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Design and fabrication of a low-activation lithium target for BNCT BNCT低活化锂靶的设计与制造
IF 3.9 2区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-05-01 Epub Date: 2026-02-02 DOI: 10.1016/j.vacuum.2026.115154
Kai-Yu Ou , Yuntao Song , Ji-Chao Wang , Nengbin Liu , Xiaolong Wang , Xiancai Meng , Lizheng Liang , Ping Liu
The lithium target is a key component located at the end of the accelerator beamline or target station, serving as a bridge between the accelerator output and neutron production. To address the heat dissipation challenges of the lithium target and to reduce its radioactivity and maintenance frequency, this study comparatively evaluated the post-irradiation activation behavior of Ag–Cu and Ge–Cu filler metals. A low-activation Ge–Cu filler was ultimately selected to investigate the brazing process between CuCrZr and 316L stainless steel. Detailed analyses of the microstructure and mechanical properties of the CuCrZr/Cu–Ge/316L joints were performed. Furthermore, a finned, water-cooled lithium target with an inclined geometry was designed through finite element simulation, and a prototype of the inclined lithium target was successfully fabricated using the optimized process.
锂靶是位于加速器束线或靶站末端的关键部件,是加速器输出和中子产生之间的桥梁。为了解决锂靶的散热问题,降低其放射性和维护频率,本研究对比评估了Ag-Cu和Ge-Cu填充金属的辐照后活化行为。最终选择了一种低活化的Ge-Cu钎料,研究了CuCrZr与316L不锈钢的钎焊工艺。对CuCrZr/ Cu-Ge /316L接头的组织和力学性能进行了详细分析。在此基础上,通过有限元仿真设计了倾斜几何形状的翅片式水冷锂靶,并利用优化后的工艺成功制作了倾斜锂靶的原型。
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引用次数: 0
Influence of 100 MeV Ag7+ ion irradiation on photoluminescence and dielectric properties of bilayer structured Au/GeO2 thin films for optoelectronics applications 100mev Ag7+离子辐照对光电用双层结构Au/GeO2薄膜光致发光和介电性能的影响
IF 3.9 2区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-05-01 Epub Date: 2026-02-10 DOI: 10.1016/j.vacuum.2026.115169
Mahendra Singh Rathore , Anand Y. Joshi , Srinivasa Rao Nelamarri
The effects of 100 MeV Ag7+ ions irradiation on tailoring the physical, photoluminescence, and dielectric properties of bilayer Au/GeO2 thin films have been investigated. GeO2 and Au thin films were grown onto silicon substrates using E-beam evaporation. Eventually, the prepared films were irradiated at different ion fluences ranging from 1 × 1012 to 1 × 1013 ions/cm2. The results reveal the grain growth and nucleation of nanoparticles upon irradiation. Rutherford backscattered spectroscopy measurements were performed to identify the elemental composition and film thickness, which was around 110 nm. The chemical composition and oxidation state of elements were examined using X-ray photoelectron spectroscopy. The bandgap energy of films varies from 2.0 to 2.33 eV with irradiation. The films irradiated at 1 × 1012 and 1 × 1013 ions/cm2 show intense UV and blue PL emission, respectively. The dielectric constant and dielectric loss obtained were around 76.5 and 191 at 15 kHz, respectively, from the film irradiated at 1 × 1013 ions/cm2. The maximum AC conductivity value is exhibited in the high-frequency range (104 to 106 Hz). The photometric properties were evaluated from an illumination study. Varying S/P ratios of irradiated films shows the potential usefulness in blue and yellowish LEDs, and also considers the potential applications of Au/GeO2 in optoelectronic devices.
