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Synergistic alumina particles and low-magnetic-field-induced vertical carbon fiber arrays for enhanced thermal conductivity and resilience of thermal interface materials 协同氧化铝颗粒和低磁场诱导垂直碳纤维阵列用于增强热界面材料的导热性和弹性
IF 7.7 2区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES Pub Date : 2026-02-01 DOI: 10.1016/j.coco.2026.102731
Zongyun Shao , Xuejiao Xia , Min Huang , Yaoyan Zhuang , Ruibang Xie , Fei Han , Yuanwei Yan
Currently, advanced thermal interface materials (TIMs) with both high thermal conductivity and elasticity are required to meet the heat dissipation needs of cutting-edge electronic devices. Therefore, constructing an ordered thermal conductive structure without compromising mechanical resilience is an attractive strategy for developing advanced TIMs. Herein, we propose a promising orientation strategy based on the synergistic interaction of magnetic fields and gravity to construct a tightly packed vertical CFs arrays within the silicone rubber (SR) matrix, where the alignment of CFs along the magnetic field is assisted by gravity. Furthermore, by incorporating spherical alumina particles to bridge the inter-fiber gaps while maintaining the integrity of CFs arrays, a defect-minimized thermal network has been created to significantly enhance both the thermal conductivity and mechanical properties of the composites. The prepared composite possesses a superior thermal conductivity of 30.8 W m−1 K−1, a low hardness of Shore 00 53, and an outstanding compressibility of 42.3 % under 40 psi. This work establishes a paradigm-shifting strategy for scalable production of next-generation TIMs, offering a robust solution to solve thermal management challenges in high-power electronics, optoelectronics, and energy storage systems.
目前,为了满足尖端电子器件的散热需求,需要具有高导热性和高弹性的先进热界面材料(TIMs)。因此,构建不影响机械弹性的有序导热结构是开发先进TIMs的一个有吸引力的策略。在此,我们提出了一种基于磁场和重力协同作用的定向策略,在硅橡胶(SR)矩阵中构建一个紧密排列的垂直碳纤维阵列,其中碳纤维沿着磁场的排列是由重力辅助的。此外,通过加入球形氧化铝颗粒来弥合纤维间的间隙,同时保持碳纤维阵列的完整性,一个缺陷最小化的热网络已经创建,以显着提高复合材料的导热性和机械性能。制备的复合材料导热系数为30.8 W m−1 K−1,硬度为邵氏00 53,在40 psi下的压缩率为42.3%。这项工作为下一代TIMs的可扩展生产建立了一种范式转换策略,为解决大功率电子、光电子和储能系统中的热管理挑战提供了一个强大的解决方案。
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引用次数: 0
In-situ MoS2-reinforced aramid nanofiber aerogels with integrated photothermal–phase-change coupling for adaptive thermal management 原位二硫化钼增强芳纶纳米纤维气凝胶集成光热相变耦合自适应热管理
IF 7.7 2区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES Pub Date : 2026-02-01 DOI: 10.1016/j.coco.2026.102745
Zhuguang Nie, Xiaoli Guo, Jinqiu Chen, Xiaonan Yang, Jiahui Chen, Rumin Wang, Shuhua Qi
Multifunctional aerogels, as ultralight, high-porosity three-dimensional network materials, achieve multiple functions such as mechanical enhancement, thermal management, photothermal conversion, and energy storage through molecular-level regulation, interface engineering, and multi-component composite design, for overcoming the brittleness and single-function limitations of traditional aerogels. This study introduces a novel fabrication of MoS2/aramid nanofiber (ANF) composite aerogels (ANFM) through in-situ hydrothermal growth of MoS2 nanosheets on ANF skeleton, integrated with polyethylene glycol (PEG) as phase-change material (PCM) to yield ANFM-PCM composites for adaptive thermal management. MoS2 nanosheets by reinforcing the pore network delay buckling instability, forming and leveraging C-Mo/N-Mo interfacial bonds to achieve efficient load transfer, enhances mechanical properties of ANFM composite aerogels from 228.25 to 501.1 kPa. ANFM-PCM composites preserve the intrinsic phase-transition behavior of PEG with maximum latent heat of 177.14 J/g, offering tunable latent heat and strong cycling durability, 92.4% enthalpy retention after 100 cycles. Moreover, their thermal decomposition temperatures all exceed 350 °C. Benefiting from high light absorption and broadband response of MoS2, the composites achieve efficient light-to-heat conversion synergized with phase-change storage for adaptive thermal regulation. Even if under a light intensity of 0.1 W/cm2, the absolute temperature difference between ANFM-PCM and the cold environment exceeds 90 °C. These lightweight, mechanically robust aerogels hold strong potential for intelligent thermal management, infrared stealth, and solar-energy storage applications.
