltage of 30 V, and a frequency of 100 Hz. With the assistance of an AC electric field, the adverse impacts caused by high chemical concentrations in the MICP process can be mitigated. We report that a more uniform distribution of the calcium carbonate content of the treated specimen is obtained under an optimal AC frequency of approximately 100 Hz in the current series of experiments. The induced ion vibration under the action of AC results in a change in crystalline form and an increase in the amount and uniformity of crystals precipitated on the surface of the soil grains, supported by X-ray diffraction (XRD) patterns and scanning electron microscope (SEM) images. For reference, the energy consumption and the cost for increasing the UCS of the bio-treated specimen to 5 MPa is estimated at 375.86 kWh and 676.55 HK$ per cubic meter, respectively. The findings from our experimental investigation and analysis provide compelling evidence that utilizing AC electric field holds great potential for achieving an enhanced treatment effect of MICP and hence a stronger bio-soil.