Optimizing graphite-enhanced composite PCMs for superior thermal transport in shell and tube latent heat storage systems

Abstract

Latent heat thermal energy storage (LHTES) systems are designed to store excess thermal energy, addressing supply-demand mismatches during periods of low supply. Integrating such systems in the field is challenging due to the slow charging caused by the low thermal conductivity of phase change materials (PCM). This shortfall can be mitigated using composite PCM (CPCM) as the thermal storage medium, consisting of form-stable porous graphite foam impregnated with PCM. Compressed expanded graphite (CEG) is one such easily accessible form-stable porous material. The graphite foam in the CPCM causes a significant improvement in the effective thermal conductivity of the storage medium; however, it causes reduced latent heat storage capacity. Existing literature on CPCM mainly emphasizes positive aspects like enhanced thermal conductivity and reduced melting time while overlooking the adverse impact on latent heat storage capacity. This trade-off must be addressed while designing such a system, particularly when the storage unit is of fixed size and shape. This study aims to find the optimal volumetric proportion of CEG in CPCM, striking the best balance between these two conflicting attributes. Objective parameters such as energy storage ratio (ESR) and capacity ratio (CR) are introduced, along with charging duration, and they are optimized based on control parameters like CEG foam porosity (ε), HTF inlet temperature ($T_{in}$), and flow Reynolds number (Re). The analysis, obtained from a volume-averaged numerical model, involves diffusion-dominated energy transfer in the CPCM domain and provides crucial design guidelines for fixed-geometry LHTES units with CPCM as the storage medium.