Development and diagnostic study of the RF nitrogen atom source

IF 3.8 2区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Vacuum Pub Date : 2024-11-09 DOI:10.1016/j.vacuum.2024.113820
Mengting Li, Xin Xu, Wubin Wu, Shixiang Peng, Weiping Chen, Zhiyi Zhai, Qing Luo, Haiping Peng, Ailin Zhang
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Abstract

With the development of thin film technology, particularly the increasing demand for research on group III nitride materials, the need for N ions has significantly increased. A wider and more efficient RF nitrogen atom source specifically designed for nitride film growth has been developed. To evaluate the nitrogen atom density from the RF nitrogen source, a global model of RF nitrogen gas discharge plasma was created. This model was calibrated by measuring the emission spectrum of RF nitrogen gas discharge, and the relationships between nitrogen atom density and actual working pressure, power, and discharge chamber size were determined. It was found that the nitrogen atom density increases with increasing power and initially increases with pressure before decreasing. Finally, the nitrogen atom density was determined, achieving an 18 % nitrogen atom dissociation rate and a nitrogen atom density of 5 × 1012/cm³ at an RF power of 400 W. This density is significantly higher than that of nitrogen ions, indicating that this is a nitrogen atom source with high purity.
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射频氮原子源的开发和诊断研究
随着薄膜技术的发展,特别是对 III 族氮化物材料研究的需求不断增加,对氮离子的需求也大大增加。专门为氮化物薄膜生长设计的更广泛、更高效的射频氮原子源已经开发出来。为了评估射频氮源的氮原子密度,创建了一个射频氮气放电等离子体的全局模型。通过测量射频氮气放电的发射光谱对该模型进行了校准,并确定了氮原子密度与实际工作压力、功率和放电室尺寸之间的关系。结果发现,氮原子密度随功率的增加而增加,最初随压力的增加而增加,然后再减小。最后,对氮原子密度进行了测定,在射频功率为 400 W 时,氮原子解离率为 18%,氮原子密度为 5 × 1012/cm³,明显高于氮离子的密度,表明这是一种高纯度的氮原子源。
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来源期刊
Vacuum
Vacuum 工程技术-材料科学:综合
CiteScore
6.80
自引率
17.50%
发文量
0
审稿时长
34 days
期刊介绍: Vacuum is an international rapid publications journal with a focus on short communication. All papers are peer-reviewed, with the review process for short communication geared towards very fast turnaround times. The journal also published full research papers, thematic issues and selected papers from leading conferences. A report in Vacuum should represent a major advance in an area that involves a controlled environment at pressures of one atmosphere or below. The scope of the journal includes: 1. Vacuum; original developments in vacuum pumping and instrumentation, vacuum measurement, vacuum gas dynamics, gas-surface interactions, surface treatment for UHV applications and low outgassing, vacuum melting, sintering, and vacuum metrology. Technology and solutions for large-scale facilities (e.g., particle accelerators and fusion devices). New instrumentation ( e.g., detectors and electron microscopes). 2. Plasma science; advances in PVD, CVD, plasma-assisted CVD, ion sources, deposition processes and analysis. 3. Surface science; surface engineering, surface chemistry, surface analysis, crystal growth, ion-surface interactions and etching, nanometer-scale processing, surface modification. 4. Materials science; novel functional or structural materials. Metals, ceramics, and polymers. Experiments, simulations, and modelling for understanding structure-property relationships. Thin films and coatings. Nanostructures and ion implantation.
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