Aleksandra Ziółkowska, Tomasz Kruczyński, Dietrich Gudat and Łukasz Ponikiewski
{"title":"Phosphanylphosphaalkenes as precursors for metallaphosphaalkene complexes†","authors":"Aleksandra Ziółkowska, Tomasz Kruczyński, Dietrich Gudat and Łukasz Ponikiewski","doi":"10.1039/D4DT03012E","DOIUrl":null,"url":null,"abstract":"<p >We synthesized phosphanylphosphaalkenes (biph)<small><sub>2</sub></small>C<img>P-P(<em>t</em>Bu)<small><sub>2</sub></small> (<strong>2</strong>), Ph<small><sub>2</sub></small>C<img>P-P(NEt<small><sub>2</sub></small>)<small><sub>2</sub></small> (<strong>3</strong>), and (biph)<small><sub>2</sub></small>C<img>P-P(NEt<small><sub>2</sub></small>)<small><sub>2</sub></small> (<strong>4</strong>). The diaminophosphanyl derivatives reversibly dimerize head-to-head and react with a ruthenium complex, leading to P–P bond activation and the formation of a bridging phospaalkene complex under mild conditions.</p>","PeriodicalId":71,"journal":{"name":"Dalton Transactions","volume":" 48","pages":" 19107-19111"},"PeriodicalIF":3.3000,"publicationDate":"2024-11-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Dalton Transactions","FirstCategoryId":"92","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2024/dt/d4dt03012e","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
Abstract
We synthesized phosphanylphosphaalkenes (biph)2CP-P(tBu)2 (2), Ph2CP-P(NEt2)2 (3), and (biph)2CP-P(NEt2)2 (4). The diaminophosphanyl derivatives reversibly dimerize head-to-head and react with a ruthenium complex, leading to P–P bond activation and the formation of a bridging phospaalkene complex under mild conditions.
期刊介绍：
Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