多功能气凝胶是一种超轻、高孔隙度的三维网状材料,通过分子水平调控、界面工程和多组分复合设计,克服了传统气凝胶脆性和单一功能的局限性,实现了机械增强、热管理、光热转换和能量储存等多种功能。本研究介绍了一种新型的MoS2/芳纶纳米纤维(ANF)复合气凝胶(ANFM)的制备方法,通过在ANF骨架上原位水热生长MoS2纳米片,并与聚乙二醇(PEG)作为相变材料(PCM)相结合,得到具有自适应热管理功能的ANFM-PCM复合材料。MoS2纳米片通过强化孔隙网络延缓屈曲失稳,形成并利用C-Mo/N-Mo界面键实现有效的载荷传递,将ANFM复合气凝胶的力学性能从228.25提高到501.1 kPa。ANFM-PCM复合材料保留了PEG的固有相变行为,最大潜热为177.14 J/g,潜热可调,循环耐久性强,100次循环后焓保持率为92.4%。而且,它们的热分解温度都超过350℃。得益于MoS2的高光吸收和宽带响应,复合材料实现了高效的光热转换,并协同相变存储进行自适应热调节。即使在0.1 W/cm2的光强下,ANFM-PCM与冷环境的绝对温差也超过90℃。这些重量轻、机械坚固的气凝胶在智能热管理、红外隐身和太阳能存储应用方面具有巨大的潜力。
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引用次数: 0
Stimulating strain hardening ability to achieve excellent ductility for aluminum matrix composites by activating hetero-deformation induced hardening through designing grain partition 通过设计晶粒分配激活异质变形诱导硬化,从而激发应变硬化能力,使铝基复合材料具有良好的延性
IF 7.7 2区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES Pub Date : 2026-02-01 DOI: 10.1016/j.coco.2026.102739
Yulei Li , Xin Zhang , Jun Wang , Xin Li , Dongxu Hui , Shaodi Wang , Yifan Liang , Bo Li , Shengyin Zhou , Shufeng Li
In this study, a bimodal heterostructure TiB2/Al composites with designable coarse/fine grain partition were fabricated by combining multi-stage ball milling with a powder assembly process during powder metallurgy. The effects of different coarse/fine-grained fractions on the microstructure and mechanical properties of heterostructure composites were systematically investigated. The results demonstrate that the bimodal heterostructure can induce additional hetero-deformation induced (HDI) hardening compared to the fine-grained homogenous structure composites, effectively enhancing dislocation storage of coarse-grained zones and plastic deformation capability of fine-grained zones. Thereby promoting the strength-ductility synergy of the composites. When the coarse-grained mass fraction reaches 25 wt% (HS25), the elongation to failure of the bimodal heterostructure TiB2/Al composites increases from 8.1% for homogenous structure composites to 13%. Moreover, its strength rises by 11% compare to the heterostructure composites with 50 wt% coarse grain (HS50) without compromising the ductility. It provides an inspired strategy for developing Al matrix composites with coordinated matching of strength and ductility.
在本研究中,采用粉末冶金中的多级球磨和粉末组装相结合的方法制备了具有可设计的粗/细晶粒划分的双峰异质结构TiB2/Al复合材料。系统研究了不同粗/细晶组分对异质结构复合材料显微组织和力学性能的影响。结果表明:与细晶均相复合材料相比,双峰异质组织可诱发额外的异质变形诱导硬化(HDI),有效增强了粗晶区的位错储存和细晶区的塑性变形能力;从而促进复合材料的强度-延性协同作用。当粗晶质量分数达到25 wt% (HS25)时,双峰异质组织TiB2/Al复合材料的失效伸长率从均匀组织复合材料的8.1%提高到13%。此外,与含有50%粗晶的异质结构复合材料(HS50)相比,其强度提高了11%,而塑性不受影响。这为开发强度和延性协调匹配的铝基复合材料提供了一种有启发性的策略。
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引用次数: 0
Synergistic photocatalytic and antibacterial properties of Nd2O3/Sm2O3 nanocomposites for wastewater treatment and biomedical applications Nd2O3/Sm2O3纳米复合材料在废水处理和生物医学中的协同光催化和抗菌性能
IF 7.7 2区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES Pub Date : 2026-02-01 DOI: 10.1016/j.coco.2026.102734
Divya Selvakumar , Wenbin Zhou
Widely used synthetic organic dyes pose severe environmental and health risks due to their stability and resistance to degradation, while conventional metal oxide photocatalysts often exhibit limited efficiency in water remediation. Motivated by this challenge and the need for alternative photocatalytic materials, Sm2O3 nanoparticles (NPs), Nd2O3 NPs, and Nd2O3/Sm2O3 nanocomposites (NCs) were synthesized and evaluated for their photocatalytic degradation of commercially obtained dyes—Methylene Blue (MB), Rhodamine B (RhB), Methyl Orange (MO), Methyl Red (MR), and Congo Red (CR)—under UV irradiation. The Nd2O3/Sm2O3 NCs possess a larger specific surface area (SSA, 42.38 m2/g) as determined by BET analysis, enhancing active site availability and charge carrier mobility, while optical studies showed a lower band gap (4.21 eV), enabling improved photocatalytic performance. XPS confirmed Sm3+ and Nd3+ states, with