Superhydrophobicity With Self-Adaptive Water Pressure Resistance and Adhesion of Pistia Stratiotes Leaf

IF 6.7 1区 化学 Q1 CHEMISTRY, ANALYTICAL Analytical Chemistry Pub Date : 2024-11-12 DOI:10.1002/adma.202412702
Huijuan Shao, Dehui Wang, Jianing Song, Zhenxu Shi, Kun Yin, Yang Shen, Bowen Zhang, Luqing Xu, Junchang Guo, Jinlong Yang, Xu Deng
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Abstract

Superhydrophobic surfaces are promising for optimizing amphibious aircraft by minimizing water drag and adhesion. Achieving this involves ensuring these surfaces can resist high liquid pressure caused by deep water and fluid flow. Maximizing the solid-liquid contact area is a common strategy to improve liquid pressure resistance. However, this approach inevitably increases solid-liquid adhesion, making it challenging to guarantee a trade-off between the two wetting characteristics. Here, it is found that the Pistia stratiotes leaf exhibits superhydrophobicity with high water pressure resistance and low adhesion, attributed to its self-adaptive deformable microstructure with unique re-entrant features. Under pressure, these microstructures deform to increase the solid-liquid contact area, thereby enhancing water pressure resistance. The re-entrant features elevate the deformation threshold, enabling higher modulus microstructures to achieve adaptive response. This facilitates the recovery of deformed microstructures, restoring the air layer and maintaining low adhesion. Following these concepts, Pistia stratiotes leaf-inspired surfaces are fabricated, achieving an 183% improvement in water impact resistance and an ≈80% reduction in adhesion after overpressure compared to conventional superhydrophobic surfaces. The design principles inspired by Pistia stratiotes promise significant advancements in amphibious aircraft and other trans-media vehicles.

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具有自适应抗水压和附着力的超疏水性糙叶连翘叶片
超疏水表面可最大限度地减少水阻力和附着力,从而有望优化水陆两栖飞机。要实现这一目标,就必须确保这些表面能够抵抗深水和流体流动造成的高液体压力。最大化固液接触面积是提高抗液压力的常用策略。然而,这种方法不可避免地会增加固液粘附性,因此要保证在两种润湿特性之间进行权衡具有挑战性。在这里,研究人员发现,Pistia stratiotes 叶片具有高抗水压性和低粘附性的超疏水特性,这归功于其具有独特再入角特征的自适应可变形微结构。在压力作用下,这些微结构会发生形变,增加固液接触面积,从而提高抗水压能力。重入特征提高了变形阈值,使高模量微结构能够实现自适应响应。这有利于变形微结构的恢复,恢复空气层并保持低粘附性。根据这些概念,我们制造出了受石蕊叶启发的表面,与传统的超疏水表面相比,其抗水冲击性能提高了 183%,超压后的附着力降低了≈80%。受地肤叶启发的设计原理有望在水陆两栖飞机和其他跨媒体飞行器方面取得重大进展。
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来源期刊
Analytical Chemistry
Analytical Chemistry 化学-分析化学
CiteScore
12.10
自引率
12.20%
发文量
1949
审稿时长
1.4 months
期刊介绍: Analytical Chemistry, a peer-reviewed research journal, focuses on disseminating new and original knowledge across all branches of analytical chemistry. Fundamental articles may explore general principles of chemical measurement science and need not directly address existing or potential analytical methodology. They can be entirely theoretical or report experimental results. Contributions may cover various phases of analytical operations, including sampling, bioanalysis, electrochemistry, mass spectrometry, microscale and nanoscale systems, environmental analysis, separations, spectroscopy, chemical reactions and selectivity, instrumentation, imaging, surface analysis, and data processing. Papers discussing known analytical methods should present a significant, original application of the method, a notable improvement, or results on an important analyte.
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