{"title":"Enhancing cycling stability in Li-rich layered oxides by atomic layer deposition of LiNbO3 nanolayers","authors":"","doi":"10.1016/j.ssi.2024.116727","DOIUrl":null,"url":null,"abstract":"<div><div>Lithium-rich layered oxides (LROs), serving as high-energy cathode materials for lithium-ion batteries (LIBs), possess significant drawbacks that hinder their widespread use in practical applications. While surface modification can effectively shield LRO from structural degradation, precisely designing the surface structure remains a big challenge. This study focuses on the fabrication of uniform and thickness-controlled LiNbO<sub>3</sub>-coated nanostructures on the surface of LRO using the atomic layer deposition (ALD) technique. The LiNbO<sub>3</sub> nanostructures on the cathode surface not only bolster the structural and interfacial stability but also facilitate Li<sup>+</sup> diffusion, enhancing the cycling stability and the rate capability of LRO. Specifically, the LRO modified with a 3 nm thick LiNbO<sub>3</sub> layer exhibited better capacity retention of 86.4 % after 200 cycles at 1C with a voltage decay rate of 2.86 mV per cycle, and a reversible discharge capacity of 88.1 mAh g<sup>−1</sup> at 10C, underscoring the crucial role of surface nanostructures in enhancing electrochemical performance. This research sheds light on the strategic design of nanostructures at the grain surface of advanced cathode materials for high-performance LIBs.</div></div>","PeriodicalId":431,"journal":{"name":"Solid State Ionics","volume":null,"pages":null},"PeriodicalIF":3.0000,"publicationDate":"2024-11-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Solid State Ionics","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0167273824002753","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
Lithium-rich layered oxides (LROs), serving as high-energy cathode materials for lithium-ion batteries (LIBs), possess significant drawbacks that hinder their widespread use in practical applications. While surface modification can effectively shield LRO from structural degradation, precisely designing the surface structure remains a big challenge. This study focuses on the fabrication of uniform and thickness-controlled LiNbO3-coated nanostructures on the surface of LRO using the atomic layer deposition (ALD) technique. The LiNbO3 nanostructures on the cathode surface not only bolster the structural and interfacial stability but also facilitate Li+ diffusion, enhancing the cycling stability and the rate capability of LRO. Specifically, the LRO modified with a 3 nm thick LiNbO3 layer exhibited better capacity retention of 86.4 % after 200 cycles at 1C with a voltage decay rate of 2.86 mV per cycle, and a reversible discharge capacity of 88.1 mAh g−1 at 10C, underscoring the crucial role of surface nanostructures in enhancing electrochemical performance. This research sheds light on the strategic design of nanostructures at the grain surface of advanced cathode materials for high-performance LIBs.
期刊介绍:
This interdisciplinary journal is devoted to the physics, chemistry and materials science of diffusion, mass transport, and reactivity of solids. The major part of each issue is devoted to articles on:
(i) physics and chemistry of defects in solids;
(ii) reactions in and on solids, e.g. intercalation, corrosion, oxidation, sintering;
(iii) ion transport measurements, mechanisms and theory;
(iv) solid state electrochemistry;
(v) ionically-electronically mixed conducting solids.
Related technological applications are also included, provided their characteristics are interpreted in terms of the basic solid state properties.
Review papers and relevant symposium proceedings are welcome.