Leaftronics: Natural lignocellulose scaffolds for sustainable electronics

IF 11.7 1区 综合性期刊 Q1 MULTIDISCIPLINARY SCIENCES Science Advances Pub Date : 2024-11-08 DOI:10.1126/sciadv.adq3276
Rakesh R. Nair, Jakob Wolansky, Kai Uhlig, Ali Solgi, Laura Teuerle, Tianyi Zhang, Jonas Schröder, Tobias Antrack, Johannes Benduhn, Hans Kleemann, Karl Leo
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Abstract

The global rise in electronic waste is alarming, driven by the persistent use of glass, epoxy, and plastic substrates owing to their cost, stability, flexibility, and transparency. This underscores the need for biodegradable alternatives with similar properties. This study shows that leaf-derived lignocellulose scaffolds can stabilize bio-sourced, solution-processed polymers by acting as natural sequestering media. Such reinforced films, even when based on gelatin (Tg ~ 60°C), can endure processes over 200°C. We demonstrate dip-coated ethyl cellulose films for commercially viable reflow soldered circuitry. The films offer high flexibility, more than 80% transparency, and surface roughness below 5.5 nm. Advanced OPDs and OECTs fabricated on these films perform comparably to those on glass and the low material cost and simple fabrication process yields a minimal carbon footprint of 1.6 kgCO2/m2. This work thus opens a vista of possibilities for biodegradable polymers heretofore considered unsuitable for making temperature-stable substrates for state-of-the-art electronics applications.
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叶电子学:用于可持续电子产品的天然木质纤维素支架。
由于玻璃、环氧树脂和塑料基底材料的成本、稳定性、灵活性和透明度,这些材料的持续使用导致全球电子废弃物的增加令人担忧。这凸显了对具有类似特性的可生物降解替代品的需求。本研究表明,源自树叶的木质纤维素支架可作为天然固存介质,稳定生物来源的溶液加工聚合物。即使是基于明胶(Tg ~ 60°C)的增强薄膜,也能承受 200°C 以上的加工温度。我们展示了用于商业化回流焊接电路的浸涂乙基纤维素薄膜。这种薄膜具有很高的柔韧性,透明度超过 80%,表面粗糙度低于 5.5 nm。在这些薄膜上制造的先进 OPD 和 OECT 的性能与在玻璃上制造的不相上下,而且材料成本低、制造工艺简单,产生的碳足迹最小,仅为 1.6 kgCO2/m2。因此,这项工作为生物可降解聚合物开辟了一条新的可能性之路,因为在此之前,生物可降解聚合物一直被认为不适合用于制造温度稳定的基底,而这种基底可用于最先进的电子应用。
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来源期刊
Science Advances
Science Advances 综合性期刊-综合性期刊
CiteScore
21.40
自引率
1.50%
发文量
1937
审稿时长
29 weeks
期刊介绍: Science Advances, an open-access journal by AAAS, publishes impactful research in diverse scientific areas. It aims for fair, fast, and expert peer review, providing freely accessible research to readers. Led by distinguished scientists, the journal supports AAAS's mission by extending Science magazine's capacity to identify and promote significant advances. Evolving digital publishing technologies play a crucial role in advancing AAAS's global mission for science communication and benefitting humankind.
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