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Preliminary study of the technology of vacuum-thermal production of low-carbon ferrochrome 真空热法生产低碳铬铁技术的初步研究
IF 0.9 4区 材料科学 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-06-21 DOI: 10.1007/s11015-024-01729-y
A. I. Volkov, P. E. Stulov, A. F. Charkin, V. P. Panfilov, N. Z. Nurgali, I. A. Krasnyanskaya, M. M. Kospanov, I. I. Masgutov, S. V. Pozharov

In this study, existing and promising methods of processing fine fractions and dust of aspiration systems for the production of ferroalloys were analyzed. The technological properties of high-carbon ferrochrome screenings and dust of the ferrochrome crushing aspiration system of the Aktobe Ferroalloy Plant as raw materials for the production of low-carbon ferrochrome briquettes using the vacuum-thermal method were studied. The contents of basic and impurity elements, including gas-forming ones, were determined. The oxygen content in the dust reached 4.2 and 0.12% in the screening. The average size of aspiration dust particles was 9.6 μm, whereas that of the ferrochrome screenings was 1.44 mm. In the dust and screening samples, the main phase was Cr7C3, and graphite was present in the dust sample. During thermal analysis, the dust sample completely melted at 1453 °C, and a liquid phase was not observed when ferrochrome was heated. At 1340 °C, the formation of iron silicide was noted. With increasing temperature, the concentrations of carbon and chromium carbide decreased. From thermodynamic calculations, recommendations were given on the parameters of vacuum-thermal decarburization of high-carbon ferrochrome. The results of preliminary experiments confirmed the possibility of removing carbon from screenings and aspiration dust. From samples containing 9.04–9.11% carbon, ferrochrome with a content of 0.10% carbon could be obtained. At the next stage of our work, we plan to work out in detail the parameters affecting the vacuum-heat treatment of ferrochrome. We assume that ferrochrome with a carbon content of 0.00x% can be obtained.

在这项研究中,分析了用于生产铁合金的吸风系统的细馏分和粉尘的现有和有前途的加工方法。研究了阿克托别铁合金厂铬铁破碎吸风系统的高碳铬铁筛分物和粉尘的技术特性,作为使用真空-热法生产低碳铬铁压块的原料。测定了基本元素和杂质元素(包括气体形成元素)的含量。粉尘中的氧含量达到 4.2%,筛选中的氧含量为 0.12%。吸入粉尘颗粒的平均大小为 9.6 μm,而铬铁筛分物的平均大小为 1.44 mm。在粉尘和筛分样品中,主要相为 Cr7C3,粉尘样品中存在石墨。在热分析过程中,粉尘样品在 1453 °C时完全熔化,加热铬铁时未观察到液相。在 1340 ℃ 时,发现形成了硅化铁。随着温度升高,碳和碳化铬的浓度降低。通过热力学计算,对高碳铬铁的真空热脱碳参数提出了建议。初步实验结果证实了从筛分和吸尘中去除碳的可能性。从含碳量为 9.04-9.11% 的样品中可以获得含碳量为 0.10% 的铬铁。在下一阶段的工作中,我们计划详细研究影响铬铁真空热处理的参数。我们假设可以获得碳含量为 0.00x% 的铬铁。
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引用次数: 0
Ligature synthesis by aluminothermic reduction of ytterbium oxide with the formation of nanoscale intermetallides 通过铝热还原氧化镱合成配位体并形成纳米级金属间化合物
IF 0.9 4区 材料科学 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-06-21 DOI: 10.1007/s11015-024-01709-2
V. Yu. Bazhin, S. S. Demidov, V. A. Slobodin

As part of the development of critical technologies, it is necessary to search for alternative replacement of components in the compositions of aluminum ligatures, including known modifying additives of scandium and yttrium with other rare-earth and rare elements. Aluminum ligatures with rare-earth metals are widely considered in many scientific papers, but the research on the production of Al-Yb ligatures is limited. In this paper, the authors describe the results of studying the production of ligatures of the aluminum-ytterbium system from ytterbium oxide by aluminothermic reduction, containing nanoscale Al3Yb intermetallic compounds and eutectics in their structure. Serving as crystallization centers, the optimal-size particles of intermetallic compounds provide uniform fine-grained structure in aluminum alloy castings. The relationship has been obtained that enables the maximum transition of ytterbium into the alloy depending on the quantitative and qualitative composition of the reaction mixture and various melting process parameters. The conducted studies have shown that ligatures obtained by aluminothermic reduction of ytterbium oxide with the addition of 5 to 15 wt. % Mg to the reaction mixture have the highest characteristic of ytterbium transition into the ligature.

