Determining the alumina solubility in low-temperature KF-NaF-AlF3 melts using electrochemical methods

IF 2.5 Q2 CHEMISTRY, MULTIDISCIPLINARY Results in Chemistry Pub Date : 2024-11-23 DOI:10.1016/j.rechem.2024.101928
Sai Krishna Padamata , Daniel Gunnarsson , Rauan Meirbekova , Andrey Yasinskiy , Gudrun Saevarsdottir
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Abstract

Alumina solubility in KF-NaF-AlF3 melt was estimated using square wave voltammetry and linear sweep voltammetry methods. A 45° inclined and horizontal electrode were used in square wave voltammetry and linear sweep voltammetry, respectively. The electrolyte used in this study had a cryolite ratio (CR) of 1.3 and a potassium ratio (KR) of 0.3 at 800 °C. Voltammograms were recorded on both electrodes at different alumina concentrations in the melt. Based on these studies, the alumina solubility in the studied melt is 3.879 wt%, which agrees with the literature.

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利用电化学方法确定氧化铝在低温 KF-NaF-AlF3 熔体中的溶解度
采用方波伏安法和线性扫描伏安法估算了氧化铝在 KF-NaF-AlF3 熔体中的溶解度。方波伏安法和线性扫描伏安法分别使用了 45° 倾斜电极和水平电极。本研究中使用的电解液在 800 °C 下的冰晶石比率 (CR) 为 1.3,钾比率 (KR) 为 0.3。在熔体中氧化铝浓度不同的情况下,在两个电极上都记录了伏安图。根据这些研究,氧化铝在所研究熔体中的溶解度为 3.879 wt%,与文献报道一致。
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来源期刊
Results in Chemistry
Results in Chemistry Chemistry-Chemistry (all)
CiteScore
2.70
自引率
8.70%
发文量
380
审稿时长
56 days
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