研究了100mev Ag7+离子辐照对Au/GeO2双层薄膜物理、光致发光和介电性能的影响。采用电子束蒸发的方法在硅衬底上生长了GeO2和Au薄膜。最后,制备的薄膜在1 × 1012 ~ 1 × 1013离子/cm2的不同离子浓度下辐照。结果揭示了辐照后纳米颗粒的晶粒生长和成核过程。卢瑟福背向散射光谱测量确定了元素组成和膜厚度,膜厚度约为110 nm。用x射线光电子能谱分析了元素的化学组成和氧化态。辐照后薄膜的带隙能在2.0 ~ 2.33 eV之间变化。在1 × 1012和1 × 1013离子/cm2辐照下,薄膜分别显示出强烈的紫外和蓝色PL发射。在1 × 1013离子/cm2辐照下,薄膜的介电常数和介电损耗分别为76.5和191。最大交流电导率值显示在高频范围(104 ~ 106 Hz)。通过光照研究对其光度特性进行了评价。不同S/P比值的辐照膜显示了在蓝色和黄色led中的潜在用途,并考虑了Au/GeO2在光电器件中的潜在应用。
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引用次数: 0
Requirements, design, and challenges of the HIAF vacuum system HIAF真空系统的要求、设计和挑战
IF 3.9 2区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-05-01 Epub Date: 2026-02-05 DOI: 10.1016/j.vacuum.2026.115162
J. Meng , J.C. Yang , C. Luo , W.S. Yang , W.J. Xie , Z. Chai , G.D. Shen , J.X. Wu , C.C. Li , J.L. Liu , J.Q. Jiao , X.J. Lin , N.F. Wei , Y.P. Wan , Y.M. Gao , X.R. Zhu , X.L. Ma , K.X. Zhong , R.P. Zhang , X.P. Zhang
The High Intensity heavy ion Accelerator Facility (HIAF) is the world's first heavy ion research device that integrates superconducting linear, synchronous acceleration, and storage rings. Its vacuum system is critical for the stable transport of high intensity beams and long-term reliable operation. This paper systematically presents the technical challenges, key innovations, and engineering achievements of the nearly 2-km-long HIAF vacuum system. To reduce the eddy current effect caused by rapidly changing magnetic fields, the Booster Ring (BRing) magnetic vacuum chamber innovatively adopts a titanium alloy-lined ultra-thin-walled (wall thickness 0.3 mm) structure based on the combination of 3D printing and Non-Evaporable Getter (NEG) coating technology. This type of vacuum chamber accounts for 60% of the BRing. In addition, by optimizing the outgassing process and chamber structure of the built-in components, an average pressure of 4.7 × 10−10 Pa was achieved, representing the world's largest room temperature ultra-thin-walled vacuum system; Faced with the challenge of limited installation space for the Spectrometer Ring (SRing) electronic-cooling system, an integrated solution combining sputter ion pumps, built-in titanium wire evaporation, and NEG coating was implemented. The system ultimately achieved an average pressure of 1.0 × 10−9 Pa; For the high radiation area of the High energy Fragment Separator (HFRS), a self-developed split type sealing flange is used to achieve remote disassembly and reliable sealing of pipelines, maintaining a pressure of 2.5 × 10−6 Pa; In addition, a 3 mm ultra-thin integrated baking jacket has been developed, achieving precise high-temperature baking of complex vacuum systems. The design of the HIAF vacuum system was initiated in 2018, following multiple iterations and process validations, its large-scale installation was launched in March 2024. Full integration of the system was achieved by September of the same year, completed the entire installation and commissioning process within a six-month period. The vacuum performance of each subsystem ultimately exceeded the design specifications, providing a new technological path and engineering paradigm for the design and construction of future large-scale accelerator vacuum systems.
高强度重离子加速器设施(HIAF)是世界上第一个重离子研究设备,集成了超导线性、同步加速和存储环。它的真空系统对高强度光束的稳定传输和长期可靠运行至关重要。本文系统地介绍了近2公里长的HIAF真空系统的技术挑战、关键创新和工程成果。为了减少磁场快速变化带来的涡流效应,助推环(BRing)磁真空室创新性地采用了基于3D打印和非蒸发吸气剂(NEG)涂层技术相结合的钛合金衬里超薄壁(壁厚0.3 mm)结构。这种类型的真空室占整个真空室的60%。此外,通过优化出气工艺和内置组件的腔室结构,实现了4.7 × 10−10 Pa的平均压力,代表了世界上最大的室温超薄壁真空系统;针对spectrum Ring (string)电子冷却系统安装空间有限的问题,采用了溅射离子泵、内置钛丝蒸发和NEG涂层相结合的集成解决方案。该系统最终实现了平均压力为1.0 × 10−9 Pa;高能碎片分离器(high energy Fragment Separator, HFRS)的高辐射区采用自主研发的分体式密封法兰,实现管道的远程拆卸和可靠密封,压力保持在2.5 × 10−6 Pa;此外,还开发了3mm超薄集成烘烤套,实现了复杂真空系统的精确高温烘烤。HIAF真空系统的设计始于2018年,经过多次迭代和工艺验证,其大规模安装于2024年3月启动。同年9月实现了系统的全面集成,在6个月内完成了整个安装和调试过程。各分系统的真空性能最终都超过了设计指标,为未来大型加速器真空系统的设计和建造提供了新的技术路径和工程范式。
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引用次数: 0
Microstructure evolution and mechanical properties of 5B70 Al alloy induced by micro-arc oxidation 微弧氧化诱发5B70铝合金组织演变及力学性能
IF 3.9 2区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-05-01 Epub Date: 2026-02-10 DOI: 10.1016/j.vacuum.2026.115175
Mingjin wu , Lixin Wang , Yao Xie , Chaoyu Han , Libin Ren , Ping Zhu , Chunyin Deng , Zhongbing Chen , Shuhui Wu , Li Lu , Jia Yang
This study focused on the structural heterogeneity of ceramic film formed during micro-arc oxidation (MAO) and its influence on mechanical properties. Using 5B70 Al alloy as the substrate, a systematic investigation was conducted to compare the microstructural features and mechanical performance between the edge transition zone around discharge pores and the ceramic region between pores. The results indicated that the edge transition zone, affected by localized high-temperature discharges, exhibited amorphous/sub-grain structures accompanied by the precipitation of ZrO2 particles and structural defects. In contrast, the inter-pore ceramic region features fine and dense grains with a high density of dispersed Al3Sc nanoparticles. Nanoindentation tests revealed that the inter-pore ceramic region demonstrated higher hardness and elastic modulus, whereas the edge transition zone showed reduced local fracture toughness due to microcracks and coarse particle-induced stress concentrations. This study elucidated the coupled mechanism between reinforcement phase evolution and discharge behavior in regulating film properties, providing theoretical guidance for optimizing the MAO process and enhancing the overall performance of ceramic films.