作为关键技术发展的一部分,有必要在铝韧带成分中寻找替代成分,包括已知的钪和钇与其他稀土和稀有元素的改性添加剂。在许多科学论文中,人们都广泛地考虑了含有稀土金属的铝韧带,但有关铝镱韧带生产的研究却很有限。在本文中,作者介绍了通过铝热还原法从氧化镱制备铝镱系络合物的研究成果,络合物结构中含有纳米级 Al3Yb 金属间化合物和共晶。作为结晶中心,金属间化合物的最佳尺寸颗粒为铝合金铸件提供了均匀的细粒结构。根据反应混合物的定量和定性成分以及不同的熔化工艺参数,得出了镱在合金中最大转化率的关系。研究表明,通过铝热还原氧化镱,并在反应混合物中添加 5 至 15 wt.
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引用次数: 0
Upgrade of the mechatronic rolls positioning system of the piercing mill 升级穿孔机的机电一体化轧辊定位系统
IF 0.9 4区 材料科学 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-06-21 DOI: 10.1007/s11015-024-01726-1
A. V. Tsukanov, K. V. Litsin, S. N. Baskov

An analysis of the operation of the piercing mill revealed the need to upgrade the mechatronic rolls positioning system and to introduce an intelligent system to improve the quality of rolled products. The main problem is the formation of defects at the ends of the shells during rolling on a piercing mill. The excess material must be cut off and recycled because more raw materials than required are used for rolling one billet. To eliminate this problem, it is necessary to change the preload of the workpiece during rolling, thereby forming a profile that reduces the undesirable changes at the ends of rolled pipes. The mill currently has foreign equipment which is difficult to purchase. Such difficulties may lead to downtime. Moreover, the unit operates only in manual or semi-automatic mode. The possibility of replacing equipment with domestic analogs is considered. A visualization and control program has been developed. To determine the position of the workpiece in the mill and change the preload of the shell in automatic mode, a neural-network control system has been developed.

对穿孔轧机运行情况的分析表明,有必要对机电一体化轧辊定位系统进行升级,并引入智能系统,以提高轧制产品的质量。主要问题是穿孔轧机在轧制过程中在坯壳两端形成缺陷。由于轧制一个钢坯所使用的原材料超过了所需的数量,因此必须将多余的材料切断并回收利用。为了消除这个问题,有必要在轧制过程中改变工件的预紧力,从而形成一个轮廓,减少轧制管材端部的不良变化。该轧机目前使用的是难以购买的外国设备。这些困难可能会导致停机。此外,设备只能以手动或半自动模式运行。考虑用国内类似设备替代的可能性。开发了一个可视化和控制程序。为了确定工件在轧机中的位置,并在自动模式下改变外壳的预紧力,开发了一个神经网络控制系统。
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引用次数: 0
Investigation of the influence of vibration on the processes of porous magnesium products formation 振动对多孔镁产品形成过程影响的研究
IF 0.9 4区 材料科学 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-06-21 DOI: 10.1007/s11015-024-01711-8
A. I. Kovtunov, Yu. Yu. Khokhlov, P. N. Selyanin

Magnesium foam is a promising material in industry and medicine due to its low density, high damping properties, ability to absorb acoustic and electromagnetic vibrations, and biocompatibility with the human body. The methods developed for producing products from porous magnesium by filtering the liquid melt through soluble granules ensure the production of porous magnesium with a pore size of at least 4 mm. To reduce the pore size by increasing the fluidity and fillability of the granular filling during the production of porous magnesium, vibration treatment of the melt during pouring has been proposed. The conducted studies have shown that vibration treatment allows increasing the fluidity of the Mg90 magnesium melt. In addition, a refinement of the magnesium structure and an increase in hardness are observed. Vibration treatment during the pouring and forming of porous magnesium contributes to an increase in the depth of impregnation of the granular filling and creates conditions for producing products from porous magnesium with a pore size of up to 2 mm, a density of 0.55–0.75 g/cm3, and a porosity of 57–68%.

