{"title":"Quantifying zinc and manganese reduction potentials in organic solvents","authors":"Sagnik Chakrabarti , Liviu M. Mirica","doi":"10.1016/j.chempr.2024.10.015","DOIUrl":null,"url":null,"abstract":"<div><div>Zinc and manganese are the reductants of choice for nickel-catalyzed cross-electrophile coupling (XEC), but their exact redox potentials are unknown in organic solvents. In a recent report from Stahl and colleagues in <em>Nature Chemistry</em>, these potentials have been measured for the first time and their implications on model XEC reactions have been discussed.</div></div>","PeriodicalId":268,"journal":{"name":"Chem","volume":"10 11","pages":"Pages 3273-3275"},"PeriodicalIF":19.1000,"publicationDate":"2024-11-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chem","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2451929424005412","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
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Abstract
Zinc and manganese are the reductants of choice for nickel-catalyzed cross-electrophile coupling (XEC), but their exact redox potentials are unknown in organic solvents. In a recent report from Stahl and colleagues in Nature Chemistry, these potentials have been measured for the first time and their implications on model XEC reactions have been discussed.
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Chem, affiliated with Cell as its sister journal, serves as a platform for groundbreaking research and illustrates how fundamental inquiries in chemistry and its related fields can contribute to addressing future global challenges. It was established in 2016, and is currently edited by Robert Eagling.
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