distinct O 1s, Sm 3d, and Nd 3d peaks, verifying the formation of NCs. The TEM and SEM analyses of Nd2O3/Sm2O3 NCs showed spherical particles with a porous morphology, with average particle sizes of ∼91 nm and ∼0.048 μm, respectively, which in turn supports enhanced charge transfer and photocatalytic activity. Consequently, the Nd2O3/Sm2O3 NCs achieved higher degradation efficiencies 83.21 % (MB), 96.61 % (RhB), 97.92 % (MO), 97.55 % (MR), and 85.55 % (CR), than individual NPs, with faster reaction rate constants and shorter half-lives, while recyclability tests confirmed their stability and reusability. The increased photocatalytic efficiency of Nd2O3/Sm2O3 NCs, resulting from their larger surface area, reduced band gap, and improved charge separation, suggests their potential for wastewater treatment applications. Their radical scavenger experiments revealed that O2∗ radical plays a major role in MB and RhB degradation, whereas h+ is more influential in the degradation of MO, MR, and CR. Furthermore, antibacterial studies against the bacterial strains Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus) demonstrated superior antibacterial performance for Nd2O3/Sm2O3 NCs compared to individual oxides, emphasizing their potential for biomedical applications.
广泛使用的合成有机染料由于其稳定性和抗降解性而造成严重的环境和健康风险,而传统的金属氧化物光催化剂在水修复中往往表现出有限的效率。基于这一挑战和对替代光催化材料的需求,我们合成了Sm2O3纳米颗粒(NPs)、Nd2O3纳米颗粒(NPs)和Nd2O3/Sm2O3纳米复合材料(nc),并评估了它们在紫外线照射下对商业染料亚甲基蓝(MB)、罗丹明B (RhB)、甲基橙(MO)、甲基红(MR)和刚刚红(CR)的光催化降解效果。根据BET分析,Nd2O3/Sm2O3纳米材料具有更大的比表面积(SSA, 42.38 m2/g),提高了活性位点可用性和载流子迁移率,而光学研究显示其带隙较低(4.21 eV),从而提高了光催化性能。XPS证实了Sm3+和Nd3+态,有明显的O 1s、Sm 3d和Nd 3d峰,证实了NCs的形成。透射电镜和扫描电镜分析表明,Nd2O3/Sm2O3纳米材料的平均粒径分别为~ 91 nm和~ 0.048 μm,呈球形,具有多孔形貌,从而增强了电荷转移和光催化活性。结果表明,Nd2O3/Sm2O3 NCs的降解效率分别为83.21% (MB)、96.61% (RhB)、97.92% (MO)、97.55% (MR)和85.55% (CR),且反应速率常数更快,半衰期更短,可回收性测试证实了其稳定性和可重复使用性。Nd2O3/Sm2O3 NCs由于其更大的表面积、更小的带隙和更好的电荷分离而提高了光催化效率,这表明它们在废水处理中的应用潜力。他们的自由基清除实验表明,O2 *自由基在MB和RhB的降解中起主要作用,而h+在MO, MR和CR的降解中更有影响。此外,对大肠杆菌(E. coli)和金黄色葡萄球菌(S. aureus)的抗菌研究表明,与单个氧化物相比,Nd2O3/Sm2O3 NCs具有更优越的抗菌性能,强调了它们在生物医学上的应用潜力。
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引用次数: 0
Stretchable fatigue-resistant embedded copper electrodes with high figure of merit 可拉伸抗疲劳嵌入式铜电极,具有高品质系数
IF 7.7 2区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES Pub Date : 2026-02-01 DOI: 10.1016/j.coco.2026.102736
Xueyu Li , Yongliang Zhang , Qianqian Jia , Jingxian Xu , Chuanqian Shi , Yinji Ma , Jizhou Song , Hongliang Zhang
Flexible electronics are rapidly evolving, creating a strong demand for transparent electrodes that are not only highly conductive and transparent but also stretchable. This work presents a novel fabrication strategy based on one-step photolithography and electroplating to achieve a fully embedded horseshoe-shaped copper mesh, which demonstrates a superior combination of optoelectronic properties and mechanical durability compared to many existing transparent electrodes. The resulting electrode features a horseshoe-shaped copper mesh fully embedded in polydimethylsiloxane (PDMS), offering an ultra-low sheet resistance of 0.21 Ω/□, 82.9 % transmittance, and an outstanding figure of merit exceeding 8300. More importantly, the ESTCF demonstrates excellent mechanical durability, with only a fourfold increase in resistance after 3000 stretching cycles at 20 % strain. Using in-situ SEM and finite element analysis, We elucidate the stretching mechanism: it combines the geometric adaptation of the horseshoe structure with efficient stress dissipation at the metal and elastomer, a synergy that underpins system's exceptional stretchability. As a proof of concept, a transparent stretchable heater rapidly exceeds 100 °C at low voltage and maintains stable heating even when stretched up to 50 %. This work provides a reliable and scalable pathway toward high-performance stretchable transparent electrodes for next-generation wearable devices.
