Joy N. Onwumere, Rong Hua, Guojun Zhou, Haoquan Zheng and Zhehao Huang
{"title":"Bismuth oxybromide nanosheets as an efficient photocatalyst for dye degradation†","authors":"Joy N. Onwumere, Rong Hua, Guojun Zhou, Haoquan Zheng and Zhehao Huang","doi":"10.1039/D4DT02180K","DOIUrl":null,"url":null,"abstract":"<p >The contamination of water resources by organic pollutants presents significant environmental and health challenges. Therefore, it is urgent to develop highly efficient and green approach for treating organic water pollutants. Bismuth oxybromide (BiOBr) has gained attention due to its high photoactivity. In this work, we report a modification to improve its photocatalytic activity. BiOBr were prepared using a capping agent, benzene-1,3,5-tricarboxylic acid, to tune the morphology of the compound. The resulting BiOBr shows nanosheet morphology, which provides a high surface-to-volume ratio and a larger conduction band compared to bulk BiOBr. As a result, the BiOBr nanosheets show the highest efficiency for photodegradation of Rhodamine B, compared to benchmark TiO<small><sub>2</sub></small> and bulk BiOBr catalysts.</p>","PeriodicalId":71,"journal":{"name":"Dalton Transactions","volume":" 48","pages":" 19196-19201"},"PeriodicalIF":3.3000,"publicationDate":"2024-10-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2024/dt/d4dt02180k?page=search","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Dalton Transactions","FirstCategoryId":"92","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2024/dt/d4dt02180k","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
Abstract
The contamination of water resources by organic pollutants presents significant environmental and health challenges. Therefore, it is urgent to develop highly efficient and green approach for treating organic water pollutants. Bismuth oxybromide (BiOBr) has gained attention due to its high photoactivity. In this work, we report a modification to improve its photocatalytic activity. BiOBr were prepared using a capping agent, benzene-1,3,5-tricarboxylic acid, to tune the morphology of the compound. The resulting BiOBr shows nanosheet morphology, which provides a high surface-to-volume ratio and a larger conduction band compared to bulk BiOBr. As a result, the BiOBr nanosheets show the highest efficiency for photodegradation of Rhodamine B, compared to benchmark TiO2 and bulk BiOBr catalysts.
期刊介绍:
Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.