Anatase/TiO2(B) Homojunction Nanosheets with Gold Cocatalyst for Direct Photocatalytic Coupling of Methane to Ethane

IF 4.3 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Chemical Communications Pub Date : 2024-11-06 DOI:10.1039/d4cc05090h
Xuanzhao Lu, Huanhuan Luo, Biyang Xu, Zhuo Liu, Yue Cao, Kai Li, Xiaohan Yang, Liangyiqun Xie, Tao Guan, Wenlei Zhu, Yang Zhou
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引用次数: 0

Abstract

Anatase/TiO2(B) homojunction loaded with Au nanoparticles was synthesized, achieving a C2H6 yield rate of 170 μmol g−1 h−1 in a flow photoreactor. The homojunction reduces TiO2(B)’s strong oxidative ability, offering a more moderate environment for methane dehydrogenation, while Au aids in charge mitigation and methyl radicals coupling. The catalyst highlights homojunction engineering and a ternary synergistic effect in photocatalytic CH4 coupling.
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带有金催化剂的 Anatase/TiO2(B) 均质纳米片用于甲烷与乙烷的直接光催化耦合
合成了负载金纳米粒子的 Anatase/TiO2(B) 同质结,在流动光反应器中实现了 170 μmol g-1 h-1 的 C2H6 产率。同质结合降低了 TiO2(B) 的强氧化能力,为甲烷脱氢提供了更温和的环境,而金则有助于电荷缓解和甲基自由基偶联。该催化剂突出了同质结工程和光催化甲烷耦合的三元协同效应。
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来源期刊
Chemical Communications
Chemical Communications 化学-化学综合
CiteScore
8.60
自引率
4.10%
发文量
2705
审稿时长
1.4 months
期刊介绍: ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.
期刊最新文献
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