Determination of Potassium, Neodymium, and Strontium in Solid Solutions in the KNd(SO4)2·H2O–SrSO4·0.5H2O System Using X-Ray Fluorescence Spectrometry

IF 1 4区 化学 Q4 CHEMISTRY, ANALYTICAL Journal of Analytical Chemistry Pub Date : 2024-11-01 DOI:10.1134/S1061934824700977
N. N. Bushuev, D. S. Zinin, G. K. Tatosyan, N. V. Sviridenkova
{"title":"Determination of Potassium, Neodymium, and Strontium in Solid Solutions in the KNd(SO4)2·H2O–SrSO4·0.5H2O System Using X-Ray Fluorescence Spectrometry","authors":"N. N. Bushuev,&nbsp;D. S. Zinin,&nbsp;G. K. Tatosyan,&nbsp;N. V. Sviridenkova","doi":"10.1134/S1061934824700977","DOIUrl":null,"url":null,"abstract":"<p>The composition of solid solutions in the KNd(SO<sub>4</sub>)<sub>2</sub>·H<sub>2</sub>O–SrSO<sub>4</sub>·0.5H<sub>2</sub>O system, synthesized from aqueous solutions of KCl, NdCl<sub>3</sub>, SrCl<sub>2</sub>, and H<sub>2</sub>SO<sub>4</sub>, was studied by X-ray fluorescence spectrometry. Coefficients of calibration dependences for intensity vs. element concentrations were calculated for Nd, Sr, and K by the least-squares technique. A linear approximation function was used in determining potassium and a parabolic approximation function was recommended in determining neodymium and strontium. The obtained dependences are characterized by low (&lt;1%) relative approximation errors. In the analytical ranges (wt %) for K 0.863−8.892, Sr 8.41−38.03, and Nd 5.296−29.30, the standard deviations were 0.012−0.028, 0.008−0.098, and 0.05−0.27 respectively.</p>","PeriodicalId":606,"journal":{"name":"Journal of Analytical Chemistry","volume":null,"pages":null},"PeriodicalIF":1.0000,"publicationDate":"2024-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Analytical Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S1061934824700977","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
引用次数: 0

Abstract

The composition of solid solutions in the KNd(SO4)2·H2O–SrSO4·0.5H2O system, synthesized from aqueous solutions of KCl, NdCl3, SrCl2, and H2SO4, was studied by X-ray fluorescence spectrometry. Coefficients of calibration dependences for intensity vs. element concentrations were calculated for Nd, Sr, and K by the least-squares technique. A linear approximation function was used in determining potassium and a parabolic approximation function was recommended in determining neodymium and strontium. The obtained dependences are characterized by low (<1%) relative approximation errors. In the analytical ranges (wt %) for K 0.863−8.892, Sr 8.41−38.03, and Nd 5.296−29.30, the standard deviations were 0.012−0.028, 0.008−0.098, and 0.05−0.27 respectively.

Abstract Image

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
利用 X 射线荧光光谱法测定 KNd(SO4)2-H2O-SrSO4-0.5H2O 体系固溶体中的钾、钕和锶
X 射线荧光光谱法研究了 KNd(SO4)2-H2O-SrSO4-0.5H2O 体系固溶体的组成,该固溶体是由 KCl、NdCl3、SrCl2 和 H2SO4 的水溶液合成的。通过最小二乘法技术计算了 Nd、Sr 和 K 的强度与元素浓度的校准相关系数。在测定钾时使用了线性近似函数,在测定钕和锶时建议使用抛物线近似函数。所获得的依赖关系具有相对近似误差小(1%)的特点。在钾 0.863-8.892、锶 8.41-38.03 和钕 5.296-29.30 的分析范围(重量百分比)内,标准偏差分别为 0.012-0.028、0.008-0.098 和 0.05-0.27。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
Journal of Analytical Chemistry
Journal of Analytical Chemistry 化学-分析化学
CiteScore
2.10
自引率
9.10%
发文量
146
审稿时长
13 months
期刊介绍: The Journal of Analytical Chemistry is an international peer reviewed journal that covers theoretical and applied aspects of analytical chemistry; it informs the reader about new achievements in analytical methods, instruments and reagents. Ample space is devoted to problems arising in the analysis of vital media such as water and air. Consideration is given to the detection and determination of metal ions, anions, and various organic substances. The journal welcomes manuscripts from all countries in the English or Russian language.
期刊最新文献
Separation of Chlorogenic Acids and Caffeine on a Diasfer-110-C10CN Stationary Phase Development, Validation, and Quantification of Organic Impurities with Mass Balance in the Levodopa and Benserazide Hydrochloride Pharmaceutical Dosage Form Surface-Assisted Laser Desorption/Ionization of Metal Complexes with Dithizone Determination of Potassium, Neodymium, and Strontium in Solid Solutions in the KNd(SO4)2·H2O–SrSO4·0.5H2O System Using X-Ray Fluorescence Spectrometry Thin-Layer Chromatography of Methylated Derivatives of Linear Alkylbenzene Sulfonates in Water Analysis by Gas Chromatography–Mass Spectrometry
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1