Strengthening SiC Ceramic Structural Integrity Made via 3D Printing with Pyrolysis and Precursor Infiltration

Manojit Das*, Arijit Jana, Karthik R, Rishabh Swarnkar, Astha Dixit, Sushanta Kumar Panda, Shobhit Kumar, Renjith Devasia* and Chandra Sekhar Tiwary*, 
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Abstract

3D printing, particularly direct ink writing (DIW), offers a different approach to crafting intricate ceramic structures. Here, 3D printing technology (direct ink writing (DIW)) based on extrusion has been utilized to fabricate SiC ceramic structures. The particle size, binder composition, and printing conditions were optimized to fabricate high-strength green structures. The mechanical properties of the 3D-printed SiC green structure were infiltrated with the liquid precursor, which filled the porous part of the structure. The composite is fired at a higher temperature, which results in the formation of SiC from the liquid precursor, demonstrating improved surface morphology, strength, density, and thermal properties of the printed structures. The 3D-printed SiC composite structures show an increase in mechanical strength up to 600% stronger as compared to the pristine SiC structures. Furthermore, the infiltrated, sintered composite demonstrates superior thermal properties, notably improved heat dissipation, in contrast to noninfiltrated samples, rendering it well-suited for high-temperature applications. This method presents a promising avenue for manufacturing advanced SiC components with superior properties.

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利用热解和前驱体渗透技术加强通过 3D 打印制造的碳化硅陶瓷结构的完整性
三维打印,尤其是直接墨水写入(DIW),为制作复杂的陶瓷结构提供了一种不同的方法。在此,我们利用基于挤压的三维打印技术(直接墨水写入(DIW))来制造碳化硅陶瓷结构。对粒度、粘合剂成分和打印条件进行了优化,以制造出高强度的绿色结构。液态前驱体渗入三维打印的碳化硅绿色结构,填充了结构的多孔部分,从而提高了其机械性能。复合材料在较高温度下烧制,从而使液态前驱体形成 SiC,显示出打印结构的表面形态、强度、密度和热性能均得到改善。与原始碳化硅结构相比,3D 打印碳化硅复合材料结构的机械强度提高了 600%。此外,与未浸润的样品相比,浸润烧结的复合材料具有优异的热性能,尤其是散热性能得到改善,因此非常适合高温应用。这种方法为制造具有优异性能的先进碳化硅元件提供了一条前景广阔的途径。
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期刊介绍: ACS Applied Engineering Materials is an international and interdisciplinary forum devoted to original research covering all aspects of engineered materials complementing the ACS Applied Materials portfolio. Papers that describe theory simulation modeling or machine learning assisted design of materials and that provide new insights into engineering applications are welcomed. The journal also considers experimental research that includes novel methods of preparing characterizing and evaluating new materials designed for timely applications. With its focus on innovative applications ACS Applied Engineering Materials also complements and expands the scope of existing ACS publications that focus on materials science discovery including Biomacromolecules Chemistry of Materials Crystal Growth & Design Industrial & Engineering Chemistry Research Inorganic Chemistry Langmuir and Macromolecules.The scope of ACS Applied Engineering Materials includes high quality research of an applied nature that integrates knowledge in materials science engineering physics mechanics and chemistry.
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