Frontispiz: K+-Mediated vs Pd-Catalyzed Cyclotrimerization of 9,10-Didehydrotribenzo[8]annulene (TribenzoCOTyne): Stereodivergent Access to (α,α,α)- and (α,α,β)-Fragments of Cubic Graphite

Dr. Jesús Bello-García, Prof. Jesús A. Varela, Prof. Carlos Saá
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Abstract

Annulenes. In their Communication (e202414017), Jesús Bello-García, Jesús A. Varela, and Carlos Saá report the K+-mediated versus Pd-catalyzed cyclotrimerization of 9,10-didehydrotribenzo[8]annulene to access stereodivergent fragments of cubic graphite.

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正文:K+ 介导与 Pd 催化的 9,10-二脱氢三苯并[8]茚(TribenzoCOTyne)环三聚反应:立体发散进入立方石墨的 (α,α,α)- 和 (α,α,β)- 片段
烯。Jesús Bello-García、Jesús A. Varela 和 Carlos Saá 在他们的通讯(e202414017)中报告了 K+ 介导和 Pd 催化的 9,10-二脱氢三苯并[8]烯环三聚反应,从而获得立方石墨的立体异构片段。
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来源期刊
Angewandte Chemie
Angewandte Chemie 化学科学, 有机化学, 有机合成
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