Impact of hydrochar in stabilization/solidification of heavy metal-contaminated soil with Portland cement.

Abstract

Stabilization/Solidification (S/S) using Portland cement is a common soil remediation technique for heavy metal-contaminated sites. However, due to the hindrance of cement hydration by heavy metals (HMs) and the high CO₂ emissions from cement production, efforts have been made to reduce cement consumption. Supplementary cementitious materials (SCMs) present an efficient alternative for this purpose. This study investigates the impact of hydrochar and modified hydrochar as SCMs for remediating soils contaminated with Zn, Pb, and Cd. Forty treated soil samples were evaluated using unconfined compressive strength (UCS), pH, Toxicity characteristic leaching procedure (TCLP), and sequential extraction procedure (SEP) tests, and statistical analysis was conducted to assess the effects of binder content, hydrochar dosage, and hydrochar type. Results show that substituting cement with hydrochar or modified hydrochar reduces UCS by 10-40%, with hydrochar having a greater negative impact than modified hydrochar. pH values ranged from 6.98 to 12.64, facilitating HMs precipitation. In heavily contaminated samples, hydrochar or modified hydrochars significantly decreased the Zn, Pb, and Cd TCLP values by 55%, 63%, and 50%, respectively. In moderately contaminated samples, the reduction was slight for Zn and Pb, with no significant change for Cd. SEP test results indicated that hydrochar or modified hydrochar in cement improves the transformation of the acid-soluble fraction to the residual fraction of Zn and Pb, but not for Cd-contaminated soil samples. Overall, these findings suggest that incorporating hydrochar or modified hydrochar as SCMs in cement contributes to reducing cement usage and CO₂ emissions while enhancing the stabilization efficiency of certain heavy metals in contaminated soils.