研究了微弧氧化(MAO)过程中陶瓷膜的结构非均质性及其对力学性能的影响。以5B70铝合金为基体,系统研究了放电孔周围边缘过渡区和孔间陶瓷区的组织特征和力学性能。结果表明:受局部高温放电的影响,合金边缘过渡区呈现出非晶/亚晶结构,并伴有ZrO2颗粒的析出和组织缺陷;相比之下,孔间陶瓷区具有细而致密的晶粒和高密度的分散Al3Sc纳米颗粒。纳米压痕测试表明,孔间陶瓷区具有较高的硬度和弹性模量,而边缘过渡区由于微裂纹和粗颗粒引起的应力集中而表现出局部断裂韧性降低。本研究阐明了增强相演化与放电行为对膜性能调节的耦合机制,为优化MAO工艺,提高陶瓷膜的整体性能提供理论指导。
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引用次数: 0
Structurally ordered glucose-derived carbon coatings enabling enhanced Cu–C interfacial thermal transport in 3D copper foams 结构有序的葡萄糖衍生碳涂层增强了三维铜泡沫中的Cu-C界面热传输
IF 3.9 2区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-05-01 Epub Date: 2026-02-09 DOI: 10.1016/j.vacuum.2026.115170
Junlei Qi, Yong Xia, Zhenyu Ye, Jian Cao, Yaotian Yan
As modern electronic systems advance toward compact architectures and intensified power densities, managing heat generation and dissipation has become a central challenge affecting both device stability and functional reliability. In this study, a carbon-coated three-dimensional (3D) porous copper foam composite (CFCC) was synthesized using a combined hydrothermal and annealing process to enhance heat dissipation. Optimization studies revealed that the combination of 6 g glucose with a 600 °C annealing treatment produced the most favorable coating quality. Consequently, the CFCC exhibited an in-plane thermal conductivity of 16.3 W m−1 K−1 and a thermal diffusivity of 28.5 mm2 s−1, representing 39.3% and 122.7% increases over pristine copper foam, respectively. Infrared thermography confirmed significantly improved heat spreading, with the optimized composite maintaining the lowest steady-state temperature (145.8 °C) under a constant 160 °C heat load.
Microstructural and mechanistic investigations indicate that the improved heat-transfer capability originates from the higher ordering of the carbon domains, the decrease in structural defects, and the strengthened Cu–C interfacial interactions. These factors collectively reduce phonon scattering, extend the phonon mean free path, and minimize interfacial thermal resistance, enabling effective three-dimensional heat conduction. Overall, the integrated hydrothermal–annealing strategy presents a controllable, scalable, and cost-effective approach for producing high-quality carbon coatings on porous metal substrates, offering substantial promise for advanced thermal management in next-generation high-power electronic systems.
