Josina L. Bohlen , Nele Wieprecht , Merle Arrowsmith , Alena Häfner , Marco Neder , Holger Braunschweig
{"title":"One-step selective synthesis of doubly and triply fused chiral boroloborole derivatives†","authors":"Josina L. Bohlen , Nele Wieprecht , Merle Arrowsmith , Alena Häfner , Marco Neder , Holger Braunschweig","doi":"10.1039/d4cc04433a","DOIUrl":null,"url":null,"abstract":"<div><div>Chiral 3<em>a</em>,6<em>a</em>-dihydroborolo[3,2-<em>b</em>]boroles are obtained in one diastereoselective step from the reactions of <em>ortho</em>-(dihaloboryl)arenes with stannole derivatives <em>via</em> a complex rearrangement of 1-borolyl-2-(dihaloboryl)arene intermediates.</div></div>","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"60 99","pages":"Pages 14782-14785"},"PeriodicalIF":4.2000,"publicationDate":"2024-11-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Communications","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S1359734524024406","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2024/11/13 0:00:00","PubModel":"Epub","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Chiral 3a,6a-dihydroborolo[3,2-b]boroles are obtained in one diastereoselective step from the reactions of ortho-(dihaloboryl)arenes with stannole derivatives via a complex rearrangement of 1-borolyl-2-(dihaloboryl)arene intermediates.
期刊介绍:
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