Green hybrid composites partially reinforced with flax woven fabric and coconut shell waste-based micro-fillers

Abstract

This research is focused on hybrid green composites using flax woven fabric in which the matrix phase was further reinforced with coconut shell waste-based cellulosic microparticles as fillers. Mesoscale mechanical models were successfully developed to simulate the tensile properties of such hybrid composites based on hybridization of fibers and biobased materials using epoxy resin. S-glass fabrics with plain, twill and biaxial constructions, were used as the outer layers, while plain-woven flax fabric was used as the middle layer. A high level of agreement was observed between the experimental and predicted values. The static tensile tests were followed by cyclic tensile tests, microscopic analysis of fracture surfaces and dynamic mechanical analysis. The influence of the hybrid fabric geometry and combination with biowaste-based micro cellulosic material was observed to significantly influence the tensile properties determined by both experimental and numerical analysis. Dynamic mechanical analysis also validated the quasistatic measurements. A higher storage modulus and loss modulus were registered for the hybrid composites impregnated with a 1 % bio filler-based matrix. The damping factor (tan delta) was lower for the hybrid composites than for the nonhybrid samples and the control samples from the pure matrix. This difference is attributed to the stronger interface between the fibers and the particle-based matrix, which restricts the molecular mobility and increases the stiffness of the composites. Fractographic images were obtained by scanning electron microscopy (SEM) to study the failure modes and mechanisms of the composite samples. The microparticles were uniformly dispersed in the epoxy resin and thus enabled microcracking rather than macrocracks. The failure mainly occurred due to fiber failure, matrix cracking and delamination. Such hybrid composites are useful for exterior and interior components in automotive applications.