随着现代电子系统朝着结构紧凑和功率密度增强的方向发展,管理热量的产生和消散已经成为影响器件稳定性和功能可靠性的核心挑战。本研究采用水热和退火相结合的方法合成了碳包覆三维多孔泡沫铜复合材料(CFCC),以增强其散热性。优化研究表明,6 g葡萄糖和600°C退火处理的组合产生了最有利的涂层质量。结果表明,CFCC的面内导热系数为16.3 W m−1 K−1,热扩散系数为28.5 mm2 s−1,比原始泡沫铜分别提高了39.3%和122.7%。红外热成像证实,在160°C恒定热负荷下,优化后的复合材料能保持最低稳态温度(145.8°C)。显微组织和力学研究表明,传热性能的提高源于碳畴有序度的提高、结构缺陷的减少和Cu-C界面相互作用的增强。这些因素共同减少声子散射,延长声子平均自由程,最小化界面热阻,实现有效的三维热传导。总的来说,集成的水热退火策略为在多孔金属基板上生产高质量的碳涂层提供了一种可控的、可扩展的、具有成本效益的方法,为下一代大功率电子系统的先进热管理提供了巨大的希望。
{"title":"Structurally ordered glucose-derived carbon coatings enabling enhanced Cu–C interfacial thermal transport in 3D copper foams","authors":"Junlei Qi,&nbsp;Yong Xia,&nbsp;Zhenyu Ye,&nbsp;Jian Cao,&nbsp;Yaotian Yan","doi":"10.1016/j.vacuum.2026.115170","DOIUrl":"10.1016/j.vacuum.2026.115170","url":null,"abstract":"<div><div>As modern electronic systems advance toward compact architectures and intensified power densities, managing heat generation and dissipation has become a central challenge affecting both device stability and functional reliability. In this study, a carbon-coated three-dimensional (3D) porous copper foam composite (CFCC) was synthesized using a combined hydrothermal and annealing process to enhance heat dissipation. Optimization studies revealed that the combination of 6 g glucose with a 600 °C annealing treatment produced the most favorable coating quality. Consequently, the CFCC exhibited an in-plane thermal conductivity of 16.3 W m<sup>−1</sup> K<sup>−1</sup> and a thermal diffusivity of 28.5 mm<sup>2</sup> s<sup>−1</sup>, representing 39.3% and 122.7% increases over pristine copper foam, respectively. Infrared thermography confirmed significantly improved heat spreading, with the optimized composite maintaining the lowest steady-state temperature (145.8 °C) under a constant 160 °C heat load.</div><div>Microstructural and mechanistic investigations indicate that the improved heat-transfer capability originates from the higher ordering of the carbon domains, the decrease in structural defects, and the strengthened Cu–C interfacial interactions. These factors collectively reduce phonon scattering, extend the phonon mean free path, and minimize interfacial thermal resistance, enabling effective three-dimensional heat conduction. Overall, the integrated hydrothermal–annealing strategy presents a controllable, scalable, and cost-effective approach for producing high-quality carbon coatings on porous metal substrates, offering substantial promise for advanced thermal management in next-generation high-power electronic systems.</div></div>","PeriodicalId":23559,"journal":{"name":"Vacuum","volume":"248 ","pages":"Article 115170"},"PeriodicalIF":3.9,"publicationDate":"2026-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146193153","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Brazing-induced microstructural effects on galvanic corrosion of AA4343/AA3xxx multi-layered alloys 钎焊诱导的显微组织对AA4343/AA3xxx多层合金电蚀的影响
IF 3.9 2区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-05-01 Epub Date: 2026-02-06 DOI: 10.1016/j.vacuum.2026.115165
Qiaoling Wang , Menghao Jiang , Zhikang Yang , Zhipeng Yuan , Yilu Zhang , Datian Cui , Yiyou Tu , Ting Yuan , Fang Liu , Liang Huang , Jin Peng , Zenglei Ni , Wenyi Huo
Galvanic corrosion limits the durability of multi-layered aluminum alloys in automotive heat exchangers, particularly in chloride-containing environments. This study investigated brazing-induced microstructural effects on the corrosion behavior of AA4343/AA3xxx/AA4343 multi-layered aluminum sheets, addressing interlayer and particle/matrix galvanic interactions. Using immersion tests in 3.5 wt% NaCl, electrochemical measurements, and thorough microstructural characterization, the results show that α-Al(Fe,Mn)Si particles act as cathodic sites, initiating pitting at particle/matrix interfaces, while grain boundary Al4Cu2Mg8Si7 (Q phase) precipitates undergo Mg dissolution and Cu enrichment, forming cathodic paths that promote intergranular corrosion. Brazing exacerbates corrosion by enhancing Si diffusion and Cu segregation at the clad/core interface, increasing galvanic coupling and intensifying both pitting and intergranular attack. These findings elucidate the synergistic roles of intermetallic particles, grain boundary phases, and brazing-induced microstructures in localized corrosion. This work provides critical insights for optimizing alloy composition, brazing processes, and service life prediction and advances the design of corrosion-resistant aluminum heat exchangers for new energy vehicles.
