Synthesis and Photophysical and Electrochemical Properties of Conjugated Donor–Acceptor–Donor Systems Based on 1,3,4-Thiadiazole and Fused Naphtho[2,1-b]thiophene Derivatives

IF 0.8 4区 化学 Q4 CHEMISTRY, ORGANIC Russian Journal of Organic Chemistry Pub Date : 2024-11-07 DOI:10.1134/S1070428024090033
E. B. Uliankin, A. S. Kostyuchenko, A. S. Fisyuk
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Abstract

A series of 2,5-diaryl-1,3,4-thiadiazole derivatives have been synthesized from fused benzothio­phene-2-carboxylates and alkyl-substituted 2,2′-bithiophene-5-carboxylate. Photophysical and electrochemical properties of the synthesized compounds have been studied. Extension of the conjugation chain in the donor moiety of substituted 1,3,4-thiadiazoles has been found to narrow the energy band gap due mainly to increase of the HOMO energy.

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基于 1,3,4-噻二唑和融合萘并[2,1-b]噻吩衍生物的共轭供体-受体-供体系统的合成及其光物理和电化学性质
由熔融苯并噻吩-2-羧酸酯和烷基取代的 2,2′-噻吩-5-羧酸酯合成了一系列 2,5 二基-1,3,4-噻二唑衍生物。对合成化合物的光物理和电化学性质进行了研究。研究发现,取代的 1,3,4-噻二唑的供体分子中共轭链的延长会缩小能带隙,这主要是由于 HOMO 能量的增加。
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来源期刊
CiteScore
1.40
自引率
25.00%
发文量
139
审稿时长
3-6 weeks
期刊介绍: Russian Journal of Organic Chemistry is an international peer reviewed journal that covers all aspects of modern organic chemistry including organic synthesis, theoretical organic chemistry, structure and mechanism, and the application of organometallic compounds in organic synthesis.
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