Recent advances in semi-heterogenous photocatalysis in organic synthesis

IF 9.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Chinese Chemical Letters Pub Date : 2024-09-18 DOI:10.1016/j.cclet.2024.110469
Jia-Cheng Hou , Wei Cai , Hong-Tao Ji , Li-Juan Ou , Wei-Min He
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Abstract

Semi-heterogeneous photocatalysis has emerged as a powerful and productive platform in organic chemistry, which provides mild and eco-friendly conditions for a diverse range of bond-forming reactions. The synergy of homogeneous catalysts and heterogeneous catalysts inherits their main advantages, such as higher activities, easy separation and superior recyclability. In this review, we summarize the recent advances in recyclable semi-heterogenous protocols for the light promoted bond-forming reactions and identify directions for future research according to the different photocatalysts/metal/redox catalysts involved. Notably, this review is not a comprehensive description of reported literature but aim to highlight and illustrate key concepts, strategies, reaction model, reaction conditions and mechanisms.

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有机合成中半同源光催化技术的最新进展
半均相光催化技术已成为有机化学领域一个强大而富有成效的平台,它为各种成键反应提供了温和而环保的条件。均相催化剂和异相催化剂的协同作用继承了它们的主要优点,如更高的活性、易于分离和卓越的可回收性。在本综述中,我们总结了用于光促进成键反应的可回收半异质方案的最新进展,并根据所涉及的不同光催化剂/金属/氧化还原催化剂确定了未来的研究方向。值得注意的是,本综述并非对已报道文献的全面描述,而是旨在强调和说明关键概念、策略、反应模型、反应条件和机理。
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来源期刊
Chinese Chemical Letters
Chinese Chemical Letters 化学-化学综合
CiteScore
14.10
自引率
15.40%
发文量
8969
审稿时长
1.6 months
期刊介绍: Chinese Chemical Letters (CCL) (ISSN 1001-8417) was founded in July 1990. The journal publishes preliminary accounts in the whole field of chemistry, including inorganic chemistry, organic chemistry, analytical chemistry, physical chemistry, polymer chemistry, applied chemistry, etc.Chinese Chemical Letters does not accept articles previously published or scheduled to be published. To verify originality, your article may be checked by the originality detection service CrossCheck.
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