Defect Engineering with Rational Dopants Modulation for High-Temperature Energy Harvesting in Lead-Free Piezoceramics

IF 26.6 1区 材料科学 Q1 Engineering Nano-Micro Letters Pub Date : 2024-11-04 DOI:10.1007/s40820-024-01556-5
Kaibiao Xi, Jianzhe Guo, Mupeng Zheng, Mankang Zhu, Yudong Hou
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Abstract

Highlights

  • The solution limit of manganese ion in BiFeO3–BaTiO3 (BF–BT) was determined by combining multiple advanced characterization methods.

  • The defect engineering associated with fine doping can realize the co-modulation of polarization configuration, iron oxidation state and domain orientation.

  • The BF–BT–0.2Mn piezoelectric energy harvester shows excellent power generation capacity at 250 °C, which is an important breakthrough for lead-free piezoelectric devices.

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利用合理掺杂调制缺陷工程实现无铅压电陶瓷的高温能量收集
高温压电能量收集器(HT-PEH)是替代化学电池实现高温无线传感器独立供电的重要解决方案。然而,无铅压电陶瓷必须同时具有优异的性能,包括高优点系数(FOM)、绝缘电阻率(ρ)和去极化温度(Td),但这很难实现,尤其是在 250 °C 下工作的无铅压电陶瓷更是如此。在这里,通过创新的缺陷工程和精细的锰掺杂,BiFeO3-BaTiO3 陶瓷实现了良好的平衡性能。由于极化构型优化提高了电致伸缩系数,高价锰离子调节了铁离子氧化态,缺陷偶极稳定了畴取向,这些协同作用在锰离子的固溶极限下实现了全面优异的电性能(Td = 340 ℃,ρ250 ℃ > 107 Ω cm,FOM250 ℃ = 4905 × 10-15 m2 N-1)。利用合理设计的压电陶瓷组装的 HT-PEH 可在 250 ℃ 下对商用电解电容器进行快速充电,并具有较高的能量转换效率(η = 11.43%)。这些特性表明,缺陷工程定制的 BF-BT 可以满足高端 HT-PEHs 的要求,为开发在高温环境下工作的自供电无线传感器铺平了新的道路。
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来源期刊
Nano-Micro Letters
Nano-Micro Letters NANOSCIENCE & NANOTECHNOLOGY-MATERIALS SCIENCE, MULTIDISCIPLINARY
CiteScore
32.60
自引率
4.90%
发文量
981
审稿时长
1.1 months
期刊介绍: Nano-Micro Letters is a peer-reviewed, international, interdisciplinary, and open-access journal published under the SpringerOpen brand. Nano-Micro Letters focuses on the science, experiments, engineering, technologies, and applications of nano- or microscale structures and systems in various fields such as physics, chemistry, biology, material science, and pharmacy.It also explores the expanding interfaces between these fields. Nano-Micro Letters particularly emphasizes the bottom-up approach in the length scale from nano to micro. This approach is crucial for achieving industrial applications in nanotechnology, as it involves the assembly, modification, and control of nanostructures on a microscale.
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