Understanding the nonlinear reactive transport model in porous catalysts

IF 1.3 4区 化学 Q4 ELECTROCHEMISTRY International Journal of Electrochemical Science Pub Date : 2024-10-24 DOI:10.1016/j.ijoes.2024.100852
D. Sujatha , R.Usha Rani , G. Vennila , A. Marimuthu , M. Renugadevi , L. Rajendran
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Abstract

This paper discusses the steady-state nonlinear reaction-diffusion processes in porous catalysts. This model is based on a nonlinear second-order differential equation that includes a nonlinear term associated with the Michaelis-Menten and non-Michaelis-Menten kinetics of the reaction. The nonlinear equations can be approximately solved using the Taylors series, modified Taylors series and Akabri-Ganji technique to obtain the concentration of dissolved species. The influence of the half-saturation parameter and the characteristic reaction rate on concentration is explored. Sensitivity analysis of parameters is discussed. Our analytical findings were compared with numerical solutions.
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了解多孔催化剂中的非线性反应迁移模型
本文讨论多孔催化剂中的稳态非线性反应-扩散过程。该模型基于一个非线性二阶微分方程,其中包括一个与反应的 Michaelis-Menten 和非 Michaelis-Menten 动力学相关的非线性项。非线性方程可以使用泰勒级数、修正泰勒级数和 Akabri-Ganji 技术近似求解,从而得到溶解物种的浓度。探讨了半饱和参数和特征反应速率对浓度的影响。讨论了参数的敏感性分析。我们将分析结果与数值解法进行了比较。
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来源期刊
CiteScore
3.00
自引率
20.00%
发文量
714
审稿时长
2.6 months
期刊介绍: International Journal of Electrochemical Science is a peer-reviewed, open access journal that publishes original research articles, short communications as well as review articles in all areas of electrochemistry: Scope - Theoretical and Computational Electrochemistry - Processes on Electrodes - Electroanalytical Chemistry and Sensor Science - Corrosion - Electrochemical Energy Conversion and Storage - Electrochemical Engineering - Coatings - Electrochemical Synthesis - Bioelectrochemistry - Molecular Electrochemistry
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