Rare earth doped magnetoelectric composites for enhanced electromagnetic wave absorption

IF 6.5 2区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES Composites Communications Pub Date : 2024-11-05 DOI:10.1016/j.coco.2024.102157
Shuai Yu , Guizhou Qin , Di Lan , Hong Xu , Zicheng Yan , Yong Zhou , Bin Zhang , Xiaogang Su
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Abstract

Magnetoelectric electromagnetic wave absorption materials (EWAMs) with multiple loss mechanisms have shown remarkable results in solving electromagnetic (EM) interference and radar stealth. However, due to the Snoek limit, the magnetic properties are affected to some extent. Hence, based on low-cost two-dimensional graphite nanosheets and magnetic ferrite, a rare-earth doping strategy is innovatively proposed, aiming to develop a high-efficiency EWAM. Specifically, taking advantage of the significant differences in magnetic moments and dimensions between Gd and Fe ion, the modified ferrite owns unusual magnetic properties and dielectric capacity. Further, direct control of the EM parameters is achieved by finely tuning the component ratio, which in turn optimizes the response characteristics of EM wave absorption. Experimental results show a maximum reflection loss of −64.04 dB and a wide effective absorption bandwidth covering 4.88 GHz, corresponding to the absorption efficiency of −42.7 dB/mm and 3.25 GHz/mm, respectively. The outstanding performance is related to the synergistic effect of multiple loss management and impedance matching, and further confirmed by the radar cross section (RCS) reduction of 29.15 dBsm. Thus, the novel way opens a new horizon for the next magnetic-based EWAMs.

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用于增强电磁波吸收的掺稀土磁电复合材料
具有多种损耗机制的磁电电磁波吸收材料(EWAM)在解决电磁干扰和雷达隐身方面取得了显著效果。然而,由于 Snoek 限制,磁性会受到一定程度的影响。因此,基于低成本的二维石墨纳米片和磁性铁氧体,创新性地提出了一种稀土掺杂策略,旨在开发一种高效的 EWAM。具体而言,利用钆和铁离子在磁矩和尺寸上的显著差异,改性铁氧体具有不同寻常的磁性能和介电能力。此外,还可通过微调成分比例实现对电磁参数的直接控制,进而优化电磁波吸收的响应特性。实验结果表明,最大反射损耗为 -64.04 dB,有效吸收带宽为 4.88 GHz,吸收效率分别为 -42.7 dB/mm 和 3.25 GHz/mm。出色的性能与多重损耗管理和阻抗匹配的协同效应有关,雷达截面(RCS)降低 29.15 dBsm 也进一步证实了这一点。因此,这种新方法为下一代磁性 EWAM 开辟了新天地。
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来源期刊
Composites Communications
Composites Communications Materials Science-Ceramics and Composites
CiteScore
12.10
自引率
10.00%
发文量
340
审稿时长
36 days
期刊介绍: Composites Communications (Compos. Commun.) is a peer-reviewed journal publishing short communications and letters on the latest advances in composites science and technology. With a rapid review and publication process, its goal is to disseminate new knowledge promptly within the composites community. The journal welcomes manuscripts presenting creative concepts and new findings in design, state-of-the-art approaches in processing, synthesis, characterization, and mechanics modeling. In addition to traditional fiber-/particulate-reinforced engineering composites, it encourages submissions on composites with exceptional physical, mechanical, and fracture properties, as well as those with unique functions and significant application potential. This includes biomimetic and bio-inspired composites for biomedical applications, functional nano-composites for thermal management and energy applications, and composites designed for extreme service environments.
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