电偶腐蚀限制了多层铝合金在汽车热交换器中的耐久性,特别是在含氯化物的环境中。本研究研究了钎焊诱导的微观组织对AA4343/AA3xxx/AA4343多层铝板腐蚀行为的影响,解决了层间和颗粒/基体电相互作用的问题。结果表明:α-Al(Fe,Mn)Si颗粒作为阴极位点,在颗粒/基体界面处引发点蚀,而晶界Al4Cu2Mg8Si7 (Q相)析出相则发生Mg溶解和Cu富集,形成促进晶间腐蚀的阴极路径。钎焊通过增强包层/芯界面的Si扩散和Cu偏析,增加电偶联,加剧点蚀和晶间攻击,从而加剧腐蚀。这些发现阐明了金属间颗粒、晶界相和钎焊诱导的显微组织在局部腐蚀中的协同作用。这项工作为优化合金成分、钎焊工艺和使用寿命预测提供了重要见解,并推动了新能源汽车耐腐蚀铝热交换器的设计。
{"title":"Brazing-induced microstructural effects on galvanic corrosion of AA4343/AA3xxx multi-layered alloys","authors":"Qiaoling Wang ,&nbsp;Menghao Jiang ,&nbsp;Zhikang Yang ,&nbsp;Zhipeng Yuan ,&nbsp;Yilu Zhang ,&nbsp;Datian Cui ,&nbsp;Yiyou Tu ,&nbsp;Ting Yuan ,&nbsp;Fang Liu ,&nbsp;Liang Huang ,&nbsp;Jin Peng ,&nbsp;Zenglei Ni ,&nbsp;Wenyi Huo","doi":"10.1016/j.vacuum.2026.115165","DOIUrl":"10.1016/j.vacuum.2026.115165","url":null,"abstract":"<div><div>Galvanic corrosion limits the durability of multi-layered aluminum alloys in automotive heat exchangers, particularly in chloride-containing environments. This study investigated brazing-induced microstructural effects on the corrosion behavior of AA4343/AA3xxx/AA4343 multi-layered aluminum sheets, addressing interlayer and particle/matrix galvanic interactions. Using immersion tests in 3.5 wt% NaCl, electrochemical measurements, and thorough microstructural characterization, the results show that α-Al(Fe,Mn)Si particles act as cathodic sites, initiating pitting at particle/matrix interfaces, while grain boundary Al<sub>4</sub>Cu<sub>2</sub>Mg<sub>8</sub>Si<sub>7</sub> (Q phase) precipitates undergo Mg dissolution and Cu enrichment, forming cathodic paths that promote intergranular corrosion. Brazing exacerbates corrosion by enhancing Si diffusion and Cu segregation at the clad/core interface, increasing galvanic coupling and intensifying both pitting and intergranular attack. These findings elucidate the synergistic roles of intermetallic particles, grain boundary phases, and brazing-induced microstructures in localized corrosion. This work provides critical insights for optimizing alloy composition, brazing processes, and service life prediction and advances the design of corrosion-resistant aluminum heat exchangers for new energy vehicles.</div></div>","PeriodicalId":23559,"journal":{"name":"Vacuum","volume":"248 ","pages":"Article 115165"},"PeriodicalIF":3.9,"publicationDate":"2026-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146193213","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
First-principles study of the mechanical and thermal properties of borates MBO3 (M = Sc, Al, Ga) under high pressure 高压条件下硼酸盐MBO3 (M = Sc, Al, Ga)力学和热性能的第一性原理研究
IF 3.9 2区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-05-01 Epub Date: 2026-02-08 DOI: 10.1016/j.vacuum.2026.115160
Hao Wu , He Ma , Xudong Zhang , Lijia Chen , Xiaoming Wang , Haonan Li
First-principles calculations have been systematically employed to investigate the mechanical and thermal properties of trigonal MBO3 (M = Sc, Al, Ga) under hydrostatic pressure up to 25 GPa. At ambient conditions, AlBO3 possesses the highest stiffness and hardness but exhibits brittleness, in contrast to the most ductile yet mechanically softest ScBO3, with GaBO3 displaying intermediate character. With increasing pressure, the elastic moduli of AlBO3 and GaBO3 initially increase before softening, while those of ScBO3 decrease continuously, indicating distinct mechanical responses. Notably, AlBO3 undergoes a brittle-to-ductile transition around 15 GPa. Overall, pressure enhances ductility and elastic anisotropy but reduces material hardness. Regarding thermal properties, the lattice thermal conductivity increases with pressure for all compounds, whereas the Debye temperature shows a unique decrease only for ScBO3. These results elucidate the critical structure-property relationships in MBO3 borates under extreme pressure, offering valuable theoretical guidance for their targeted application in high-pressure environments.
