Hydrothermal synthesis of CeSe anchored on graphitic carbon nitride nanoclusters as an electrocatalyst for enhanced oxygen evolution reaction

Abstract

The oxygen evolution reaction (OER) is a critical half-reaction in the process of water splitting, yet its practical application is hindered by slow kinetics and the high cost of conventional electrocatalysts. This study explores the potential of a novel CeSe/g-C₃N₄ nanocomposite as an efficient catalyst for OER in an alkaline environment. The CeSe/g-C₃N₄ nanocomposite exhibits exceptional electrocatalytic performance, demonstrated by a low overpotential of 196 mV at a current density of 10 mA cm⁻² and a reduced onset potential of 1.29 V versus the reversible hydrogen electrode (RHE). Additionally, nanocomposite's Tafel slope of 58.14 mV/dec is significantly lower compared to pure CeSe (76.89 mV/dec) and multi-layered g-C3N4 (89.76 mV/dec), indicating superior kinetic behavior. Remarkably, the CeSe/g-C₃N₄ composite also demonstrates excellent electrochemical stability, maintaining its performance over a 40-hour period. These findings suggest that the CeSe/g-C₃N₄ nanocomposite not only enhances the electrocatalytic properties necessary for OER but also holds the potential to outperform traditional noble metal-based catalysts, paving the way for more cost-effective and efficient water-splitting technologies.