Unravelling the Synthesis of 2-Aminobenzo[d]thiazole Derivatives via a Novel Zinc(II)-Catalyzed Strategy

IF 2.3 4区 化学 Q3 CHEMISTRY, PHYSICAL Catalysis Letters Pub Date : 2024-11-13 DOI:10.1007/s10562-024-04835-3
Mohan Neetha, S. B. Umabharathi, Gopinathan Anilkumar
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Abstract

The first zinc(II)-catalyzed approach towards an array of 2-aminobenzothiazole derivatives was successfully developed. In this process, the substrate 2-bromophenyl isothiocyanate was reacted with a range of amines, including aromatic and aliphatic (primary and secondary) and cyclic secondary amines, yielding the products in reasonably good amounts. The reactivity analyses of different amines revealed that cyclic secondary amines performed exceptionally well, providing excellent outcomes. Additionally, aliphatic amines also exhibited the capability to undergo the transformation successfully.

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通过新型锌(II)催化策略揭示 2-氨基苯并[d]噻唑衍生物的合成过程
首次成功开发出锌(II)催化的 2-氨基苯并噻唑衍生物系列。在这一过程中,底物 2-溴苯基异硫氰酸酯与一系列胺类(包括芳香族和脂肪族(伯胺和仲胺)以及环状仲胺)发生反应,以合理的数量生成产物。对不同胺类的反应性分析表明,环状仲胺的反应性特别好,能产生极佳的结果。此外,脂肪族胺也表现出了成功进行转化的能力。
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来源期刊
Catalysis Letters
Catalysis Letters 化学-物理化学
CiteScore
5.70
自引率
3.60%
发文量
327
审稿时长
1 months
期刊介绍: Catalysis Letters aim is the rapid publication of outstanding and high-impact original research articles in catalysis. The scope of the journal covers a broad range of topics in all fields of both applied and theoretical catalysis, including heterogeneous, homogeneous and biocatalysis. The high-quality original research articles published in Catalysis Letters are subject to rigorous peer review. Accepted papers are published online first and subsequently in print issues. All contributions must include a graphical abstract. Manuscripts should be written in English and the responsibility lies with the authors to ensure that they are grammatically and linguistically correct. Authors for whom English is not the working language are encouraged to consider using a professional language-editing service before submitting their manuscripts.
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