柔性电子产品正在迅速发展,对透明电极产生了强烈的需求,这种电极不仅具有高导电性和透明度,而且具有可拉伸性。这项工作提出了一种基于一步光刻和电镀的新型制造策略,以实现完全嵌入的马蹄形铜网,与许多现有的透明电极相比,它展示了光电性能和机械耐久性的优越组合。所得到的电极具有完全嵌入聚二甲基硅氧烷(PDMS)的马蹄形铜网,提供0.21 Ω/□的超低片电阻,82.9%的透光率,以及超过8300的杰出数字。更重要的是,ESTCF表现出优异的机械耐久性,在20%应变下3000次拉伸循环后阻力仅增加4倍。通过原位扫描电镜和有限元分析,我们阐明了拉伸机制:它结合了马蹄形结构的几何适应性和金属和弹性体的有效应力耗散,这是支撑系统卓越拉伸性的协同作用。作为概念证明,透明可拉伸加热器在低电压下迅速超过100°C,并且即使拉伸到50%也能保持稳定的加热。这项工作为下一代可穿戴设备的高性能可拉伸透明电极提供了可靠和可扩展的途径。
{"title":"Stretchable fatigue-resistant embedded copper electrodes with high figure of merit","authors":"Xueyu Li ,&nbsp;Yongliang Zhang ,&nbsp;Qianqian Jia ,&nbsp;Jingxian Xu ,&nbsp;Chuanqian Shi ,&nbsp;Yinji Ma ,&nbsp;Jizhou Song ,&nbsp;Hongliang Zhang","doi":"10.1016/j.coco.2026.102736","DOIUrl":"10.1016/j.coco.2026.102736","url":null,"abstract":"<div><div>Flexible electronics are rapidly evolving, creating a strong demand for transparent electrodes that are not only highly conductive and transparent but also stretchable. This work presents a novel fabrication strategy based on one-step photolithography and electroplating to achieve a fully embedded horseshoe-shaped copper mesh, which demonstrates a superior combination of optoelectronic properties and mechanical durability compared to many existing transparent electrodes. The resulting electrode features a horseshoe-shaped copper mesh fully embedded in polydimethylsiloxane (PDMS), offering an ultra-low sheet resistance of 0.21 Ω/□, 82.9 % transmittance, and an outstanding figure of merit exceeding 8300. More importantly, the ESTCF demonstrates excellent mechanical durability, with only a fourfold increase in resistance after 3000 stretching cycles at 20 % strain. Using in-situ SEM and finite element analysis, We elucidate the stretching mechanism: it combines the geometric adaptation of the horseshoe structure with efficient stress dissipation at the metal and elastomer, a synergy that underpins system's exceptional stretchability. As a proof of concept, a transparent stretchable heater rapidly exceeds 100 °C at low voltage and maintains stable heating even when stretched up to 50 %. This work provides a reliable and scalable pathway toward high-performance stretchable transparent electrodes for next-generation wearable devices.</div></div>","PeriodicalId":10533,"journal":{"name":"Composites Communications","volume":"62 ","pages":"Article 102736"},"PeriodicalIF":7.7,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146074832","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Surface modification of garnet fillers via an acidic small molecule agent enables compatible interfaces and high ion transport in solid-state composite electrolytes 通过酸性小分子剂对石榴石填料进行表面改性,使固体复合电解质中的界面兼容和高离子传输成为可能
IF 7.7 2区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES Pub Date : 2026-02-01 DOI: 10.1016/j.coco.2026.102744
Bingke Liu , Yihui Liu , Fei Wang , Rongjie Luo , Kele Miao , Yanfang Liang , Zhaochen Jiang , Xianming Liu , Xiaobin Sun , Cheng Zhang , Kunming Pan , Guangxin Wang , Yong Liu
