{"title":"The sulfur isotopic composition of Cenozoic pyrite is affected by methane content and depositional environment","authors":"","doi":"10.1016/j.epsl.2024.119097","DOIUrl":null,"url":null,"abstract":"<div><div>The sulfur isotopic composition of pyrite (δ<sup>34</sup>S<sub>pyr</sub>) is often used to reconstruct ancient geobiological processes, but recent studies have shown that δ<sup>34</sup>S<sub>pyr</sub> is strongly dependent on local sedimentary environmental conditions. Here we present a global compilation of >3700 published pyrite sulfur isotopic compositions from the past 165 million years, from outcrop as well as marine sediment cores. We show that sediment core δ<sup>34</sup>S<sub>pyr</sub> has a statistically significant relationship with methane content, sedimentation rate, lithology, and proximity from shore, while outcrop δ<sup>34</sup>S<sub>pyr</sub> has distinct distributions depending on categories of depositional water depth and lithology. There are no obvious trends in the average δ<sup>34</sup>S<sub>pyr</sub> from the late Mesozoic to the present, although we suggest that this temporal record is affected by the inherent bias of data compilation. Our study further emphasizes the importance of considering sedimentology and stratigraphic context when using the sulfur isotopic composition of pyrite to infer global environmental changes.</div></div>","PeriodicalId":11481,"journal":{"name":"Earth and Planetary Science Letters","volume":null,"pages":null},"PeriodicalIF":4.8000,"publicationDate":"2024-10-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Earth and Planetary Science Letters","FirstCategoryId":"89","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0012821X24005296","RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"GEOCHEMISTRY & GEOPHYSICS","Score":null,"Total":0}
引用次数: 0
Abstract
The sulfur isotopic composition of pyrite (δ34Spyr) is often used to reconstruct ancient geobiological processes, but recent studies have shown that δ34Spyr is strongly dependent on local sedimentary environmental conditions. Here we present a global compilation of >3700 published pyrite sulfur isotopic compositions from the past 165 million years, from outcrop as well as marine sediment cores. We show that sediment core δ34Spyr has a statistically significant relationship with methane content, sedimentation rate, lithology, and proximity from shore, while outcrop δ34Spyr has distinct distributions depending on categories of depositional water depth and lithology. There are no obvious trends in the average δ34Spyr from the late Mesozoic to the present, although we suggest that this temporal record is affected by the inherent bias of data compilation. Our study further emphasizes the importance of considering sedimentology and stratigraphic context when using the sulfur isotopic composition of pyrite to infer global environmental changes.
期刊介绍:
Earth and Planetary Science Letters (EPSL) is a leading journal for researchers across the entire Earth and planetary sciences community. It publishes concise, exciting, high-impact articles ("Letters") of broad interest. Its focus is on physical and chemical processes, the evolution and general properties of the Earth and planets - from their deep interiors to their atmospheres. EPSL also includes a Frontiers section, featuring invited high-profile synthesis articles by leading experts on timely topics to bring cutting-edge research to the wider community.