泡沫镁具有密度低、阻尼性能高、吸收声波和电磁振动的能力以及与人体的生物相容性等特点,是一种很有前途的工业和医学材料。通过可溶性颗粒过滤液体熔体来生产多孔镁产品的方法可确保生产出孔径至少为 4 毫米的多孔镁。为了在多孔镁的生产过程中通过增加颗粒填充物的流动性和可填充性来减小孔径,有人建议在浇注过程中对熔体进行振动处理。研究表明,振动处理可以增加 Mg90 镁熔体的流动性。此外,还观察到镁结构的细化和硬度的增加。多孔镁在浇注和成型过程中的振动处理有助于增加颗粒填充物的浸渍深度,并为生产孔隙大小达 2 毫米、密度为 0.55-0.75 克/立方厘米、孔隙率为 57-68% 的多孔镁产品创造了条件。
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引用次数: 0
Weldability of aluminum alloys based upon the Al–Ca–Zn–Mg system 基于 Al-Ca-Zn-Mg 系的铝合金的焊接性
IF 0.9 4区 材料科学 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-06-21 DOI: 10.1007/s11015-024-01718-1
V. V. Ovchinnikov, T. K. Akopyan, A. G. Sbitnev, D. A. Polyakov

Based upon calculated data compositions of experimental aluminum alloys, which are characterized by the lowest tendency towards hot brittleness during casting, are selected. Sheets 2.5 mm thick are obtained from ingots of experimental alloys by hot rolling. It is shown that weldability of the Al–1Ca–5.5Zn–1.5Mg–0.5Mn alloy is at the level of that for serial alloy 1915. Analysis of the obtained data shows that cracking characteristics of the Al–2Ca–2.5Mg–0.4Mn alloy (alloy 2) (specimen cracking coefficient and critical deformation rate) are at a level corresponding to AMg3 alloy. The alloys studied with appropriate surface preparation are not prone to pore formation during fusion welding. Mechanical properties of joints of the alloys studied during argon-arc and plasma welding are determined.

根据计算数据,选择了实验铝合金的成分,这些成分的特点是在铸造过程中热脆性最小。通过热轧从实验合金铸锭中获得厚度为 2.5 毫米的板材。结果表明,Al-1Ca-5.5Zn-1.5Mg-0.5Mn 合金的可焊性达到了系列合金 1915 的水平。对所得数据的分析表明,Al-2Ca-2.5Mg-0.4Mn 合金(合金 2)的开裂特性(试样开裂系数和临界变形率)达到了 AMg3 合金的水平。所研究的合金经过适当的表面处理后,在熔焊过程中不易形成气孔。测定了所研究的合金在氩弧焊和等离子焊接过程中接头的机械性能。
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引用次数: 0
Layered synthesis of workpieces by mig-pulse surface method using austenitic metal-cored wire with nitrogen 使用含氮奥氏体金属芯焊丝的迁移-脉冲表面法分层合成工件
IF 0.9 4区 材料科学 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-06-20 DOI: 10.1007/s11015-024-01710-9
A. S. Smolentsev, A. V. Berezovsky, D. N. Trushnikov, G. L. Permyakov, V. E. Veselova, A. V. Shak, E. A. Usoltsev

WAAM technology (Wire + Arc Additive Manufacture) is a new method of additive manufacturing using wire as a construction material. The high productivity of the process, the ability to construct large-sized products without the need to use a controlled atmosphere chamber, and the low cost of equipment and construction materials allow using the WAAM technology to built products of simple and medium complexity with the highest economic efficiency. However, WAAM technologies in MIG-Pulse/CMT surfacing processes have a number of disadvantages, such as significant size of the heat-affected zone (HAZ) and large sizes of the build-up layer, which leads to undesirable temperature gradients and the accumulation of residual stresses. A further way to improve WAAM technology is to use metal-cored wires. For the research, metal-cored wire Cr20Mn5Ni4Mo2.5Cu3N0.3 Ø 1.6 mm was developed. It has been established that the use of metal-cored wire allows producing a defect-free surfaced metal with an austenite-ferritic structure (δF ≈ 1–3%), which has high strength and plastic characteristics (σB = 810 MPa, σ0,2 = 500 MPa, δ = 40%). The yield strength of the developed composition is more than 2 times higher than that of the widespread austenitic steel of the Kh18N10T type (σ0,2 = 206 MPa). Further research will be aimed at improving the impact strength of the surfaced cast metal by optimizing the composition of the metal-cored wire.

