High-performance PVdF-HFP/PEG-IL composites: The combined effects of PEG and ionic liquid on proton conductivity and dielectric characteristics

IF 6.5 2区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES Composites Communications Pub Date : 2024-11-21 DOI:10.1016/j.coco.2024.102175
Mesut Yılmazoğlu , Hikmet Okkay , Ufuk Abaci , Ozan Coban
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Abstract

This study explores the influence of varying polyethylene glycol (PEG) concentrations on the properties of PVdF-HFP/PEG-IL polymer composites through comprehensive characterization techniques, including FTIR, SEM, TGA, DMA, XRD and the detailed assessments of proton conductivity, dielectric properties, and relaxation dynamics. In terms of conductivity, the addition of PEG markedly improves proton conductivity. The PVdF-HFP/PEG40-IL composite exhibits the highest conductivity, reaching 1.96 × 10⁻2 S/m at 1 MHz and 300 K, and increasing to 4.27 × 10⁻2 S/m at 420 K. Dielectric properties show that the dielectric constant (ε′) increases with PEG content at low frequencies but decreases at higher frequencies due to reduced ionic polarization. Notably, PVdF-HFP/PEG40-IL achieves a dielectric constant of 3.39 × 106 at 20 Hz, which decreases to 30.34 at 1 MHz. Dielectric loss (ε'') also rises with temperature, with PVdF-HFP/PEG40-IL demonstrating the highest dielectric loss, indicative of superior proton conduction and polarization capabilities. Relaxation dynamics, as evidenced by tanδ, reveal that relaxation time significantly decreases with both increased PEG content and temperature, dropping from 1.06 × 10⁻4 s to 2 × 10⁻6 s as PEG concentration increases from 10 % to 40 %. This reduction in relaxation time correlates with enhanced proton conductivity and faster dipole relaxation, indicating PEG effect as a plasticizer that reduces polymer viscosity and improves ion transport. In conclusion, incorporating PEG into PVdF-HFP-IL composites leads to substantial improvements in proton conductivity, dielectric properties, and relaxation dynamics. The results highlight the crucial role of PEG in optimizing the performance of polymer electrolyte composites, making them effective candidates for advanced energy storage and conversion applications.
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高性能 PVdF-HFP/PEG-IL 复合材料:PEG 和离子液体对质子传导性和介电特性的综合影响
本研究通过傅立叶变换红外光谱(FTIR)、扫描电子显微镜(SEM)、热重分析(TGA)、二甲基亚砜(DMA)、X 射线衍射(XRD)以及质子电导率、介电性能和弛豫动力学的详细评估等综合表征技术,探讨了不同浓度的聚乙二醇(PEG)对 PVdF-HFP/PEG-IL 聚合物性能的影响。在电导率方面,PEG 的加入明显提高了质子电导率。介电性能表明,在低频下,介电常数(ε′)随 PEG 含量的增加而增加,但在高频下,由于离子极化的减少,介电常数(ε′)会降低。值得注意的是,PVdF-HFP/PEG40-IL 在 20 Hz 时的介电常数为 3.39 × 106,在 1 MHz 时降至 30.34。介电损耗(ε'')也随温度升高而增加,PVdF-HFP/PEG40-IL 的介电损耗最大,表明其质子传导和极化能力更强。tanδ 显示的弛豫动力学表明,弛豫时间随着 PEG 含量和温度的增加而显著缩短,当 PEG 浓度从 10% 增加到 40% 时,弛豫时间从 1.06 × 10-4 秒缩短到 2 × 10-6 秒。弛豫时间的缩短与质子传导性的增强和偶极弛豫的加快有关,这表明 PEG 作为增塑剂具有降低聚合物粘度和改善离子传输的作用。总之,在 PVdF-HFP-IL 复合材料中加入 PEG 能显著提高质子传导性、介电性能和弛豫动力学。这些结果凸显了 PEG 在优化聚合物电解质复合材料性能方面的关键作用,使其成为先进能量存储和转换应用的有效候选材料。
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来源期刊
Composites Communications
Composites Communications Materials Science-Ceramics and Composites
CiteScore
12.10
自引率
10.00%
发文量
340
审稿时长
36 days
期刊介绍: Composites Communications (Compos. Commun.) is a peer-reviewed journal publishing short communications and letters on the latest advances in composites science and technology. With a rapid review and publication process, its goal is to disseminate new knowledge promptly within the composites community. The journal welcomes manuscripts presenting creative concepts and new findings in design, state-of-the-art approaches in processing, synthesis, characterization, and mechanics modeling. In addition to traditional fiber-/particulate-reinforced engineering composites, it encourages submissions on composites with exceptional physical, mechanical, and fracture properties, as well as those with unique functions and significant application potential. This includes biomimetic and bio-inspired composites for biomedical applications, functional nano-composites for thermal management and energy applications, and composites designed for extreme service environments.
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