Interstitial and substitutional doping of Mn2+ in 2D PEA2PbBr4 and BA2PbBr4 perovskites

IF 4.3 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Chemical Communications Pub Date : 2024-11-22 DOI:10.1039/d4cc04074k
Udara M. Kuruppu, Alvaro J. Magdaleno, Anuraj S. Kshirsagar, Bruno Donnadieu, Ferry Prins, Mahesh K. Gangishetty
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Abstract

Mn2+ doping imposes intriguing optoelectronic properties on lead-halide perovskites; however, its impact on their crystal structure remains unclear. This study investigates the consequences of interstitial and substitutional Mn2+ doping on the lattice-strain and interplanar spacings of 2D perovskites and correlates the structural changes to their optical properties.

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二维 PEA2PbBr4 和 BA2PbBr4 包晶中 Mn2+ 的间隙掺杂和取代掺杂
Mn2+ 的掺杂给铅卤化物包晶带来了引人入胜的光电特性;然而,它对晶体结构的影响仍不清楚。本研究探讨了间隙掺杂和取代掺杂 Mn2+ 对二维包晶的晶格应变和平面间距的影响,并将结构变化与其光学特性联系起来。
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来源期刊
Chemical Communications
Chemical Communications 化学-化学综合
CiteScore
8.60
自引率
4.10%
发文量
2705
审稿时长
1.4 months
期刊介绍: ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.
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