Genesis and Accumulation Modes of Coalbed Methane at the Eastern Margin of Ordos Basin, China: Evidence from Its Geochemistry

IF 4.3 3区 材料科学 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC ACS Applied Electronic Materials Pub Date : 2024-10-30 DOI:10.1021/acsomega.4c0741610.1021/acsomega.4c07416
Zhanwei Li, Shida Chen*, Dazhen Tang and Yuanhao Zhi, 
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Abstract

The genesis, occurrence, and accumulation of coalbed methane (CBM) are critical to the methane exploration and development. Combining the geological and geochemical data from CBM exploration wells and basin modeling, the genesis and accumulation characteristics of CBM in different regions and depths at the eastern margin of Ordos Basin were elucidated. Regional-scale gas content is controlled by depth and coal rank without turning depth occurs, but blocks perform variably. Three CBM genetic types, that is, secondary microbial, thermogenic, and mixed genesis, were identified based on data of gas components and isotopic composition. Under the influences of tectonic and hydrogeological conditions, secondary microbial gas is widely distributed in shallow coal seams (depth <1350 m) showing mixed gas characteristics, while secondary thermogenic gas dominates in deep coal seams. The extensive variations of carbon isotope of methane raised from desorption–diffusion induced by tectonic uplift, dissolution in flowing groundwater, secondary microbial gas generation, and rapid gas generation enhanced by magmatic thermal. Three CBM accumulation modes have been concluded depending on the depth and coal rank. The Baode mode is characterized by a high-ratio secondary microbial gas replenishment, typically occurring at lower ranks and shallow depths. The Linxing mode is distinguished by magmatic thermal influences, and the Daji mode features massive secondary thermogenetic gas associated with higher ranks and deeper depths. Every mode has the potential to form high-gas-content zones.

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中国鄂尔多斯盆地东缘煤层气的成因和聚集模式:地球化学证据
煤层气的成因、赋存和积聚是煤层气勘探开发的关键。结合煤层气探井的地质和地球化学资料以及盆地建模,阐明了鄂尔多斯盆地东缘不同区域、不同深度煤层气的成因和积聚特征。区域尺度的含气量受深度和煤层等级的控制,不会出现深度转折,但区块表现各异。根据气体成分和同位素组成数据,确定了三种煤层气成因类型,即次生微生物成因、热成因和混合成因。受构造和水文地质条件的影响,次生微生物气广泛分布于浅煤层(深度 1350 米),呈现混合气特征,而次生热成气在深煤层中占主导地位。构造抬升引起的解吸扩散、流动地下水的溶解、次生微生物瓦斯生成以及岩浆热作用下的快速瓦斯生成,导致了甲烷碳同位素的广泛变化。根据煤层深度和煤层等级,总结出三种煤层气积聚模式。宝德模式的特点是高比例的二次微生物瓦斯补充,通常发生在较低的层位和较浅的深度。临兴模式以岩浆热影响为特征,而达吉模式则以大量二次热生瓦斯为特征,与较高的层位和较深的深度相关。每种模式都有可能形成高含气区。
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CiteScore
7.20
自引率
4.30%
发文量
567
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