Garnet-type Li6.4La3Zr1.4Ta0.6O12 (LLZTO) serves as an active filler in solid-state composite electrolytes for high-performance solid-state batteries because of its excellent conductivity, high chemical stability, and superior shear modulus. Nevertheless, composite electrolytes with LLZTO often exhibit slow Li+ transport and poor interface compatibility because of alkaline impurities (e.g., Li2CO3) formed on the LLZTO’s surface, hindering fast Li+ transport. Herein, we report a simple strategy to achieve in situ transformation of the alkaline impurities (Li2CO3) into an ion-conducting layer on the LLTZO’s surface via a trifluoromethanesulfonic acid (TfOH) treatment, which not only establishes effective interfacial contact with polyvinylidene fluoride (PVDF) but also facilitates Li+ transport. The resulting LiOTf layer can facilitate the formation of an LiF-enriched solid electrolyte interphase and a cathode–electrolyte interphase, which greatly improve the electrochemical performance of the solid state Li batteries with LiOTf@LLZTO electrolyte. Specifically, the PVDF/LiOTf@LLZTO electrolyte achieved a higher room-temperature ionic conductivity (6.0 × 10−4 S cm−1) and a higher Li+ transference number of 0.45 than the PVDF@LLZTO electrolyte. Moreover, the symmetric battery with the PVDF/LiOTf@LLZTO electrolyte showed a stable cycling for 1200 h at 0.2 mA cm−2, and the assembled Li|LiNi0.8Co0.1Mn0.1O2 full battery exhibited a high capacity retention rate of 88.1 % for 1000 cycles at 2 C.
石榴石型Li6.4La3Zr1.4Ta0.6O12 (LLZTO)具有优异的导电性、较高的化学稳定性和优越的剪切模量,可作为高性能固态电池固态复合电解质的活性填料。然而,由于LLZTO表面形成的碱性杂质(如Li2CO3)阻碍了Li+的快速传输,LLZTO复合电解质往往表现出Li+传输缓慢和界面相容性差。在此,我们报告了一种简单的策略,通过三氟甲烷磺酸(TfOH)处理将碱性杂质(Li2CO3)原位转化为LLTZO表面的离子导电层,这不仅与聚偏氟乙烯(PVDF)建立了有效的界面接触,还促进了Li+的运输。所得的LiOTf层有利于形成富liff的固体电解质界面和阴极-电解质界面,大大提高了LiOTf@LLZTO电解质固态锂电池的电化学性能。具体而言,PVDF/LiOTf@LLZTO电解质比PVDF@LLZTO电解质具有更高的室温离子电导率(6.0 × 10−4 S cm−1)和更高的Li+转移数(0.45)。此外,使用PVDF/LiOTf@LLZTO电解质的对称电池在0.2 mA cm−2下可稳定循环1200 h,组装的Li|LiNi0.8Co0.1Mn0.1O2充满电池在2℃下可循环1000次,容量保持率高达88.1%。
{"title":"Surface modification of garnet fillers via an acidic small molecule agent enables compatible interfaces and high ion transport in solid-state composite electrolytes","authors":"Bingke Liu ,&nbsp;Yihui Liu ,&nbsp;Fei Wang ,&nbsp;Rongjie Luo ,&nbsp;Kele Miao ,&nbsp;Yanfang Liang ,&nbsp;Zhaochen Jiang ,&nbsp;Xianming Liu ,&nbsp;Xiaobin Sun ,&nbsp;Cheng Zhang ,&nbsp;Kunming Pan ,&nbsp;Guangxin Wang ,&nbsp;Yong Liu","doi":"10.1016/j.coco.2026.102744","DOIUrl":"10.1016/j.coco.2026.102744","url":null,"abstract":"<div><div>Garnet-type Li<sub>6.4</sub>La<sub>3</sub>Zr<sub>1.4</sub>Ta<sub>0.6</sub>O<sub>12</sub> (LLZTO) serves as an active filler in solid-state composite electrolytes for high-performance solid-state batteries because of its excellent conductivity, high chemical stability, and superior shear modulus. Nevertheless, composite electrolytes with LLZTO often exhibit slow Li<sup>+</sup> transport and poor interface compatibility because of alkaline impurities (e.g., Li<sub>2</sub>CO<sub>3</sub>) formed on the LLZTO’s surface, hindering fast Li<sup>+</sup> transport. Herein, we report a simple strategy to achieve in situ transformation of the alkaline impurities (Li<sub>2</sub>CO<sub>3</sub>) into an ion-conducting layer on the LLTZO’s surface via a trifluoromethanesulfonic acid (TfOH) treatment, which not only establishes effective interfacial contact with polyvinylidene fluoride (PVDF) but also facilitates Li<sup>+</sup> transport. The