Enhancing the piezoelectric performance of novel PZT-PMS-PSN piezoelectric ceramics by fine-tuning the monoclinic phase

IF 5.1 2区材料科学 Q1 MATERIALS SCIENCE, CERAMICS Ceramics International Pub Date : 2024-09-25 DOI:10.1016/j.ceramint.2024.09.287

Peixin Qiao , Ying Yang , Yiping Wang , Jiyang Zhang , Jintao Wu , Lei Zhao , Jikui Liu , Hao Liu , Huihui Liu , Wenbin Tang

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Abstract

The enhanced high-power performance of 0.93 Pb(Zr_1-xTi_x)O₃-0.05 Pb(Mn_1/3Sb_2/3)O₃-0.02 Pb(Sc_1/2Nb_1/2)O₃ (x = 0.48, 0.50, 0.52, 0.54, 0.56) piezoelectric ceramics (PZT-PMS-PSN) has been achieved with notable improvement in the piezoelectric coefficient (d₃₃). The presence of the monoclinic phase (Cc) has led to an increase in d₃₃ from 214 pC N⁻¹ to 315 pC N⁻¹. Therefore, the composition 0.93 Pb(Zr_0.48Ti_0.52)O₃-0.05 Pb(Mn_1/3Sb_2/3)O₃-0.02 Pb(Sc_1/2Nb_1/2)O₃ exhibits excellent mechanical and electrical parameters: a d₃₃ value of 315 pC N⁻¹, a high mechanical quality factor of 1578, an electromechanical coupling factor k_p of 52 %, and a low dielectric loss tanδ of only 0.288 %. Additionally, this ceramic exhibits a significantly high Curie temperature (T_c), reaching up to 328 °C which stabilizes its ferroelectric phase. Moreover, the phase transition of PZT-PMS-PSN ceramics from rhombohedral to tetragonal phase was investigated by X-ray diffraction, Raman scattering, Piezo-response force microscopy.

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通过微调单斜相提高新型 PZT-PMS-PSN 压电陶瓷的压电性能

0.93 Pb（Zr1-xTix）O3-0.05 Pb（Mn1/3Sb2/3）O3-0.02 Pb（Sc1/2Nb1/2）O3（x = 0.48、0.50、0.52、0.54、0.56）压电陶瓷（PZT-PMS-PSN）的高功率性能得到增强，压电系数（d33）显著提高。单斜相 (Cc) 的存在使 d33 从 214 pC N-1 增加到 315 pC N-1。因此，0.93 Pb（Zr0.48Ti0.52）O3-0.05 Pb（Mn1/3Sb2/3）O3-0.02 Pb（Sc1/2Nb1/2）O3 这种成分具有出色的机械和电气参数：d33 值为 315 pC N-1，机械品质因数高达 1578，机电耦合系数 kp 为 52 %，介电损耗 tanδ 很低，仅为 0.288 %。此外，这种陶瓷的居里温度（Tc）明显较高，最高可达 328 ℃，从而稳定了铁电相。此外，还通过 X 射线衍射、拉曼散射和压电响应力显微镜研究了 PZT-PMS-PSN 陶瓷从斜方相到四方相的相变过程。

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来源期刊

Ceramics International 工程技术-材料科学：硅酸盐

CiteScore

9.40

自引率

15.40%

发文量

4558

审稿时长

25 days

期刊介绍： Ceramics International covers the science of advanced ceramic materials. The journal encourages contributions that demonstrate how an understanding of the basic chemical and physical phenomena may direct materials design and stimulate ideas for new or improved processing techniques, in order to obtain materials with desired structural features and properties. Ceramics International covers oxide and non-oxide ceramics, functional glasses, glass ceramics, amorphous inorganic non-metallic materials (and their combinations with metal and organic materials), in the form of particulates, dense or porous bodies, thin/thick films and laminated, graded and composite structures. Process related topics such as ceramic-ceramic joints or joining ceramics with dissimilar materials, as well as surface finishing and conditioning are also covered. Besides traditional processing techniques, manufacturing routes of interest include innovative procedures benefiting from externally applied stresses, electromagnetic fields and energetic beams, as well as top-down and self-assembly nanotechnology approaches. In addition, the journal welcomes submissions on bio-inspired and bio-enabled materials designs, experimentally validated multi scale modelling and simulation for materials design, and the use of the most advanced chemical and physical characterization techniques of structure, properties and behaviour. Technologically relevant low-dimensional systems are a particular focus of Ceramics International. These include 0, 1 and 2-D nanomaterials (also covering CNTs, graphene and related materials, and diamond-like carbons), their nanocomposites, as well as nano-hybrids and hierarchical multifunctional nanostructures that might integrate molecular, biological and electronic components.