Impacting Non-Covalent Interactions through Vibrational Strong Coupling.

IF 3 4区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY ChemPlusChem Pub Date : 2024-10-30 DOI:10.1002/cplu.202400591
Kalaivanan Nagarajan, Sourav Maiti, Gnana Maheswar Kothapalli
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Abstract

Light-matter strong coupling, especially Vibrational Strong Coupling (VSC), has become a significant research focus due to its potential to alter materials' inherent physical and chemical properties. Remarkably, VSC operates even in the absence of light, harnessing subtle quantum fluctuations to influence material characteristics. Vibro-polaritonic states, which are half photonic and half material, are introduced in the molecular/material energy ladder under VSC conditions. Although the underlying mechanism remains elusive, it is proposed that these hybrid states may modify chemical reactivity and other properties by altering factors such as polarity, polarizability, and Van der Waals interactions. This evolving field, vibro-polaritonic chemistry, holds vast potential for deeper exploration, particularly within molecular sciences. This Review examines VSC's observed effects on non-bonding interactions, including hydrogen bonding and π-π interactions, typically governed by dispersive forces.

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通过振动强耦合影响非共价相互作用
光-物质强耦合,尤其是振动强耦合(VSC),因其改变材料固有物理和化学特性的潜力而成为研究的重点。值得注意的是,振动强耦合甚至可以在没有光的情况下工作,利用微妙的量子波动影响材料特性。在 VSC 条件下,分子/材料能量阶梯中引入了振动极子态,这种态一半是光子态,一半是材料态。虽然其基本机制仍然难以捉摸,但有人提出,这些混合态可能会通过改变极性、极化性和范德华相互作用等因素来改变化学反应性和其他特性。振动极性化学这一不断发展的领域蕴含着深入探索的巨大潜力,尤其是在分子科学领域。本综述探讨了所观察到的振动极化对非键相互作用的影响,包括氢键和 π-π 相互作用,这些作用通常受分散力的支配。
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来源期刊
ChemPlusChem
ChemPlusChem CHEMISTRY, MULTIDISCIPLINARY-
CiteScore
5.90
自引率
0.00%
发文量
200
审稿时长
1 months
期刊介绍: ChemPlusChem is a peer-reviewed, general chemistry journal that brings readers the very best in multidisciplinary research centering on chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies. Fully comprehensive in its scope, ChemPlusChem publishes articles covering new results from at least two different aspects (subfields) of chemistry or one of chemistry and one of another scientific discipline (one chemistry topic plus another one, hence the title ChemPlusChem). All suitable submissions undergo balanced peer review by experts in the field to ensure the highest quality, originality, relevance, significance, and validity.
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