Advancing gamma radiation shielding with Bitumen-WO₃ composite materials

Abstract

This research focuses on a manner in which bitumen-WO₃ (petroleum-derived bitumen mixed with tungsten trioxide nanoparticles) materials can be a good shielding candidate against gamma radiation. The objective we set in mixing WO₃ nanoparticles with bitumen was to take advantage of both the bitumen's natural qualities and the WO₃'s excellent shielding capabilities. The prepared composites were tested against various gamma-ray energies emitted from multiple gamma-ray sources to examine their shielding capabilities. The X-ray diffraction (XRD) analysis of the composites' structural properties verified the effective integration of the WO₃ with the bitumen structure. Scanning electron microscopy (SEM) showed that microstructural changes, such as an increase in material density and an improvement in particle dispersion, are caused by a rise in WO₃ concentration, which is an essential step toward efficient shielding. Then, the Mean Free Path (MFP), Half-value Layer (HVL), and Linear Attenuation Coefficients (μ_l) were computed, showing that the composite's capacity to reduce gamma radiation is much enhanced by raising the WO₃ content, especially at lower gamma-ray energies. For instance, at 20 keV, the LAC of 50 wt% WO₃-bitumen composite increased to 9.18 cm⁻¹ compared to pure bitumen's 0.40 cm⁻¹, while the HVL decreased from 1.73 cm to 0.08 cm, and the MFP dropped from 2.3 cm to 0.1 cm” The results demonstrate the potential of bitumen-WO₃ composites as a sustainable and efficient material for radiation shielding, particularly highlighting their applicability in various sectors, including the development of building wall paints against gamma radiation.