Hongmei Cao, Yudong Zhang, Xunzhu Zhou, Jie Yu, Xiang Chen, Lin Li
{"title":"Boosting the electrochemical performance of the Ni-rich LiNi<sub>0.96</sub>Co<sub>0.02</sub>Mn<sub>0.02</sub>O<sub>2</sub> cathode by high-valence Zr/Mo dual-doping.","authors":"Hongmei Cao, Yudong Zhang, Xunzhu Zhou, Jie Yu, Xiang Chen, Lin Li","doi":"10.1039/d4cc04275a","DOIUrl":null,"url":null,"abstract":"<p><p>Ni-rich oxides are attractive high-energy cathodes for lithium-ion batteries but suffer from inherent instability. Herein, we employed an ectopic Zr<sup>4+</sup>/Mo<sup>6+</sup> dual-doping strategy to reinforce the layered structure through robust M-O bonds and the pillar effect. This strategy mitigates lattice distortion during cycling and inhibits the interface side reactions.</p>","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":" ","pages":""},"PeriodicalIF":4.3000,"publicationDate":"2024-11-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Communications","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1039/d4cc04275a","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Ni-rich oxides are attractive high-energy cathodes for lithium-ion batteries but suffer from inherent instability. Herein, we employed an ectopic Zr4+/Mo6+ dual-doping strategy to reinforce the layered structure through robust M-O bonds and the pillar effect. This strategy mitigates lattice distortion during cycling and inhibits the interface side reactions.
期刊介绍:
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