Thermobarrier and antifriction properties of triboceramics on the surface of a cutting tool with (TiAlCrSiY)N/(TiAlCr)N coating during high-speed dry cutting

IF 0.8 4区 材料科学 Q4 METALLURGY & METALLURGICAL ENGINEERING Metallurgist Pub Date : 2024-11-08 DOI:10.1007/s11015-024-01809-z
A. I. Kovalev, D. L. Wainstein, E. P. Konovalov, V. O. Vakhrushev, S. A. Dmitrievskii, A. A. Tomchuk
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Abstract

The physical mechanism of self-organization of a multilayer nanolaminated coating based upon non-equilibrium (TiAlCrSiY)N/(TiAlCr)N nitride on a cutting tool during high-speed (600 m/min.) dry cutting of N13 steel is established. Using a set of modern surface analysis methods coating degradation and tribo-oxidation are studied within the running-in and steady stages of wear. It is shown that during cutting, amorphous-nanocrystalline films of oxides similar to Cr2O3, TiO2, Al2O3 (sapphire) and Al2O3 · 2 (SiO2) (mullite) are formed within a wear crater. Using computer calculations by a finite element method, heat transfer is considered in the cutting zone during formation of protective tribo-oxides. It is found that among all tribo-oxides, mullite has the best thermal barrier properties. Oxidation is the main adaptation mechanism of a cutting tool under extreme mechanical and thermal shock during high-speed cutting. The topography of chip contact surface is studied at various cutting stages, which makes it possible to establish a change in plastic deformation mechanisms of treated metal and friction cutting modes. Quantum chemical calculations of the electron structure of mullite show the highest degree of its electron polarization and explain the radical drop in friction coefficient during film formation upon a wear surface. In this case, mullite acts as a solid lubricant.

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带 (TiAlCrSiY)N/(TiAlCr)N 涂层的切削工具表面摩擦陶瓷在高速干切削过程中的隔热性能和抗摩擦性能
在对 N13 钢进行高速(600 米/分钟)干切削时,建立了切削工具上基于非平衡 (TiAlCrSiY)N/(TiAlCr)N 氮化物的多层纳米层状涂层的自组织物理机制。利用一套现代表面分析方法,研究了磨损的磨合期和稳定期的涂层降解和三氧化反应。结果表明,在切削过程中,类似 Cr2O3、TiO2、Al2O3(蓝宝石)和 Al2O3 - 2 (SiO2) (莫来石) 的氧化物的非晶-纳米晶薄膜会在磨损坑内形成。通过有限元法的计算机计算,考虑了保护性三氧化物形成过程中切削区的传热问题。结果发现,在所有三氧化物中,莫来石的热障性能最好。在高速切削过程中,氧化是切削工具在极端机械和热冲击下的主要适应机制。通过对不同切削阶段切屑接触面形貌的研究,可以确定被处理金属的塑性变形机制和摩擦切削模式的变化。对莫来石电子结构的量子化学计算显示了其电子极化的最高程度,并解释了在磨损表面形成薄膜时摩擦系数急剧下降的原因。在这种情况下,莫来石起到了固体润滑剂的作用。
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来源期刊
Metallurgist
Metallurgist 工程技术-冶金工程
CiteScore
1.50
自引率
44.40%
发文量
151
审稿时长
4-8 weeks
期刊介绍: Metallurgist is the leading Russian journal in metallurgy. Publication started in 1956. Basic topics covered include: State of the art and development of enterprises in ferrous and nonferrous metallurgy and mining; Metallurgy of ferrous, nonferrous, rare, and precious metals; Metallurgical equipment; Automation and control; Protection of labor; Protection of the environment; Resources and energy saving; Quality and certification; History of metallurgy; Inventions (patents).
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