Aleksandra Ziółkowska, Tomasz Kruczyński, Dietrich Gudat, Łukasz Ponikiewski
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引用次数: 0
Abstract
We synthesized phosphanylphosphaalkenes (biph)₂C=P-P(tBu)₂ (2), Ph₂C=P-P(NEt₂)₂ (3), and (biph)₂C=P-P(NEt₂)₂ (4). The diaminophosphanyl derivatives reversibly dimerize head-to-head and react with a ruthenium complex, leading to P-P bond activation and the formation of a bridging phospaalkene complex under mild condictions.
期刊介绍：
Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.
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