Ana Cristina Ramirez-Gallardo, I. Garcia-Cruz, C. Lira-Galeana
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引用次数: 0
Abstract
A method to predict the gas/oil (GOC) and oil/tar (OTC) fluid contacts of reservoir fluid columns containing heavy fractions and asphaltenes is presented. A new formulation and solution to the gravitational equilibrium equations in terms of the method of moments, and the use of an equation of state for semicontinuous mixtures are shown to provide a robust and consistent method to describe the variation of pressure, reservoir fluid composition and heavy-ends molecular weights with depth, as well as the location of the fluid contacts of a petroleum reservoir. Use of the new method is first illustrated by locating the GOC of a (continuous) ideal reservoir described by Raoult´s law, and by predicting the GOC and OTC of two reservoir systems where measured data are available. The good agreement of the new method with measured gradients shows the adequacy of the proposed approach.
期刊介绍:
Fluid Phase Equilibria publishes high-quality papers dealing with experimental, theoretical, and applied research related to equilibrium and transport properties of fluids, solids, and interfaces. Subjects of interest include physical/phase and chemical equilibria; equilibrium and nonequilibrium thermophysical properties; fundamental thermodynamic relations; and stability. The systems central to the journal include pure substances and mixtures of organic and inorganic materials, including polymers, biochemicals, and surfactants with sufficient characterization of composition and purity for the results to be reproduced. Alloys are of interest only when thermodynamic studies are included, purely material studies will not be considered. In all cases, authors are expected to provide physical or chemical interpretations of the results.
Experimental research can include measurements under all conditions of temperature, pressure, and composition, including critical and supercritical. Measurements are to be associated with systems and conditions of fundamental or applied interest, and may not be only a collection of routine data, such as physical property or solubility measurements at limited pressures and temperatures close to ambient, or surfactant studies focussed strictly on micellisation or micelle structure. Papers reporting common data must be accompanied by new physical insights and/or contemporary or new theory or techniques.