Synthesis and evaluation of new type plant extraction corrosion inhibitor

Zhi Zhang, Xiaoxiao Feng
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Abstract

The use of corrosion inhibitors in the development of oil and gas fields is an important means of effectively preventing metal corrosion, at present, the green growth of the oil and gas industry requires low-toxicity, low-residue, easy-to-post-treatment and other environmentally friendly corrosion inhibitors, however, most industrially used corrosion inhibitors such as mercury salts quaternary ammonium salts, and imidazolines are toxic to some degree. In this paper, a plant extract corrosion inhibitor was synthesized, firstly, the purple sweet potato extract was extracted by ethanol, and then the purple sweet potato extract and alkyl halide such as methane were used to produce the purple sweet potato corrosion inhibitor through condensation extraction and other processes, and the corrosion inhibitory performance of the inhibitor was evaluated by the loss-in-weight method, scanning electron microscopy, polarization curves, and impedance spectroscopy. The results show that there is a certain inhibition effect on N80 steel in the simulated stratum water environment, and the retardation rate can reach 91.38% in the gas phase, and the corrosion product morphology and chemical elements on the surface of N80 steel specimens were characterized by SEM, EDS, and it can be observed that a relatively dense protective film was formed after adding purple sweet potato corrosion inhibitor, and the corrosion inhibition rate can be known according to the weightlessness curve, Tafel curve and impedance curve. The corrosion inhibition rate increases with the increase of corrosion inhibitor concentration.
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新型植物萃取缓蚀剂的合成与评估
在油气田开发中使用缓蚀剂是有效防止金属腐蚀的重要手段,目前,油气行业的绿色发展需要低毒、低残留、易后处理等环保型缓蚀剂,然而工业上使用的汞盐类季铵盐、咪唑类等缓蚀剂大多具有一定毒性。本文合成了一种植物提取物缓蚀剂,首先用乙醇提取紫甘薯提取物,然后将紫甘薯提取物与甲烷等烷基卤化物通过缩合萃取等工艺制得紫甘薯缓蚀剂,并通过失重法、扫描电镜、极化曲线、阻抗谱等方法对缓蚀剂的缓蚀性能进行了评价。结果表明,在模拟地层水环境中对 N80 钢有一定的缓蚀效果,气相缓蚀率可达 91.38%,并通过扫描电镜、EDS 对 N80 钢试样表面的腐蚀产物形貌和化学元素进行了表征,可以观察到加入紫甘薯缓蚀剂后形成了较为致密的保护膜,根据失重曲线、Tafel 曲线和阻抗曲线可知缓蚀率。缓蚀率随缓蚀剂浓度的增加而增加。
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