Bhabani Malakar , Sudip Bhattacharjee , Nhat Quang Minh Tran , Tan Le Hoang Doan , Thang Bach Phan , Sayantan Chongdar , Asim Bhaumik
{"title":"A new microporous organic–inorganic hybrid titanium phosphate for selective acetalization of glycerol†","authors":"Bhabani Malakar , Sudip Bhattacharjee , Nhat Quang Minh Tran , Tan Le Hoang Doan , Thang Bach Phan , Sayantan Chongdar , Asim Bhaumik","doi":"10.1039/d4cc04799k","DOIUrl":null,"url":null,"abstract":"<div><div>We developed a novel strategy for synthesizing a highly acidic microporous hybrid titanium phosphate material () by incorporating 5-aminosalicylic acid (5-ASA) into the titanium phosphate framework. This new serves as a Brønsted acid catalyst, exhibiting remarkable total surface acidity of 5.9 mmol g<sup>−1</sup> and it efficiently catalyzes the acetalization of abundant biomass derived glycerol to solketal with over 99% selectivity.</div></div>","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"61 1","pages":"Pages 81-84"},"PeriodicalIF":4.2000,"publicationDate":"2024-12-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Communications","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S1359734524025321","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
We developed a novel strategy for synthesizing a highly acidic microporous hybrid titanium phosphate material () by incorporating 5-aminosalicylic acid (5-ASA) into the titanium phosphate framework. This new serves as a Brønsted acid catalyst, exhibiting remarkable total surface acidity of 5.9 mmol g−1 and it efficiently catalyzes the acetalization of abundant biomass derived glycerol to solketal with over 99% selectivity.
期刊介绍:
ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.