One-step selective synthesis of doubly and triply fused chiral boroloborole derivatives†

IF 4.2 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Chemical Communications Pub Date : 2024-11-21 Epub Date: 2024-11-13 DOI:10.1039/d4cc04433a
Josina L. Bohlen , Nele Wieprecht , Merle Arrowsmith , Alena Häfner , Marco Neder , Holger Braunschweig
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Abstract

Chiral 3a,6a-dihydroborolo[3,2-b]boroles are obtained in one diastereoselective step from the reactions of ortho-(dihaloboryl)arenes with stannole derivatives via a complex rearrangement of 1-borolyl-2-(dihaloboryl)arene intermediates.

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一步选择性合成双、三融合手性硼硼烷衍生物。
手性 3a,6a-二氢硼并[3,2-b]硼烷通过 1-硼基-2-(二卤代硼酰)炔中间体的复杂重排反应,以非对映选择性步骤从正(二卤代硼酰)炔与锡烯衍生物的反应中获得。
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来源期刊
Chemical Communications
Chemical Communications 化学-化学综合
CiteScore
8.60
自引率
4.10%
发文量
2705
审稿时长
1.4 months
期刊介绍: ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.
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