Disintegration of Thin Liquid Metal Films Engendered by Aluminum Corrosion

IF 13 2区 材料科学 Q1 CHEMISTRY, MULTIDISCIPLINARY Small Pub Date : 2024-11-17 DOI:10.1002/smll.202406363
Wangyan Wu, Guangyu Chai, Wei Luo
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Abstract

Liquid metals (LMs) illustrate a fantastic future. Thus, great endeavors are made to earn a comprehensive understanding of this fluid and carve it into a niche. Herein, by revisiting the combination of Ga-based LMs and aluminum (Al), a new phenomenon, namely the disintegration of LM films on encountering water, is identified. Deviating from previous investigations where the LM generally took the form of bulk puddles, the LM-Al slurry is spread as thin films here. In this case, Al debris embedded in the LM matrix hydrolyzes and therefore can exert disjoining pressure strong enough to split the thin film into countless tiny LM droplets. Based on this mechanism, transient circuits independent of substrate decomposition are realized. Furthermore, taking advantage of the portfolio strategy of pure LM and the LM-Al slurry, novel concepts of flood warning and information storage and encryption are demonstrated. Integrating these functions all in one demonstrates the versatility of the disintegration of thin LM films engendered by Al corrosion, which provides a scientific insight into ephemeral art and makes the Ga─Al combination more illuminating.

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铝腐蚀引起的薄液态金属膜解体。
液态金属(LMs)昭示着美好的未来。因此,人们一直在努力全面了解这种流体,并将其打造成一个利基市场。本文通过重新审视镓基液态金属与铝(Al)的结合,发现了一种新现象,即液态金属膜遇水分解。与以往的研究不同的是,以往的研究中 LM 通常以块状水坑的形式存在,而这里的 LM-Al 浆料则以薄膜的形式铺展开来。在这种情况下,嵌入 LM 基质中的铝碎片会发生水解,从而产生足够大的分离压力,将薄膜分裂成无数微小的 LM 液滴。基于这种机制,我们实现了不受基底分解影响的瞬态电路。此外,利用纯 LM 和 LM-Al 浆料的组合策略,还展示了洪水预警以及信息存储和加密的新概念。将这些功能集于一身,展示了铝腐蚀引起的 LM 薄膜分解的多功能性,为昙花一现的艺术提供了科学见解,并使 Ga─Al 组合更具启发性。
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来源期刊
Small
Small 工程技术-材料科学:综合
CiteScore
17.70
自引率
3.80%
发文量
1830
审稿时长
2.1 months
期刊介绍: Small serves as an exceptional platform for both experimental and theoretical studies in fundamental and applied interdisciplinary research at the nano- and microscale. The journal offers a compelling mix of peer-reviewed Research Articles, Reviews, Perspectives, and Comments. With a remarkable 2022 Journal Impact Factor of 13.3 (Journal Citation Reports from Clarivate Analytics, 2023), Small remains among the top multidisciplinary journals, covering a wide range of topics at the interface of materials science, chemistry, physics, engineering, medicine, and biology. Small's readership includes biochemists, biologists, biomedical scientists, chemists, engineers, information technologists, materials scientists, physicists, and theoreticians alike.
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