Vainius Skukauskas, Nicolas De Souza, Emma K. Gibson, Ian P. Silverwood
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引用次数: 0
Abstract
The dynamics of methanol within prototype methanol synthesis catalysts were studied using quasi-elastic neutron scattering. Three Cu-exchanged zeolites (mordenite, SSZ-13 and ZSM-5) were studied after methanol loading and showed jump diffusion coefficients between 1.04 × 10−10 and 2.59 × 10−10 m2·s−1. Non-Arrhenius behavior was observed with varying temperature due to methoxy formation at Brønsted acid sites and methanol clustering around copper cations.
期刊介绍：
Frontiers of Chemical Science and Engineering presents the latest developments in chemical science and engineering, emphasizing emerging and multidisciplinary fields and international trends in research and development. The journal promotes communication and exchange between scientists all over the world. The contents include original reviews, research papers and short communications. Coverage includes catalysis and reaction engineering, clean energy, functional material, nanotechnology and nanoscience, biomaterials and biotechnology, particle technology and multiphase processing, separation science and technology, sustainable technologies and green processing.
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