Liexin Wu, Dr. Lu Zhang, Dr. Jiandong Guo, Jihui Gao, Yang Ding, Dr. Jie Ke, Prof. Dr. Chuan He
{"title":"Frontispiz: Catalytic Asymmetric Construction of C- and Si-Stereogenic Silacyclopentanes via Hydrosilylation of Arylmethylenecyclopropanes","authors":"Liexin Wu, Dr. Lu Zhang, Dr. Jiandong Guo, Jihui Gao, Yang Ding, Dr. Jie Ke, Prof. Dr. Chuan He","doi":"10.1002/ange.202484862","DOIUrl":null,"url":null,"abstract":"<p><b>Asymmetric Hydrosilylation</b>. In their Communication (e202413753), Chuan He et al. report an efficient Cu-catalyzed asymmetric cascade hydrosilylation protocol, which allows the rapid assembly of carbon- and silicon-stereogenic silacyclopentanes with good to excellent enantioselectivities and diastereoselectivities.\n <figure>\n <div><picture>\n <source></source></picture><p></p>\n </div>\n </figure>\n </p>","PeriodicalId":7803,"journal":{"name":"Angewandte Chemie","volume":"136 48","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2024-11-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ange.202484862","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Angewandte Chemie","FirstCategoryId":"1085","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/ange.202484862","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
Asymmetric Hydrosilylation. In their Communication (e202413753), Chuan He et al. report an efficient Cu-catalyzed asymmetric cascade hydrosilylation protocol, which allows the rapid assembly of carbon- and silicon-stereogenic silacyclopentanes with good to excellent enantioselectivities and diastereoselectivities.