One-step selective synthesis of doubly and triply fused chiral boroloborole derivatives.

IF 4.3 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Chemical Communications Pub Date : 2024-11-22 DOI:10.1039/d4cc04433a
Josina L Bohlen, Nele Wieprecht, Merle Arrowsmith, Alena Häfner, Marco Neder, Holger Braunschweig
{"title":"One-step selective synthesis of doubly and triply fused chiral boroloborole derivatives.","authors":"Josina L Bohlen, Nele Wieprecht, Merle Arrowsmith, Alena Häfner, Marco Neder, Holger Braunschweig","doi":"10.1039/d4cc04433a","DOIUrl":null,"url":null,"abstract":"<p><p>Chiral 3<i>a</i>,6<i>a</i>-dihydroborolo[3,2-<i>b</i>]boroles are obtained in one diastereoselective step from the reactions of <i>ortho</i>-(dihaloboryl)arenes with stannole derivatives <i>via</i> a complex rearrangement of 1-borolyl-2-(dihaloboryl)arene intermediates.</p>","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":" ","pages":""},"PeriodicalIF":4.3000,"publicationDate":"2024-11-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Communications","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1039/d4cc04433a","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0

Abstract

Chiral 3a,6a-dihydroborolo[3,2-b]boroles are obtained in one diastereoselective step from the reactions of ortho-(dihaloboryl)arenes with stannole derivatives via a complex rearrangement of 1-borolyl-2-(dihaloboryl)arene intermediates.

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
一步选择性合成双、三融合手性硼硼烷衍生物。
手性 3a,6a-二氢硼并[3,2-b]硼烷通过 1-硼基-2-(二卤代硼酰)炔中间体的复杂重排反应,以非对映选择性步骤从正(二卤代硼酰)炔与锡烯衍生物的反应中获得。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
Chemical Communications
Chemical Communications 化学-化学综合
CiteScore
8.60
自引率
4.10%
发文量
2705
审稿时长
1.4 months
期刊介绍: ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.
期刊最新文献
Electrochemical Aldehydes Hydrogenation: Probing the Inner-Sphere Strategy with Nickel-Bipyridine Complexes Interstitial and substitutional doping of Mn2+ in 2D PEA2PbBr4 and BA2PbBr4 perovskites Distorted MO6 octahedral unit on the activity and stability for the oxygen evolution reaction Ca3Al2B8O18: Borate with Graphene-like Layer Featuring Two Types of Topological Six-Membered Rings Induced by [AlO4] Unit Gold-Catalyzed Hydrofluorination of Terminal Alkynes Using Potassium Bifluoride (KHF2)
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1