MXene-based materials as adsorbents, photocatalysts, membranes and sensors for detection and removal of emerging and gaseous pollutants: A comprehensive review
{"title":"MXene-based materials as adsorbents, photocatalysts, membranes and sensors for detection and removal of emerging and gaseous pollutants: A comprehensive review","authors":"Mohammad Hadi Dehghani , Nadeem Hussain Solangi , Nabisab Mujawar Mubarak , Natarajan Rajamohan , Subrajit Bosu , Amina Othmani , Md. Ahmaruzzaman , Soumya Ranjan Mishra , Baishali Bhattacharjee , Vishal Gadore , Talib Hussain Banglani , Nawab Waris , Ali hyder , Ayaz Ali Memon , Khalid Hussain Thebo , Payal Joshi , Grzegorz Boczkaj , Rama Rao Karri","doi":"10.1016/j.arabjc.2024.106052","DOIUrl":null,"url":null,"abstract":"<div><div>2D materials have garnered significant attention as potential solutions to various environmental challenges. Graphene, molybdenum disulfide, MXenes, and boron nitride have emerged as the most popular candidates among these materials. This article presents a comprehensive review and discussion on the emerging applications of MXenes in environmental engineering. MXenes have demonstrated immense potential as future materials for adsorption purposes. They have proven to be highly effective in removing emerging pollutants (heavy metals and organic pollutants) through the adsorption phenomenon. The effectiveness of MXenes in removing lead (Pb<sup>2+</sup>), chromium (Cr<sup>6+</sup>), copper (Cu<sup>2+</sup>), uranium (U<sup>6+</sup>), and mercury (Hg<sup>2+</sup>) has been confirmed, with a sorption capacity ranging from 100 to 250 mg g<sup>−1</sup>. Furthermore, MXenes have effectively removed several radionuclides, including uranium, europium, strontium, barium, and thorium. MXenes have proven to be highly efficient in treating water through adsorption in emerging organic pollutants, even for various organic dyes such as methylene blue, acid blue, congo red, methyl orange, and rhodamine B (RhB). Additionally, MXenes exhibit high treatment performance in adsorbing several pharmaceuticals like cloxacillin (CLX), ampicillin (AMP), amoxicillin (AMX), ciprofloxacin (CPX), amitriptyline (AMT), verapamil (VRP), carbamazepine (CBM), 17 α-ethinyl estradiol, ibuprofen (IBP), and diclofenac (DCF). Overall, MXenes offer several advantages, such as good conductivity, thermal performance, high surface area, and selectivity of intermolecular interactions. However, their application requires thoroughly evaluating their environmental impact and life cycle assessment.</div></div>","PeriodicalId":249,"journal":{"name":"Arabian Journal of Chemistry","volume":"18 1","pages":"Article 106052"},"PeriodicalIF":5.3000,"publicationDate":"2024-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Arabian Journal of Chemistry","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1878535224004544","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
2D materials have garnered significant attention as potential solutions to various environmental challenges. Graphene, molybdenum disulfide, MXenes, and boron nitride have emerged as the most popular candidates among these materials. This article presents a comprehensive review and discussion on the emerging applications of MXenes in environmental engineering. MXenes have demonstrated immense potential as future materials for adsorption purposes. They have proven to be highly effective in removing emerging pollutants (heavy metals and organic pollutants) through the adsorption phenomenon. The effectiveness of MXenes in removing lead (Pb2+), chromium (Cr6+), copper (Cu2+), uranium (U6+), and mercury (Hg2+) has been confirmed, with a sorption capacity ranging from 100 to 250 mg g−1. Furthermore, MXenes have effectively removed several radionuclides, including uranium, europium, strontium, barium, and thorium. MXenes have proven to be highly efficient in treating water through adsorption in emerging organic pollutants, even for various organic dyes such as methylene blue, acid blue, congo red, methyl orange, and rhodamine B (RhB). Additionally, MXenes exhibit high treatment performance in adsorbing several pharmaceuticals like cloxacillin (CLX), ampicillin (AMP), amoxicillin (AMX), ciprofloxacin (CPX), amitriptyline (AMT), verapamil (VRP), carbamazepine (CBM), 17 α-ethinyl estradiol, ibuprofen (IBP), and diclofenac (DCF). Overall, MXenes offer several advantages, such as good conductivity, thermal performance, high surface area, and selectivity of intermolecular interactions. However, their application requires thoroughly evaluating their environmental impact and life cycle assessment.
期刊介绍:
The Arabian Journal of Chemistry is an English language, peer-reviewed scholarly publication in the area of chemistry. The Arabian Journal of Chemistry publishes original papers, reviews and short reports on, but not limited to: inorganic, physical, organic, analytical and biochemistry.
The Arabian Journal of Chemistry is issued by the Arab Union of Chemists and is published by King Saud University together with the Saudi Chemical Society in collaboration with Elsevier and is edited by an international group of eminent researchers.