resulting LiOTf layer can facilitate the formation of an LiF-enriched solid electrolyte interphase and a cathode–electrolyte interphase, which greatly improve the electrochemical performance of the solid state Li batteries with LiOTf@LLZTO electrolyte. Specifically, the PVDF/LiOTf@LLZTO electrolyte achieved a higher room-temperature ionic conductivity (6.0 × 10<sup>−4</sup> S cm<sup>−1</sup>) and a higher Li<sup>+</sup> transference number of 0.45 than the PVDF@LLZTO electrolyte. Moreover, the symmetric battery with the PVDF/LiOTf@LLZTO electrolyte showed a stable cycling for 1200 h at 0.2 mA cm<sup>−2</sup>, and the assembled Li|LiNi<sub>0.8</sub>Co<sub>0.1</sub>Mn<sub>0.1</sub>O<sub>2</sub> full battery exhibited a high capacity retention rate of 88.1 % for 1000 cycles at 2 C.</div></div>","PeriodicalId":10533,"journal":{"name":"Composites Communications","volume":"62 ","pages":"Article 102744"},"PeriodicalIF":7.7,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146169982","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A local load ratio approach to fatigue delamination growth simulation in CFRP aeronautical subcomponent CFRP航空子部件疲劳分层生长模拟的局部载荷比方法
IF 7.7 2区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES Pub Date : 2026-02-01 DOI: 10.1016/j.coco.2026.102730
Angela Russo, Rossana Castaldo, Aniello Riccio
Fatigue delamination is a critical damage mechanism in carbon fibre reinforced polymer (CFRP) laminates subjected to cyclic loading. In most simulations, the so-called envelope load method is adopted to avoid modelling the full load oscillation within each fatigue cycle, applying only the peak load while introducing the applied load ratio (Rapplied=PminPmax) into the damage law. However, this global ratio does not fully capture the local stress variations developing along an evolving delamination front. This study introduces a numerical approach that evaluates the local load ratio directly at each crack-front node. The formulation extends the classical Paris-law approach by incorporating the ratio between the minimum and maximum local energy release rates, expressed as Rlocal=(RminRmax)0.5, and considering the mode-mixity of delamination progression. Here, Rlocal is defined based on the local energy release rates at the crack front, distinguishing it from the global applied load ratio Rapplied, commonly used in envelope-load simulations. The proposed method, named SMART LOOP, accurately captures the delaminated area independently of mesh size through an adaptive load step–time module. Numerical results have been validated against an experimental case from the literature involving a typical stiffened CFRP aerospace panel tested under compression–compression fatigue loading at different global load ratios. The proposed approach has provided a physically consistent description of fatigue damage accumulation in CFRP laminates and has demonstrated strong agreement with experimental trends, confirming its suitability for implementation within standard finite element frameworks for fatigue life assessment. Furthermore, the findings highlight the importance of accounting for the local load ratio when fatigue loading is applied at high global load ratios.
