Neutral nickel complexes with tetradentate N-heterocyclic carbene amidate ligands for electrocatalytic hydrogen evolution

IF 3.5 3区 化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR Dalton Transactions Pub Date : 2024-11-15 DOI:10.1039/d4dt02746a
Si Si, Wenxun Song, Jie Chen, Weimin Zhang, Wenhua Ji, Wonwoo Nam, Bin Wang
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Abstract

Neutral nickel complexes bearing tetradentate N-heterocyclic carbene (NHC) amidate ligands were prepared; the effects of coordination geometry of the nickel center and the electronic properties of the ligand on the redox behavior as well as the electrocatalytic activity for hydrogen evolution reaction (HER) were investigated.
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具有四价 N-杂环碳烯酰胺配体的中性镍络合物用于电催化氢进化
研究了镍中心的配位几何和配体的电子特性对氧化还原行为以及氢进化反应(HER)电催化活性的影响。
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来源期刊
Dalton Transactions
Dalton Transactions 化学-无机化学与核化学
CiteScore
6.60
自引率
7.50%
发文量
1832
审稿时长
1.5 months
期刊介绍: Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.
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