Parametric evaluation of carbon dioxide and steam co-gasification of sewage sludge and palm kernel shell in a downdraft fixed bed reactor: Computational Fluid Dynamics (CFD) approach

IF 10.1 1区 工程技术 Q1 ENERGY & FUELS Applied Energy Pub Date : 2024-11-22 DOI:10.1016/j.apenergy.2024.124949
Kannie Winston Kuttin , Ahmed M. Salem , Lu Ding , Guangsuo Yu
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Abstract

Thermally converting sewage sludge (SS) to harness its energy potential brings challenges like high ash content, which can cause system instability. However, co-gasifying SS with carbon-rich materials has shown to be more advantageous. This study analyses a two-dimensional Eulerian CFD numerical model for a CO2 and steam cogasification of SS and palm kernel shell in a downdraft gasifier by solving the governing equations of mass phases, turbulence, energy, and momentum on a high-resolution mesh model. The devolatilization phase is defined by comprehensive solid carbon pyrolysis kinetic mechanisms and secondary gas reaction mechanisms, whilst the gasification and combustion processes are governed by applying detailed heterogeneous and homogeneous rate-controlled reactions. An experimental assessment with temperature of 1000 °C; ER of 0.28; fuel feed rate of 0.00061 kgs−1; at atmospheric pressure was conducted to validate the current model considering the temperature distribution and gas composition. The validated model is further used to evaluate the effect of mixing ratios, steam-to-fuel ratio (S/F), carbon dioxide-fuel ratio (CO2/F), and gasification temperature on syngas composition, lower heating value, hot gas efficiency, gas yield, H2/CO and synergistic coefficient. The predicted results agree well with the experimental data with the maximum deviational error of 9.52 %. The highest H2 production was recorded during steam gasification, whilst CO was favored by CO2 gasification. Synergistic analysis presented the highest synergy coefficient for the SS mixing ratio of 25 % at 1.91 and 50 % at 1.93 for steam and CO2 gasification respectively.
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在下吹式固定床反应器中对污水污泥和棕榈仁壳的二氧化碳和蒸汽联合气化进行参数评估:计算流体动力学(CFD)方法
对污水污泥(SS)进行热转化以利用其能源潜力会带来一些挑战,如高灰分会导致系统不稳定。然而,将 SS 与富碳材料进行联合气化则更具优势。本研究通过在高分辨率网格模型上求解质相、湍流、能量和动量的控制方程,分析了在下吹气化炉中对 SS 和棕榈仁壳进行二氧化碳和蒸汽气化的二维欧拉 CFD 数值模型。固体碳热解动力学机理和二次气体反应机理对脱胶阶段进行了定义,而气化和燃烧过程则由详细的异质和均质速率控制反应来控制。在温度为 1000 °C、ER 为 0.28、燃料进料率为 0.00061 kgs-1、常压条件下进行了实验评估,以验证当前模型的温度分布和气体成分。验证后的模型进一步用于评估混合比、蒸汽与燃料比 (S/F)、二氧化碳与燃料比 (CO2/F) 和气化温度对合成气成分、较低热值、热气效率、产气量、H2/CO 和协同系数的影响。预测结果与实验数据十分吻合,最大偏差为 9.52%。蒸汽气化法的 H2 产量最高,而 CO2 气化法的 CO 产量较高。协同分析表明,在蒸汽气化和二氧化碳气化过程中,当 SS 混合比为 25% 时,协同系数最高,分别为 1.91 和 1.93。
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来源期刊
Applied Energy
Applied Energy 工程技术-工程:化工
CiteScore
21.20
自引率
10.70%
发文量
1830
审稿时长
41 days
期刊介绍: Applied Energy serves as a platform for sharing innovations, research, development, and demonstrations in energy conversion, conservation, and sustainable energy systems. The journal covers topics such as optimal energy resource use, environmental pollutant mitigation, and energy process analysis. It welcomes original papers, review articles, technical notes, and letters to the editor. Authors are encouraged to submit manuscripts that bridge the gap between research, development, and implementation. The journal addresses a wide spectrum of topics, including fossil and renewable energy technologies, energy economics, and environmental impacts. Applied Energy also explores modeling and forecasting, conservation strategies, and the social and economic implications of energy policies, including climate change mitigation. It is complemented by the open-access journal Advances in Applied Energy.
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