Optimization of structural, optical, dielectric and magnetic properties of Gd3+ substituted Mg-Mn mixed spinel ferrite ceramics

Abstract

Manganese magnesium ferrite (Mg_0.5Mn_0.5Fe₂O₄) and Gd doped Mg_0.5Mn_0.5Fe₂O₄ (Mg_0.5Mn_0.5Fe_2-xGd_xO₄ (x = 0.0, 0.1, 0.2, 0.3, 0.4, 0.5) were synthesized using the solid-state method. The structural study was performed using the powder X-ray diffraction (XRD) technique. The XRD plot confirms the presence of a spinel cubic structure for pure MgMn ferrite and the existence of a secondary GdFeO₃ phase in addition to the cubic spinel phase for Gd-doped MgMn ferrite. The average crystallite size estimated from the Williamson-Hall plot decreases from 42.75 nm to 18.97 nm with the increase in Gd content. The microstructural study confirms the clear grains with well-defined grain boundaries. The Fourier Transform Infrared (FTIR) spectra of the samples show the vibrational bands at 3440 cm⁻¹, 1636 cm⁻¹, 1385 cm⁻¹, 1100 cm⁻¹, and 560 cm⁻¹ assigned to tetrahedral and octahedral sites. The improvement in dielectric property has been observed for Gd-doped samples. The saturation magnetization and remnant magnetization decrease from 0.7 to 0.3 emu and 0.035 to 0.0273 emu respectively. The coercivity increases from 31 to 75 Oe with the increase in Gd content. The fabricated spinel ferrites have significant electrical and magnetic properties which may be promising candidates for microwave devices.