{"title":"Exploring the catalytic performance of recyclable zinc indium sulfide in polymer synthesis: Well-controlled photoATRP of acrylates","authors":"Jianmin Fu, Xiaoxia Liu, Zichen Wu, Donglei Wei, Hou Chen, Liangjiu Bai, Wenxiang Wang, Huawei Yang, Lixia Yang","doi":"10.1016/j.polymer.2024.127828","DOIUrl":null,"url":null,"abstract":"<div><div>Zinc indium sulfide has been used as a heterogeneous recyclable photocatalyst in visible light-induced atom transfer radical polymerization (ATRP). The photocatalyst was found to catalyze ATRP via an oxidative quenching mechanism without any additives. Polymers in high conversion and good control can be obtained. The kinetic study, light on/off experiment and the block copolymer synthesis showed the “living”/controlled nature of the polymerization. The photocatalyst can be reused for five times without obvious loss of control in the polymerization. Metal residue was not detected in the resulting polymers. This strategy provides a noval way for well-controlled polymer synthesis using recyclable visible light photocatalysis.</div></div>","PeriodicalId":405,"journal":{"name":"Polymer","volume":"315 ","pages":"Article 127828"},"PeriodicalIF":4.1000,"publicationDate":"2024-11-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymer","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0032386124011649","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
引用次数: 0
Abstract
Zinc indium sulfide has been used as a heterogeneous recyclable photocatalyst in visible light-induced atom transfer radical polymerization (ATRP). The photocatalyst was found to catalyze ATRP via an oxidative quenching mechanism without any additives. Polymers in high conversion and good control can be obtained. The kinetic study, light on/off experiment and the block copolymer synthesis showed the “living”/controlled nature of the polymerization. The photocatalyst can be reused for five times without obvious loss of control in the polymerization. Metal residue was not detected in the resulting polymers. This strategy provides a noval way for well-controlled polymer synthesis using recyclable visible light photocatalysis.
期刊介绍：
Polymer is an interdisciplinary journal dedicated to publishing innovative and significant advances in Polymer Physics, Chemistry and Technology. We welcome submissions on polymer hybrids, nanocomposites, characterisation and self-assembly. Polymer also publishes work on the technological application of polymers in energy and optoelectronics.
The main scope is covered but not limited to the following core areas:
Polymer Materials
Nanocomposites and hybrid nanomaterials
Polymer blends, films, fibres, networks and porous materials
Physical Characterization
Characterisation, modelling and simulation* of molecular and materials properties in bulk, solution, and thin films
Polymer Engineering
Advanced multiscale processing methods
Polymer Synthesis, Modification and Self-assembly
Including designer polymer architectures, mechanisms and kinetics, and supramolecular polymerization
Technological Applications
Polymers for energy generation and storage
Polymer membranes for separation technology
Polymers for opto- and microelectronics.
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