Lu He , Jingxian Qin , Wanli Zhang , Weiwei Zhu , Jiang Li , Shaoyun Guo , Jiabin Shen
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引用次数: 0
Abstract
Membrane separation technology is a promising choice for treating oily water from industrial and domestic sewage. The elaborate design of pore structure can realize a good trade-off between separation flux and efficiency, thus taking the full advantages of membrane separation. Herein, polychlorotrifluoroethylene (PCTFE) microporous membrane with tunable pore structure was fabricated via a sacrificial template method. Fluoroelastomer (FR), serving as sacrificial template, was incorporated into PCTFE via a solvent-assisted method, forming PCTFE/FR blending films. After removing FR via solvent-dissolving, porous PCTFE membrane was obtained. More important, the gradual increment of FR loading made the morphology of PCTFE/FR blending films realize the transformation from “sea-island” to bicontinuous structure, thus endowing the membranes with tunable pore structure, surface wettability, as well as mechanical properties. Among the candidates, 50FR membranes possessed good flexibility, twist-resistance, as well as excellent creep-resistance and can efficiently separate oil from various water/oil mixtures. The oil (dichloromethane) permeability, separation efficiency, and filtrated oil purity were high up ∼10000 L/(m2⋅h), ∼99 %, and ∼99.92 wt%, respectively. Additionally, although undergoing 25 separation cycles or being immersed into various highly-corrosive liquid (including 1 M HCl, 1 M NaOH, DMF, ethanediamine, and concentrated HNO3) for 7 days, the properties of the membrane changed little. These features suggested a great potential for preparing PCTFE membranes used for oil/water separation in various harsh environment.
期刊介绍:
Polymer is an interdisciplinary journal dedicated to publishing innovative and significant advances in Polymer Physics, Chemistry and Technology. We welcome submissions on polymer hybrids, nanocomposites, characterisation and self-assembly. Polymer also publishes work on the technological application of polymers in energy and optoelectronics.
The main scope is covered but not limited to the following core areas:
Polymer Materials
Nanocomposites and hybrid nanomaterials
Polymer blends, films, fibres, networks and porous materials
Physical Characterization
Characterisation, modelling and simulation* of molecular and materials properties in bulk, solution, and thin films
Polymer Engineering
Advanced multiscale processing methods
Polymer Synthesis, Modification and Self-assembly
Including designer polymer architectures, mechanisms and kinetics, and supramolecular polymerization
Technological Applications
Polymers for energy generation and storage
Polymer membranes for separation technology
Polymers for opto- and microelectronics.