本文采用第一性原理计算系统地研究了三角形MBO3 (M = Sc, Al, Ga)在高达25 GPa静水压力下的力学和热性能。在环境条件下,AlBO3具有最高的刚度和硬度,但表现出脆性,与最具延展性但机械最软的ScBO3相反,GaBO3表现出中间特性。随着压力的增加,AlBO3和GaBO3的弹性模量在软化前先增大,而ScBO3的弹性模量不断减小,力学响应明显。值得注意的是,AlBO3在15gpa左右经历了脆性到延性的转变。总的来说,压力增强了延展性和弹性各向异性,但降低了材料的硬度。在热性能方面,所有化合物的晶格热导率都随压力的增加而增加,而德拜温度仅对ScBO3显示出独特的降低。这些结果阐明了极端压力下硼酸MBO3的关键结构-性能关系,为其在高压环境中的定向应用提供了有价值的理论指导。
{"title":"First-principles study of the mechanical and thermal properties of borates MBO3 (M = Sc, Al, Ga) under high pressure","authors":"Hao Wu ,&nbsp;He Ma ,&nbsp;Xudong Zhang ,&nbsp;Lijia Chen ,&nbsp;Xiaoming Wang ,&nbsp;Haonan Li","doi":"10.1016/j.vacuum.2026.115160","DOIUrl":"10.1016/j.vacuum.2026.115160","url":null,"abstract":"<div><div>First-principles calculations have been systematically employed to investigate the mechanical and thermal properties of trigonal MBO<sub>3</sub> (M = Sc, Al, Ga) under hydrostatic pressure up to 25 GPa. At ambient conditions, AlBO<sub>3</sub> possesses the highest stiffness and hardness but exhibits brittleness, in contrast to the most ductile yet mechanically softest ScBO<sub>3</sub>, with GaBO<sub>3</sub> displaying intermediate character. With increasing pressure, the elastic moduli of AlBO<sub>3</sub> and GaBO<sub>3</sub> initially increase before softening, while those of ScBO<sub>3</sub> decrease continuously, indicating distinct mechanical responses. Notably, AlBO<sub>3</sub> undergoes a brittle-to-ductile transition around 15 GPa. Overall, pressure enhances ductility and elastic anisotropy but reduces material hardness. Regarding thermal properties, the lattice thermal conductivity increases with pressure for all compounds, whereas the Debye temperature shows a unique decrease only for ScBO<sub>3</sub>. These results elucidate the critical structure-property relationships in MBO<sub>3</sub> borates under extreme pressure, offering valuable theoretical guidance for their targeted application in high-pressure environments.</div></div>","PeriodicalId":23559,"journal":{"name":"Vacuum","volume":"248 ","pages":"Article 115160"},"PeriodicalIF":3.9,"publicationDate":"2026-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146161642","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Magnetic properties and hysteresis behavior of a mixed-spin (3/2, 1) ovalene like structure: A Monte Carlo study 混合自旋(3/ 2,1)类卵二烯结构的磁性和磁滞特性:蒙特卡罗研究
IF 3.9 2区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-04-01 Epub Date: 2026-02-10 DOI: 10.1016/j.vacuum.2026.115171
H. Kerrai , D. Bokpe , M. Mouhib , O. Mennaoui , S. Elhadfi , J. Chenouf , E.M. Jalal , H. Saadi , R. El Mrabet , A. El Fadl , T.D. Oke
Ovalene is a polycyclic aromatic hydrocarbon (PAH) characterized by a planar structure and high chemical stability, which confer unique electronic properties and make it a promising candidate for nanoscale applications. In this work, Monte Carlo simulations were employed to investigate the hysteresis behavior and magnetic properties of an ovalene-like nanostructure within the framework of a mixed-spin (3/2,1) Blume–Capel model. The ground-state phase diagrams as functions of various physical parameters were examined. The effects of the exchange coupling and single-ion anisotropy on the phase diagrams and magnetic properties were analyzed. The results indicated that the system exhibited compensation behavior as well as first- and second-order phase transitions. Furthermore, the influence of temperature, crystal field, and exchange interaction on the hysteresis cycles was investigated. Multiple hysteresis loop behaviors were observed for specific physical parameters, originating from the competition among anisotropy, temperature, and the longitudinal magnetic field.