WAAM 技术(线材+电弧增材制造)是一种使用线材作为结构材料的新型增材制造方法。该工艺生产率高,无需使用可控气氛室即可制造大型产品,设备和建筑材料成本低,因此使用 WAAM 技术可以制造出简单和中等复杂程度的产品,经济效益最高。然而,MIG-脉冲/CMT 堆焊工艺中的 WAAM 技术也存在一些缺点,例如热影响区(HAZ)尺寸较大,堆积层尺寸较大,从而导致不理想的温度梯度和残余应力的积累。改进 WAAM 技术的另一个方法是使用金属芯线。研究开发了直径为 1.6 毫米的 Cr20Mn5Ni4Mo2.5Cu3N0.3 金属芯线。研究表明,使用金属芯线材可以生产出表面无缺陷的金属,这种金属具有奥氏体-铁素体结构(δF ≈ 1-3%),具有很高的强度和塑性(σB = 810 兆帕,σ0,2 = 500 兆帕,δ = 40%)。所开发成分的屈服强度比 Kh18N10T 类型的普通奥氏体钢(σ0,2 = 206 兆帕)高出 2 倍多。进一步研究的目标是通过优化金属芯线的成分来提高表面铸造金属的冲击强度。
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引用次数: 0
Information-modeling system for monitoring heat losses in the lower part of a blast furnace 用于监测高炉下部热损失的信息建模系统
IF 0.9 4区 材料科学 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-06-20 DOI: 10.1007/s11015-024-01721-6
N. A. Spirin, I. A. Gurin, V. V. Lavrov, A. S. Istomin, L. A. Zaynullin

The article presents a structure of the algorithm and mathematical and software systems. The general characteristics of the algorithm for determining heat losses in the hearth of a blast furnace based on the use of the heat balance of the lower zone are presented. External heat losses in the process of melting occurring through the tuyere belt, barrel, and bosh, are determined by the difference between the input and output components of the zonal heat balance for the lower part of heat transfer. The determination of heat losses by the heat balance in the lower heat transfer part allows their value to be estimated according to the current information about the operation of the furnace under specific raw materials and operating parameters. The information support of the system is presented, the software architecture is described, the characteristics of the software modules are given, and fragments of its work are illustrated. The information modeling system is distinguished by taking into account the basic physical and chemical laws of the processes of the control object, the principles of system analysis, and the use of modern principles for the development and construction of mathematical models and software. Heat loss control is necessary to assess the condition of the blast furnace refractory lining and rational gas distribution, as well as to adjust the coke rate.

文章介绍了算法结构以及数学和软件系统。文章介绍了根据下区热平衡确定高炉炉膛热损失算法的一般特征。在熔化过程中,通过风口带、料筒和坯料发生的外部热量损失由热量传递下部的分区热平衡的输入和输出分量之差确定。通过传热下部的热平衡确定热损失,可以根据特定原料和运行参数下熔炉运行的当前信息估算热损失值。介绍了该系统的信息支持、软件结构、软件模块的特点,并对其工作片段进行了说明。信息建模系统的特点是考虑到了控制对象过程的基本物理和化学规律、系统分析原理以及使用现代原理开发和构建数学模型和软件。热损失控制是评估高炉耐火衬和合理煤气分布状况以及调整焦炭率的必要条件。
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引用次数: 0
Analysis and mathematical modeling for microgeometry reproduction of a textured roll surface on a cold-rolled galvanized strip during temper rolling 回火轧制过程中冷轧镀锌带材轧辊表面纹理微观几何再现的分析和数学建模
IF 0.9 4区 材料科学 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-06-20 DOI: 10.1007/s11015-024-01724-3
N. N. Ogarkov, E. Yu. Zvyagina, S. M. Gorbatyuk, E. V. Sheshenin, K. F. Ibragimov

The possibility of representing the process of temper rolling for a galvanized cold-rolled strip as a simultaneous deformation of a binary zinc-steel system is demonstrated. It is confirmed that the simultaneous plastic deformation of the components of the galvanized strip during its temper rolling occurs when the critical thickness of zinc is achieved. The process of reproducing the microgeometry of the textured surface of the roll on a galvanized cold-rolled strip during its temper rolling is considered the process of filling the micro-cavities of the roll with the material in contact with it. A mathematical dependence is obtained for calculating the reproducibility ratio of the parameters of the textured surface on a cold roll on a galvanized cold-rolled strip, depending on the thickness and mechanical properties of the galvanized coating and steel strip, equipment characteristics, modes, and conditions of its temper rolling, as well as on the roughness parameters S, Ra, and Pc of the roll surface. A comparative assessment of the influence of the technological parameters of temper rolling on the reproduction ratio of the microgeometry of the roll surface on a galvanized cold-rolled strip is provided.