疲劳脱层是碳纤维增强聚合物(CFRP)复合材料在循环载荷作用下的一种重要损伤机制。在大多数模拟中,为了避免模拟每个疲劳周期内的全载荷振荡,采用包络载荷法,只应用峰值载荷,而将应用载荷比(reapplied =PminPmax)引入损伤规律。然而,这一全球比值并不能完全反映沿分层前沿发展的局部应力变化。本文介绍了一种直接计算裂缝前缘各节点局部荷载比的数值方法。该公式扩展了经典的巴黎定律方法,将最小和最大局部能量释放率之比表示为Rlocal=(RminRmax)0.5,并考虑了分层过程的模态混合。这里,Rlocal是基于裂缝前缘的局部能量释放率来定义的,这与包络荷载模拟中常用的全局加载比Rapplied有所区别。该方法通过自适应负载步长模块精确捕获与网格大小无关的分层区域,称为SMART LOOP。数值结果与文献中的一个实验案例进行了验证,该案例涉及一个典型的加筋CFRP航空航天板,在不同的整体载荷比下进行了压缩-压缩疲劳载荷试验。提出的方法提供了CFRP层压板疲劳损伤积累的物理一致描述,并与实验趋势表现出强烈的一致性,确认了其在疲劳寿命评估的标准有限元框架内实施的适用性。此外,研究结果强调了在高整体载荷比下应用疲劳载荷时考虑局部载荷比的重要性。
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引用次数: 0
Water-tuned dynamic hydrogen-bond networks and modulus mismatch synergy for interfacial toughening in bilayer hydrogels 水调动态氢键网络和模量失配协同作用对双层水凝胶界面增韧的影响
IF 7.7 2区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES Pub Date : 2026-02-01 DOI: 10.1016/j.coco.2026.102713
Shan Jin, Xia Liu, Qingsheng Yang
Hydrogels suffer from low modulus-induced crack propagation, restricting their applications due to insufficient fracture toughness. Bilayer systems can enhance fracture toughness via modulus mismatch, but its synergistic toughening mechanism with interfacial adhesion remains unclear. Herein, a bilayer hydrogel system was designed by integrating Zr4+-completed CNF-PAAM/PAA layers to create “soft-hard” modulus mismatch and a 0.1 mm CNF-PAAM/PAA interlayer for enhanced interfacial adhesion. The CNF-mediated dynamic hydrogen bonding networks in the interlayer address energy dissipation deficiency under dynamic loading. Experiments showed that with 0.63 wt% CNF content and 68.63 wt% water content, the interfacial adhesion energy reached 307 J/m2, reducing the energy release rate by 29.7 % compared to the non-interlayer system. The elastic mismatch mechanism synergized with a 0.1 mm interlayer reduced stress concentration at the crack tip, increasing the critical elongation to 10. Based on Dundurs’ theory, an energy release rate expression considering water content was derived, revealing the quantitative synergistic toughening mechanism of “adhesion interface-modulus mismatch".
水凝胶受低模量裂纹扩展的影响,由于断裂韧性不足,限制了其应用。双层体系可以通过模量失配提高断裂韧性,但其与界面粘附的协同增韧机制尚不清楚。本文通过集成Zr4+完成的CNF-PAAM/PAA层来设计双层水凝胶体系,以产生“软硬”模错配,并设计了0.1 mm的CNF-PAAM/PAA中间层以增强界面附着力。cnf介导的层间动态氢键网络解决了动态加载下能量耗散不足的问题。实验表明,当CNF含量为0.63 wt%,水含量为68.63 wt%时,界面粘附能达到307 J/m2,与无层间体系相比,能量释放率降低了29.7%。弹性失配机制与0.1 mm的夹层协同作用降低了裂纹尖端的应力集中,将临界伸长率提高到10。基于Dundurs理论,导出了考虑含水量的能量释放率表达式,揭示了“粘附界面-模量失配”的定量协同增韧机理。
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引用次数: 0
Robust heat-free curing via ‘SiNergy’ in action: Residual cure kinetics and thermal stability of epoxy Silicon Nitride / Tungsten Carbide dual filler nanocomposites 通过“SiNergy”进行的无热固化:环氧氮化硅/碳化钨双填料纳米复合材料的残余固化动力学和热稳定性
IF 7.7 2区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES Pub Date : 2026-02-01 DOI: 10.1016/j.coco.2026.102735
Gopal Krishna Bhagavatula , Snaha Leena , Krishna Prasad Rajan , Selvin P. Thomas , Rasana Nanoth , Alessandro Pegoretti , Jayanarayanan Karingamanna
This work explores the synergistic effects of SiN and WC nanofillers on the residual curing behaviour and thermal degradation of epoxy (EP). DSC was used to evaluate residual curing characteristics, while TGA assessed thermal stability. HR-TEM confirmed that both nanofillers were uniformly dispersed and exhibited strong inter-particle and matrix interactions, suggesting effective integration into EP. The 0.5 wt% SiN/EP (ES2) exhibited near-to-complete curing, attributed to the hotball mechanism of silicon nitride (SiN), enhancing localized heat transfer which promotes crosslinking reactions. Tungsten carbide (WC) demonstrated minimal influence on the curing process, acting as a thermally inert filler in this context. However, the 0.25 wt% and 0.5 wt% of SiN/WC in EP showed improved curing efficiency compared to WC-based composites, confirming a synergistic interaction between the fillers. The activation energy (Ea) for residual curing was determined using model-free methods, such as the Kissinger and Ozawa methods, among others. ES2 displayed the lowest residual content with the highest Ea, suggesting more complete curing. Thermal degradation kinetics was studied using the Horowitz-Metzger, Coats-Redfern, and Friedman models. Among all formulations, the hybrid nanocomposite demonstrated superior thermal stability, attributed to the enhanced crosslink density induced by SiN and the good thermal barrier property of WC. The combined effect of these nanofillers resulted in increased activation energy for decomposition, indicating improved resistance to thermal degradation. These findings highlight the potential of combining SiN and WC nanofillers to engineer epoxy with enhanced curing efficiency and thermal durability, making them promising candidates for high-performance applications.
