Deciphering Water Oxidation Catalysts: The Dominant Role of Surface Chemistry over Reconstruction Degree in Activity Promotion

IF 26.6 1区 材料科学 Q1 Engineering Nano-Micro Letters Pub Date : 2024-11-26 DOI:10.1007/s40820-024-01562-7
Li An, Jianyi Li, Yuanmiao Sun, Jiamin Zhu, Justin Zhu Yeow Seow, Hong Zhang, Nan Zhang, Pinxian Xi, Zhichuan J. Xu, Chun-Hua Yan
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引用次数: 0

Abstract

Highlights

  • Demonstrate that the key factor to determine the activity of reconstructed surfaces is the surface chemistry, instead of reconstruction degree using the popular perovskite LaNi1-xFexO3 oxides as model materials.

  • Fe content can influence both the surface reconstruction degree, the activation degree, and the activity of reconstructed surfaces.

  • The oxygen evolution reaction activity of reconstructed catalysts is primarily governed by the chemistry of the reconstructed surface species.

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解密水氧化催化剂:表面化学在促进活性方面的主导作用大于重构程度
以常用的过氧化物 LaNi1-xFexO3 氧化物为模型材料,证明决定重构表面活性的关键因素是表面化学,而不是重构程度。
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来源期刊
Nano-Micro Letters
Nano-Micro Letters NANOSCIENCE & NANOTECHNOLOGY-MATERIALS SCIENCE, MULTIDISCIPLINARY
CiteScore
32.60
自引率
4.90%
发文量
981
审稿时长
1.1 months
期刊介绍: Nano-Micro Letters is a peer-reviewed, international, interdisciplinary, and open-access journal published under the SpringerOpen brand. Nano-Micro Letters focuses on the science, experiments, engineering, technologies, and applications of nano- or microscale structures and systems in various fields such as physics, chemistry, biology, material science, and pharmacy.It also explores the expanding interfaces between these fields. Nano-Micro Letters particularly emphasizes the bottom-up approach in the length scale from nano to micro. This approach is crucial for achieving industrial applications in nanotechnology, as it involves the assembly, modification, and control of nanostructures on a microscale.
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