将镀锌冷轧带钢的回火轧制过程表示为二元锌钢系统的同时变形的可能性得到了证实。研究证实,当达到临界锌厚度时,镀锌板带在回火轧制过程中各组成部分同时发生塑性变形。在冷轧镀锌带钢的回火轧制过程中,轧辊纹理表面微观几何形状的再现过程被认为是轧辊微腔与接触材料的填充过程。根据镀锌涂层和钢带的厚度和机械性能、回火轧制的设备特性、模式和条件,以及轧辊表面的粗糙度参数 S、Ra 和 Pc,得出了计算镀锌冷轧带钢冷轧辊纹理表面参数重现率的数学依赖关系。本报告对回火轧制技术参数对镀锌冷轧带钢辊面微几何形状再现率的影响进行了比较评估。
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引用次数: 0
Development of an automated control system for the coiler mandrel drive 开发卷取机芯轴驱动自动控制系统
IF 0.9 4区 材料科学 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-06-20 DOI: 10.1007/s11015-024-01712-7
A. V. Tsukanov, K. V. Litsin

An automated control system for the coiler mandrel is developed. The causes of emergency situations are identified not only in the industrial conditions, but also from data obtained by reviewing the relevant literature and solving similar problems at other companies. A change in the tension of the strip due to the instability or malfunction of the coiler drive is revealed. This causes degradation in the quality of the rolled strip, its thickness variation, or even breakage. In addition, the installed system does not have a wide range of setpoints, thereby hindering the expansion of the range of rolled steel. One of the main causes of such problems is the outdated coiler mandrel motor and the lack of a proper control system. The developed automated control system is described mathematically. A torque compensation unit maintaining the required level of strip tension is designed. Matlab Simulink software is used to generate a model of an automated control system for the coiler mandrel and to analyze the strip tension and the associated electrical-drive parameters (speed, current, magnetic flux), which confirms the absence of jerks during coiling. The economic benefits of the implementation of this project are calculated. The payback period is about a year.

为卷取机芯轴开发了一套自动控制系统。不仅在工业条件下,而且通过查阅相关文献和解决其他公司的类似问题所获得的数据,确定了紧急情况的原因。研究揭示了由于卷取机驱动装置的不稳定或故障而导致的带材张力变化。这会导致轧制带材的质量下降、厚度变化,甚至断裂。此外,安装的系统设定点范围不广,从而阻碍了轧钢范围的扩大。造成这些问题的主要原因之一是卷取机芯轴电机过时和缺乏适当的控制系统。对所开发的自动控制系统进行了数学描述。设计了一个扭矩补偿装置,以保持所需的带钢张力水平。Matlab Simulink 软件用于生成卷取机芯轴自动控制系统的模型,并分析带材张力和相关的电气驱动参数(速度、电流、磁通量),从而证实卷取过程中不会出现抖动。对实施该项目的经济效益进行了计算。投资回收期约为一年。
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引用次数: 0
Improvements in steel production technology for main pipelines 改进主管道钢材生产技术
IF 0.9 4区 材料科学 Q4 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-06-20 DOI: 10.1007/s11015-024-01713-6
S. V. Kuberskii, S. A. Sbitnev, R. E. Velikotsky, D. A. Smolyarchuk, E. L. Vakulenko, S. A. Smolyarchuk

A change in the amount of the viscous component was established when testing with a falling load during the aging process of metal that has and has not undergone antiflaking heat treatment. The influence of heat treatment, heating temperature, post-tempering cooling rate, normalization, and annealing on the cold resistance of pipe steel of strength category K60 was studied. The aging of metal that has not undergone antiflaking heat treatment for 33 weeks, as well as an increase in the post-annealing cooling rate, increases cold resistance. The influence of eutectoid transformation on the mobilization processes of atomic hydrogen at the ferrite/cementite interface was characterized. The scientific notation of the theory of hydrogen brittleness has been expanded.

在对经过和未经过防脆裂热处理的金属进行时效处理的过程中,用下降载荷进行测试时,确定了粘性成分数量的变化。研究了热处理、加热温度、回火后冷却速度、正火和退火对强度类别为 K60 的钢管耐寒性的影响。未经过防脆化热处理的金属经过 33 周的时效处理,以及退火后冷却速度的增加,都会提高耐寒性。表征了共晶转变对铁素体/方解石界面原子氢调动过程的影响。扩展了氢脆理论的科学符号。
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引用次数: 0
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