本研究探讨了SiN和WC纳米填料对环氧树脂(EP)残余固化行为和热降解的协同效应。DSC用于评价残余固化特性,TGA用于评价热稳定性。HR-TEM证实,这两种纳米填料均匀分散,并表现出很强的颗粒间和基质相互作用,表明它们有效地集成到EP中。由于氮化硅(SiN)的热球机制,0.5 wt%的SiN/EP (ES2)表现出接近完全的固化,增强了局部传热,促进了交联反应。碳化钨(WC)对固化过程的影响最小,在这种情况下作为热惰性填料。然而,与WC基复合材料相比,0.25 wt%和0.5 wt%的SiN/WC在EP中表现出更高的固化效率,证实了填料之间的协同作用。剩余固化的活化能(Ea)采用无模型方法,如Kissinger法和Ozawa法等确定。ES2的残余含量最低,Ea最高,说明固化更彻底。热降解动力学研究使用Horowitz-Metzger, Coats-Redfern和Friedman模型。在所有配方中,杂化纳米复合材料表现出优异的热稳定性,这主要归功于SiN诱导的交联密度增强和WC良好的热障性能。这些纳米填料的综合作用导致了分解活化能的增加,表明了对热降解的抵抗能力的提高。这些发现强调了将SiN和WC纳米填料结合在一起,以提高固化效率和热耐久性来设计环氧树脂的潜力,使其成为高性能应用的有希望的候选者。
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引用次数: 0
Finite element analysis of fatigue behavior in different structured composite variable vanes under coupled aerodynamic load and natural frequency 气动载荷与固有频率耦合作用下不同结构复合材料可变叶片疲劳特性的有限元分析
IF 7.7 2区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES Pub Date : 2026-02-01 DOI: 10.1016/j.coco.2026.102737
Chenchen Tan , Yujia Zhai , Zhongde Shan , Zheng Sun , Hao Huang , Xuehao Shan , Weihao Wang , Zitong Guo
With the increasing demand for lightweight aero-engines, composite variable vanes have become a research focus due to their exceptional design flexibility and fatigue resistance. However, challenges persist in understanding the complex damage mechanisms induced by anisotropic behavior and in predicting fatigue performance under coupled aerodynamic loads and natural frequencies. This study focuses on different structural composite variable vanes, systematically investigating an integrated analysis methodology for aerodynamic response and fatigue behavior. The manufacturing process of variable-thickness and variable-cross-section composite vanes was analyzed, followed by the design of fixture for variable vanes, where natural frequencies were obtained through swept-frequency testing. A progressive damage failure model was employed to predict the strength and stiffness of different mesoscale structures. This approach innovatively integrated mesoscale properties with a normalized life model and aerodynamic loading, thereby revealing the failure mechanisms under complex environmental conditions. The results demonstrate that a multiaxial three-dimensional woven composite (M3DWC) structure can effectively suppress damage propagation. Aerodynamic load distribution and vane natural frequencies were coupled to analyze the fatigue evolution paths, providing theoretical foundations for reliability assessment and multidisciplinary optimization of aerodynamic-fatigue performance in composite variable vanes.
随着航空发动机轻量化需求的不断增加,复合材料可变叶片以其优异的设计灵活性和抗疲劳性能成为研究热点。然而,在理解由各向异性行为引起的复杂损伤机制以及预测气动载荷和固有频率耦合作用下的疲劳性能方面仍然存在挑战。本研究以不同结构的复合材料可变叶片为研究对象,系统地研究了复合材料气动响应和疲劳行为的综合分析方法。分析了变厚度变截面复合叶片的制造工艺,设计了变叶片夹具,通过扫频测试获得了变叶片的固有频率。采用递进破坏模型对不同中尺度结构的强度和刚度进行了预测。该方法创新性地将中尺度特性与归一化寿命模型和气动载荷相结合,从而揭示了复杂环境条件下的失效机制。结果表明,多轴三维编织复合材料(M3DWC)结构能有效抑制损伤扩展。将气动载荷分布与叶片固有频率进行耦合,分析叶片疲劳演化路径,为复合材料可变叶片气动疲劳性能可靠性评估和多学科优化提供理论依据。
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引用次数: 0
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Composites Communications
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