Boosting the electrochemical performance of the Ni-rich LiNi0.96Co0.02Mn0.02O2 cathode by high-valence Zr/Mo dual-doping.

IF 4.3 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Chemical Communications Pub Date : 2024-11-20 DOI:10.1039/d4cc04275a
Hongmei Cao, Yudong Zhang, Xunzhu Zhou, Jie Yu, Xiang Chen, Lin Li
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Abstract

Ni-rich oxides are attractive high-energy cathodes for lithium-ion batteries but suffer from inherent instability. Herein, we employed an ectopic Zr4+/Mo6+ dual-doping strategy to reinforce the layered structure through robust M-O bonds and the pillar effect. This strategy mitigates lattice distortion during cycling and inhibits the interface side reactions.

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通过高价Zr/Mo双掺杂提高富镍LiNi0.96Co0.02Mn0.02O2阴极的电化学性能。
富镍氧化物是极具吸引力的锂离子电池高能阴极,但却存在固有的不稳定性。在这里,我们采用了异位 Zr4+/Mo6+ 双掺杂策略,通过强大的 M-O 键和支柱效应来强化层状结构。这种策略可减轻循环过程中的晶格畸变,并抑制界面副反应。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Chemical Communications
Chemical Communications 化学-化学综合
CiteScore
8.60
自引率
4.10%
发文量
2705
审稿时长
1.4 months
期刊介绍: ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.
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