Bio-calcium oxide derived from eggshell-titanium dioxide@graphene oxide for photodegradation of dyes and antibacterial activities

IF 3.1 3区 物理与天体物理 Q2 Engineering Optik Pub Date : 2024-10-28 DOI:10.1016/j.ijleo.2024.172099
{"title":"Bio-calcium oxide derived from eggshell-titanium dioxide@graphene oxide for photodegradation of dyes and antibacterial activities","authors":"","doi":"10.1016/j.ijleo.2024.172099","DOIUrl":null,"url":null,"abstract":"<div><div>The utilization of calcium oxide (CaO) derived from calcined eggshells is considered a primary source of materials for semiconductor incorporation, which is a facile and environmentally friendly method. This work introduces a novel composite, namely calcium oxide-titanium dioxide@graphene oxide (CaO-TiO<sub>2</sub>@GO) with photodegradation efficiency of various organic pollutants such as crystal violet (CV), malachite green (MG), rhodamine B (RhB), and methyl orange (MO). The results showed that the synergistic efficiency of the combination of GO and CaO-TiO<sub>2</sub> increased the adsorption-photodegradation efficiency with the removal of CV, MG, RhB, and MO of 99.72, 99.41, 97.21, and 80.09 %, respectively. The kinetics of dye photodegradation follows a pseudo-first-order kinetics model, the reusability toward CV removal reaches over 85 % after 5 cycles, and the free radical scavenging experiment identifies that the •O<sub>2</sub><sup>−</sup> plays a major role in the photodegradation mechanism. In addition, the fundamental antibacterial performance toward strains of <em>Pseudomonas aeruginosa</em> and <em>Bacillus subtilis</em> was reported with antibacterial inhibition diameters of 12.1 and 11.2 mm, respectively.</div></div>","PeriodicalId":19513,"journal":{"name":"Optik","volume":null,"pages":null},"PeriodicalIF":3.1000,"publicationDate":"2024-10-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Optik","FirstCategoryId":"101","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0030402624004984","RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"Engineering","Score":null,"Total":0}
引用次数: 0

Abstract

The utilization of calcium oxide (CaO) derived from calcined eggshells is considered a primary source of materials for semiconductor incorporation, which is a facile and environmentally friendly method. This work introduces a novel composite, namely calcium oxide-titanium dioxide@graphene oxide (CaO-TiO2@GO) with photodegradation efficiency of various organic pollutants such as crystal violet (CV), malachite green (MG), rhodamine B (RhB), and methyl orange (MO). The results showed that the synergistic efficiency of the combination of GO and CaO-TiO2 increased the adsorption-photodegradation efficiency with the removal of CV, MG, RhB, and MO of 99.72, 99.41, 97.21, and 80.09 %, respectively. The kinetics of dye photodegradation follows a pseudo-first-order kinetics model, the reusability toward CV removal reaches over 85 % after 5 cycles, and the free radical scavenging experiment identifies that the •O2 plays a major role in the photodegradation mechanism. In addition, the fundamental antibacterial performance toward strains of Pseudomonas aeruginosa and Bacillus subtilis was reported with antibacterial inhibition diameters of 12.1 and 11.2 mm, respectively.
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
蛋壳-二氧化钛@氧化石墨烯衍生的生物氧化钙在染料光降解和抗菌活性方面的应用
利用从煅烧蛋壳中提取的氧化钙(CaO)被认为是掺入半导体的主要材料来源,这是一种既简便又环保的方法。本研究介绍了一种新型复合材料,即氧化钙-二氧化钛@氧化石墨烯(CaO-TiO2@GO),其对多种有机污染物如水晶紫(CV)、孔雀石绿(MG)、罗丹明 B(RhB)和甲基橙(MO)具有光降解效率。结果表明,GO 和 CaO-TiO2 的组合协同增效提高了吸附-光降解效率,对 CV、MG、RhB 和 MO 的去除率分别为 99.72%、99.41%、97.21% 和 80.09%。染料光降解动力学遵循伪一阶动力学模型,5 次循环后去除 CV 的重复利用率达到 85% 以上,自由基清除实验表明 -O2- 在光降解机理中起主要作用。此外,该化合物还对铜绿假单胞菌和枯草芽孢杆菌菌株具有基本的抗菌性能,抑菌直径分别为 12.1 毫米和 11.2 毫米。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
Optik
Optik 物理-光学
CiteScore
6.90
自引率
12.90%
发文量
1471
审稿时长
46 days
期刊介绍: Optik publishes articles on all subjects related to light and electron optics and offers a survey on the state of research and technical development within the following fields: Optics: -Optics design, geometrical and beam optics, wave optics- Optical and micro-optical components, diffractive optics, devices and systems- Photoelectric and optoelectronic devices- Optical properties of materials, nonlinear optics, wave propagation and transmission in homogeneous and inhomogeneous materials- Information optics, image formation and processing, holographic techniques, microscopes and spectrometer techniques, and image analysis- Optical testing and measuring techniques- Optical communication and computing- Physiological optics- As well as other related topics.
期刊最新文献
Optimization of C-like sandwich wall structure for high microwave transmission Novel reddish-orange emitting BaBPO5:Eu3+ phosphor for n-UV warm white-LEDs: Synthesis and study of structural and spectroscopic investigations Study of complex instability in a Thulium-doped figure-eight fiber laser including a polarization-imbalanced NOLM with no polarization control. Holographic solar concentrator with wide band using multi-wavelength transmission grating Bio-calcium oxide derived from eggshell-titanium dioxide@graphene oxide for photodegradation of dyes and antibacterial activities
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1