椭圆烯是一种多环芳烃(PAH),具有平面结构和高化学稳定性,赋予其独特的电子性质,使其成为纳米级应用的有前途的候选者。在这项工作中,采用蒙特卡罗模拟研究了混合自旋(3/2,1)Blume-Capel模型框架下的类烯丙烯纳米结构的磁滞行为和磁性能。考察了基态相图作为各种物理参数的函数。分析了交换耦合和单离子各向异性对相图和磁性能的影响。结果表明,该系统具有补偿行为,并具有一阶和二阶相变。进一步研究了温度、晶体场和交换相互作用对磁滞周期的影响。由于各向异性、温度和纵向磁场的竞争,在特定的物理参数下观察到多种磁滞回线行为。
{"title":"Magnetic properties and hysteresis behavior of a mixed-spin (3/2, 1) ovalene like structure: A Monte Carlo study","authors":"H. Kerrai ,&nbsp;D. Bokpe ,&nbsp;M. Mouhib ,&nbsp;O. Mennaoui ,&nbsp;S. Elhadfi ,&nbsp;J. Chenouf ,&nbsp;E.M. Jalal ,&nbsp;H. Saadi ,&nbsp;R. El Mrabet ,&nbsp;A. El Fadl ,&nbsp;T.D. Oke","doi":"10.1016/j.vacuum.2026.115171","DOIUrl":"10.1016/j.vacuum.2026.115171","url":null,"abstract":"<div><div>Ovalene is a polycyclic aromatic hydrocarbon (PAH) characterized by a planar structure and high chemical stability, which confer unique electronic properties and make it a promising candidate for nanoscale applications. In this work, Monte Carlo simulations were employed to investigate the hysteresis behavior and magnetic properties of an ovalene-like nanostructure within the framework of a mixed-spin <span><math><mrow><mo>(</mo><mn>3</mn><mo>/</mo><mn>2</mn><mo>,</mo><mspace></mspace><mn>1</mn><mo>)</mo></mrow></math></span> Blume–Capel model. The ground-state phase diagrams as functions of various physical parameters were examined. The effects of the exchange coupling and single-ion anisotropy on the phase diagrams and magnetic properties were analyzed. The results indicated that the system exhibited compensation behavior as well as first- and second-order phase transitions. Furthermore, the influence of temperature, crystal field, and exchange interaction on the hysteresis cycles was investigated. Multiple hysteresis loop behaviors were observed for specific physical parameters, originating from the competition among anisotropy, temperature, and the longitudinal magnetic field.</div></div>","PeriodicalId":23559,"journal":{"name":"Vacuum","volume":"247 ","pages":"Article 115171"},"PeriodicalIF":3.9,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146174106","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of long-term thermal exposure at 600°C on the tensile properties of SiCf/Ti60 composites 600℃长期热暴露对SiCf/Ti60复合材料拉伸性能的影响
IF 3.9 2区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-04-01 Epub Date: 2026-02-03 DOI: 10.1016/j.vacuum.2026.115157
Zhicong Gan, Yumin Wang, Lina Yang, Qiuyue Jia, Mushi Li, Yuming Zhang, Xu Kong, Rui Yang
In this study, the tensile properties of SiCf/Ti60 composites under hot isostatic pressing (HIP) and 600 °C/100h states were investigated. The properties of thermal exposure SiCf/Ti60 composites were reduced by about 34 MPa compared to the properties of HIP composites with good thermal stability. The results show that SiCf/Ti60 composites have good matrix and interfacial thermal stability. The average grain size of matrix α-Ti in both states was 3.4-3.6 μm, the texture of α-Ti was <0001>//AD and <10-10>//AD, and the polar densities ranged from 6.9 to 7.4 to 2.7-3.1, respectively. The thickness of the interfacial reaction layer in both states was about 0.38-0.43 μm, the interfacial thickness increased slowly, and the silicon content fraction at the interface remains virtually unchanged. The interfacial silicide volume fraction is similar. About 58.2 MPa reduced the residual compressive stress of SiC fibers after thermal exposure. In summary, SiCf/Ti60 composites exhibit excellent microstructure, mechanical properties, and thermal stability, enabling long-term operation in a 600 °C vacuum environment.
在本研究中,研究了SiCf/Ti60复合材料在热等静压(HIP)和600℃/100h状态下的拉伸性能。与热稳定性良好的HIP复合材料相比,SiCf/Ti60复合材料的热暴露性能降低了约34 MPa。结果表明,SiCf/Ti60复合材料具有良好的基体和界面热稳定性。两种状态下基体α-Ti的平均晶粒尺寸为3.4 ~ 3.6 μm,织构为<;0001>;//AD和<;10 ~ 10>//AD,极性密度分别为6.9 ~ 7.4和2.7 ~ 3.1。两种状态下界面反应层厚度约为0.38 ~ 0.43 μm,界面厚度增加缓慢,界面硅含量基本保持不变。界面硅化物体积分数相似。约58.2 MPa降低了SiC纤维热暴露后的残余压应力。综上所述,SiCf/Ti60复合材料具有优异的微观结构、机械性能和热稳定性,可以在600°C的真空环境下长期运行。
{"title":"Effect of long-term thermal exposure at 600°C on the tensile properties of SiCf/Ti60 composites","authors":"Zhicong Gan,&nbsp;Yumin Wang,&nbsp;Lina Yang,&nbsp;Qiuyue Jia,&nbsp;Mushi Li,&nbsp;Yuming Zhang,&nbsp;Xu Kong,&nbsp;Rui Yang","doi":"10.1016/j.vacuum.2026.115157","DOIUrl":"10.1016/j.vacuum.2026.115157","url":null,"abstract":"<div><div>In this study, the tensile properties of SiC<sub>f</sub>/Ti60 composites under hot isostatic pressing (HIP) and 600 °C/100h states were investigated. The properties of thermal exposure SiC<sub>f</sub>/Ti60 composites were reduced by about 34 MPa compared to the properties of HIP composites with good thermal stability. The results show that SiC<sub>f</sub>/Ti60 composites have good matrix and interfacial thermal stability. The average grain size of matrix α-Ti in both states was 3.4-3.6 μm, the texture of α-Ti was &lt;0001&gt;//AD and &lt;10-10&gt;//AD, and the polar densities ranged from 6.9 to 7.4 to 2.7-3.1, respectively. The thickness of the interfacial reaction layer in both states was about 0.38-0.43 μm, the interfacial thickness increased slowly, and the silicon content fraction at the interface remains virtually unchanged. The interfacial silicide volume fraction is similar. About 58.2 MPa reduced the residual compressive stress of SiC fibers after thermal exposure. In summary, SiC<sub>f</sub>/Ti60 composites exhibit excellent microstructure, mechanical properties, and thermal stability, enabling long-term operation in a 600 °C vacuum environment.</div></div>","PeriodicalId":23559,"journal":{"name":"Vacuum","volume":"247 ","pages":"Article 115157"},"PeriodicalIF":3.9,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146174089","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Growth temperature optimization for high-quality InAs/GaSb Type-II superlattices grown by MBE towards high-performance long-wavelength infrared detection 面向高性能长波红外探测的MBE高质量InAs/GaSb ii型超晶格生长温度优化
IF 3.9 2区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2026-04-01 Epub Date: 2026-01-09 DOI: 10.1016/j.vacuum.2026.115083
Rong Yan, Yuhao Chen, Zhenfei Xing, Jing Yu, Bingfeng Liu, Weiqiang Chen, Lidan Lu, Lianqing Zhu
In response to the critical material requirements in the field of long-wavelength infrared detection, this study systematically investigates the effect of growth temperature on the material quality and interfacial properties of long-wavelength superlattices. By growing InAs/GaSb type-II superlattice samples at different temperatures (360°C–460 °C), a variety of characterization techniques including atomic force microscopy, X-ray diffraction, scanning electron microscopy, X-ray photoelectron spectroscopy, and transmission electron microscopy were employed to systematically analyze the influence of temperature on surface morphology, crystal quality, strain state, and interfacial chemical stability. The results indicate that the sample grown at 380 °C exhibits clear atomic step-flow morphology, low root-mean-square roughness (0.262 nm), sharp interfaces, and excellent period uniformity, demonstrating that this temperature represents the optimal condition for achieving high-quality layered growth of superlattices. This study provides a reliable process window and theoretical foundation for the high-quality superlattice materials required for high-performance long-wavelength infrared detectors.
针对长波红外探测领域对材料的关键要求,本研究系统地研究了生长温度对长波超晶格材料质量和界面性质的影响。通过在不同温度(360°C - 460°C)下生长InAs/GaSb ii型超晶格样品,采用原子力显微镜、x射线衍射、扫描电镜、x射线光电子能谱、透射电镜等多种表征技术,系统分析了温度对表面形貌、晶体质量、应变状态和界面化学稳定性的影响。结果表明,在380℃下生长的样品具有清晰的原子阶梯流形貌、较低的均方根粗糙度(0.262 nm)、清晰的界面和良好的周期均匀性,表明该温度是实现高质量层状超晶格生长的最佳条件。该研究为高性能长波红外探测器所需的高质量超晶格材料提供了可靠的工艺窗口和理论基础。
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Vacuum
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